scholarly journals Towards <i>in-situ</i> U–Pb dating of dolomites

2020 ◽  
Author(s):  
Bar Elisha ◽  
Perach Nuriel ◽  
Andrew Kylander-Clark ◽  
Ram Weinberger
Keyword(s):  
High Resolution ◽  
Imaging Techniques ◽  
Dolomitic Rock ◽  
Icp Ms ◽  
Highly Sensitive ◽  
Wide Range ◽  
Absolute Dating ◽  
Crater Morphology ◽  
Epigenetic Processes

Abstract. Recent U–Pb dating by laser ablation ICP-MS has demonstrated that reasonable precision (3–10 % 2σ) can be achieved for high-resolution dating of texturally distinct calcite phases. Absolute dating of dolomite, for which biostratigraphy and traditional dating techniques are very limited, remains challenging but may resolve many fundamental questions related to the timing of mineral-rock formation by syngenetic, diagenesis, hydrothermal, and epigenetic processes. In this study we explore the possibility of dating dolomitic rocks via recent LA-ICP-MS dating techniques developed for calcite. The in-situ U–Pb dating was tested on a wide range of dolomite rocks of various origins (i.e., syngenetic, early diagenetic and epigenetic) from the Cambrian to Pliocene age – all of which from well-constrained stratigraphic sections in Israel. We present in-situ U–Pb results of dolomitic rock samples, together with imaging techniques and chemical characterizations. We show that dolomite dating is highly sensitive to textural differences and highlight parameters such as crater morphology and roughness, calcite zoning and impurities that may affect the interpretation of the resulted ages. Textural examination indicates zonation and mixing of different phases at the sub-millimeter scale (

scholarly journals Towards in situ U–Pb dating of dolomite

Geochronology ◽  
2021 ◽  
Vol 3 (1) ◽  
pp. 337-349
Author(s):  
Bar Elisha ◽  
Perach Nuriel ◽  
Andrew Kylander-Clark ◽  
Ram Weinberger
Keyword(s):  
Inductively Coupled Plasma ◽  
Chemical Characterization ◽  
Early Diagenesis ◽  
Textural Features ◽  
Inductively Coupled ◽  
Icp Ms ◽  
Plasma Mass Spectrometry ◽  
Absolute Dating ◽  
Epigenetic Processes

Abstract. Recent U–Pb dating by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) has demonstrated that reasonable precision (3 %–10 %, 2σ) can be achieved for high-resolution dating of texturally distinct calcite phases. Absolute dating of dolomite, for which biostratigraphy and traditional dating techniques are very limited, remains challenging, although it may resolve many fundamental questions related to the timing of mineral-rock formation by syngenetic, diagenesis, hydrothermal, and epigenetic processes. In this study we explore the possibility of dating dolomitic rocks via recent LA-ICP-MS dating techniques developed for calcite. The in situ U–Pb dating was tested on a range of dolomitic rocks of various origins from the Cambrian to Pliocene age – all of which are from well-constrained stratigraphic sections in Israel. We present imaging and chemical characterization techniques that provide useful information on interpreting the resulting U–Pb ages and discuss the complexity of in situ dolomite dating in terms of textural features that may affect the results. Textural examinations indicate zonation and mixing of different phases at the sub-millimeter scale (< 1 µm), and thus Tera–Wasserburg ages represent mixed dates of early diagenesis and some later epigenetic dolomitization event(s). We conclude that age mixing at the sub-millimeter scale is a major challenge in dolomite dating that needs to be further studied and note the importance of matrix-matched standards for reducing uncertainties of the dated material.

scholarly journals Highly sensitive and multiplexed in situ protein profiling with cleavable fluorescent streptavidin

2019 ◽  
Author(s):  
Renjie Liao ◽  
Diego Mastroeni ◽  
Paul D. Coleman ◽  
Jia Guo
Keyword(s):  
Signal Amplification ◽  
Individual Cell ◽  
Protein Detection ◽  
Protein Profiling ◽  
Detection Sensitivity ◽  
Layer By Layer ◽  
Protein Targets ◽  
Highly Sensitive ◽  
Wide Range

AbstractThe ability to perform highly sensitive and multiplexed in situ protein analysis is crucial to advance our understanding of normal physiology and disease pathogenesis. To achieve this goal, here we develop an approach using cleavable biotin conjugated antibodies and cleavable fluorescent streptavidin (CFS). In this approach, protein targets are first recognized by the cleavable biotin labeled antibodies. Subsequently, CFS is applied to stain the protein targets. Though layer-by-layer signal amplification using cleavable biotin conjugated orthogonal antibodies and CSF, the protein detection sensitivity can be enhanced by at least 10 fold, compared with the existing methods. After imaging, the fluorophores and the biotins unbound to streptavidin are removed by chemical cleavage. The leftover streptavidin is blocked by biotin. Upon reiterative analysis cycles, a large number of different proteins with a wide range of expression levels can be unambiguously detected in individual cell in situ.

scholarly journals U–Pb geochronology of epidote by LA–ICP–MS as a tool for dating hydrothermal-vein formation

2020 ◽  
Author(s):  
Veronica Peverelli ◽  
Tanya Ewing ◽  
Daniela Rubatto ◽  
Martin Wille ◽  
Alfons Berger ◽  
...  
Keyword(s):  
Inductively Coupled Plasma ◽  
A Priori ◽  
Swiss Alps ◽  
Hydrothermal Vein ◽  
Isotopic Compositions ◽  
Vein Formation ◽  
Icp Ms ◽  
Wide Range ◽  
Primary Reference

Abstract. Monoclinic epidote is a low-µ (µ = 283U / 204Pb) mineral occurring in a variety of geological environments, participating in many metamorphic reactions and stable throughout a wide range of pressure–temperature conditions. Despite containing fair amounts of U, its use as a U–Pb geochronometer has been hindered by the commonly high contents of initial Pb with isotopic compositions that cannot be assumed a priori. We present U–Pb geochronology of hydrothermal-vein epidote spanning a wide range of Pb (3.9–190 µg g−1), Th (0.009–38 µg g−1) and U (2.6–530 µg g−1) contents and with µ values between 7–510 from the Albula area (eastern Swiss Alps), from the Grimsel area (central Swiss Alps) and from the Heyuan fault (Guangdong province, China). The investigated epidote samples show appreciable fractions of initial Pb that vary to different extents. A protocol has been developed for in situ U–Pb dating of epidote by spot-analysis laser ablation inductively coupled plasma mass spectrometry (LA–ICP–MS) with a magmatic allanite as primary reference material. The suitability of the protocol and the reliability of the measured isotopic ratios have been ascertained by independent measurements of 238U / 206Pb and 207Pb / 206Pb ratios respectively by quadrupole and multicollector ICP–MS applied to epidote micro-separates digested and diluted in acids. For age calculation, we used the Tera–Wasserburg (207Pb / 206Pb–238U / 206Pb) diagram, which does not require corrections for initial Pb and provides the initial 207Pb / 206Pb ratio if all intra-sample analyses are co-genetic. Petrographic and microstructural data indicate that the calculated ages date the crystallization of vein epidote from a hydrothermal fluid and that the U–Pb system was not reset to younger ages by later events. Vein epidote from the Albula area formed in the Paleocene (62.7 ± 3.0 Ma) and is related to Alpine greenschist-facies metamorphism. The Miocene (19.1 ± 4.0 Ma and 16.9 ± 3.7 Ma) epidote veins from the Grimsel area formed during the Handegg phase (22–17 Ma) of the Alpine evolution of the Aar Massif. Identical initial 207Pb / 206Pb ratios reveal homogeneity in Pb isotopic compositions of the fluid across ca. 200 m. Vein epidote from the Heyuan fault is Cretaceous in age (108.1 ± 8.4 Ma) and formed during the early movements of the fault. In situ U–Pb analyses of epidote returned reliable ages of otherwise undatable epidote-quartz veins. The Tera–Wasserburg approach has proven pivotal for in situ U–Pb dating of epidote and the decisive aspect for low age uncertainties is the variability in intra-sample initial Pb fractions.

In situ determination of precise stable Si isotope ratios by UV-femtosecond laser ablation high-resolution multi-collector ICP-MS

2008 ◽  
Vol 249 (1-2) ◽  
pp. 155-166 ◽  
Author(s):  
Jérôme Chmeleff ◽  
Ingo Horn ◽  
Grit Steinhoefel ◽  
Friedhelm von Blanckenburg
Keyword(s):  
Laser Ablation ◽  
High Resolution ◽  
Femtosecond Laser ◽  
Femtosecond Laser Ablation ◽  
Isotope Ratios ◽  
Icp Ms ◽  
Si Isotope

scholarly journals High-Resolution Sea Surface Temperature and Salinity in the Global Ocean from Raw Satellite Data

2019 ◽  
Vol 11 (19) ◽  
pp. 2191 ◽  
Author(s):  
Encarni Medina-Lopez ◽  
Leonardo Ureña-Fuentes
Keyword(s):  
Neural Network ◽  
High Resolution ◽  
Satellite Data ◽  
Google Earth ◽  
Sea Surface ◽  
Global Ocean ◽  
The Neural Network ◽  
Wide Range ◽  
Sentinel 2

The aim of this work is to obtain high-resolution values of sea surface salinity (SSS) and temperature (SST) in the global ocean by using raw satellite data (i.e., without any band data pre-processing or atmospheric correction). Sentinel-2 Level 1-C Top of Atmosphere (TOA) reflectance data is used to obtain accurate SSS and SST information. A deep neural network is built to link the band information with in situ data from different buoys, vessels, drifters, and other platforms around the world. The neural network used in this paper includes shortcuts, providing an improved performance compared with the equivalent feed-forward architecture. The in situ information used as input for the network has been obtained from the Copernicus Marine In situ Service. Sentinel-2 platform-centred band data has been processed using Google Earth Engine in areas of 100 m × 100 m. Accurate salinity values are estimated for the first time independently of temperature. Salinity results rely only on direct satellite observations, although it presented a clear dependency on temperature ranges. Results show the neural network has good interpolation and extrapolation capabilities. Test results present correlation coefficients of 82 % and 84 % for salinity and temperature, respectively. The most common error for both SST and SSS is 0.4 ∘ C and 0 . 4 PSU. The sensitivity analysis shows that outliers are present in areas where the number of observations is very low. The network is finally applied over a complete Sentinel-2 tile, presenting sensible patterns for river-sea interaction, as well as seasonal variations. The methodology presented here is relevant for detailed coastal and oceanographic applications, reducing the time for data pre-processing, and it is applicable to a wide range of satellites, as the information is directly obtained from TOA data.

Coupling thermodynamic modeling and high-resolution in situ LA-ICP-MS monazite geochronology: evidence for Barrovian metamorphism late in the Grenvillian history of southeastern Ontario

2014 ◽  
Vol 108 (6) ◽  
pp. 741-758 ◽  
Author(s):  
Travis McCarron ◽  
Fred Gaidies ◽  
Christopher R. M. McFarlane ◽  
R. Michael Easton ◽  
Peter Jones
Keyword(s):  
High Resolution ◽  
Thermodynamic Modeling ◽  
Icp Ms ◽  
History Of

scholarly journals Measurement of three-dimensional displacement field in piled embankments using synchrotron X-ray tomography

2019 ◽  
Vol 56 (6) ◽  
pp. 885-892 ◽  
Author(s):  
Louis King ◽  
Abdelmalek Bouazza ◽  
Anton Maksimenko ◽  
Will P. Gates ◽  
Stephen Dubsky
Keyword(s):  
High Resolution ◽  
Imaging Techniques ◽  
Three Dimensional ◽  
Physical Models ◽  
Scale Model ◽  
Small Scale ◽  
Full Field ◽  
X Ray ◽  
Wide Range ◽  
Piled Embankments

The measurement of displacement fields by nondestructive imaging techniques opens up the potential to study the pre-failure mechanisms of a wide range of geotechnical problems within physical models. With the advancement of imaging technologies, it has become possible to achieve high-resolution three-dimensional computed tomography volumes of relatively large samples, which may have previously resulted in excessively long scan times or significant imaging artefacts. Imaging of small-scale model piled embankments (142 mm diameter) comprising sand was undertaken using the imaging and medical beamline at the Australian Synchrotron. The monochromatic X-ray beam produced high-resolution reconstructed volumes with a fine texture due to the size and mineralogy of the sand grains as well as the phase contrast enhancement achieved by the monochromatic X-ray beam. The reconstructed volumes were well suited to the application of digital volume correlation, which utilizes cross-correlation techniques to estimate three-dimensional full-field displacement vectors. The output provides insight into the strain localizations that develop within piled embankments and an example of how advanced imaging techniques can be utilized to study the kinematics of physical models.

Development of Wet Environmental TEM (Wet-ETEM) for In Situ Studies of Liquid-Catalyst Reactions on the Nanoscale

2002 ◽  
Vol 8 (1) ◽  
pp. 21-28 ◽  
Author(s):  
Pratibha L. Gai
Keyword(s):  
Biological Sciences ◽  
Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
High Resolution ◽  
Transmission Electron ◽  
Wide Range ◽  
Environmental Tem ◽  
Nanoscale Imaging ◽  
Solution Gas

We present the development of in situ wet environmental transmission electron microscopy (Wet-ETEM) for direct probing of controlled liquid–catalyst reactions at operating temperatures on the nanoscale. The first nanoscale imaging and electron diffraction of dynamic liquid hydrogenation and polymerization reactions in the manufacture of polyamides reported here opens up new opportunities for high resolution studies of a wide range of solution–solid and solution–gas–solid reactions in the chemical and biological sciences.

scholarly journals Radiology for Maxillofacial Surgeons: The Essentials

2021 ◽  
pp. 121-169
Author(s):  
Shyamsundar K. Joshi ◽  
Annie I. Kochuveettil
Keyword(s):  
High Resolution ◽  
Imaging Techniques ◽  
Maxillofacial Surgery ◽  
Vital Role ◽  
Maxillofacial Region ◽  
Patient Pathways ◽  
Wide Range ◽  
Core Concepts ◽  
Current Scenario ◽  
Investigative Technique

AbstractThe current scenario of radiological imaging of the maxillofacial region is a far cry from its humble beginnings. Rapid strides have been made over the years, with Radiology having made an immense impact on the practice of maxillofacial surgery. These advances in imaging, play a vital role not only in the diagnosis of maxillofacial disease conditions but also in the planning and implementation of appropriate and timely treatment. Since Radiology has a crucial role to play in the practice of maxillofacial surgery it is essential that a MFS should have basic understanding of the core concepts of different imaging techniques, their similarities and differences and should also be able to comprehend how imaging helps both diagnosing the clinical condition of a patient as well as management of the same.Chest Radiography and High-Resolution Ultrasound of the cheek are two imaging techniques, that are both useful and of interest to the MFS and so have been discussed in elaboration. Chest radiographs are one of the imaging investigations most frequently requested for and is of prime importance in many patient pathways. High resolution ultrasound too has a wide range of applications in the maxillofacial region, of which cheek imaging is of paramount importance. There being a paucity in existing literature on this newer investigative technique, this writeup is aimed both at creating awareness about it among maxillofacial surgeons and also at conveying the important role it plays in the management of MFS patients.

scholarly journals High-resolution inventory to capture glacier disintegration in the Austrian Silvretta

2021 ◽  
Author(s):  
Andrea Fischer ◽  
Bernd Seiser ◽  
Kay Helfricht ◽  
Martin Stocker-Waldhuber
Keyword(s):  
High Resolution ◽  
Spatial Resolution ◽  
Ice Age ◽  
Surface Elevation ◽  
Glacier Changes ◽  
Wide Range ◽  
Elevation Data ◽  
Glacier Ice ◽  
Geodetic Mass Balance

Abstract. Eastern Alpine glaciers have been receding since the LIA maximum, but the majority of glacier margins could be delineated unambiguously for the last Austrian glacier inventories. Even debris-covered termini, changes in slope, colour or the position of englacial streams enabled at least an in situ survey of glacier outlines. Today the outlines of totally debris-covered glacier ice are fuzzy and raise the theoretical discussion if these glaciogenic features are still glaciers and should be part of the respective inventory – or part of an inventory of transient cryogenic landforms. A new high-resolution glacier inventory (area and surface elevation) was compiled for the years 2017 and 2018 to quantify glacier changes for the Austrian Silvretta region in full. Glacier outlines were mapped manually, based on orthophotos and elevation models and patterns of volume change of 1 to 0.5 m spatial resolution. The vertical accuracy of the DEMs generated from 6 to 8 LiDAR points per m2 is in the order of centimetres. calculated in relation to the previous inventories dating from 2004/2006 (LiDAR), 2002, 1969 (photogrammetry) and to the Little Ice Age maximum extent (moraines). Between 2004/06 and 2017/2018, the 46 glaciers of the Austrian Silvretta lost −29 ± 4 % of their area and now cover 13.1 ± 0.4 km2. This is only 32 ± 2 % of their LIA extent of 40.9 ± 4.1 km2. The area change rate increased from −0.6 %/year (1969–2002) to −2.4 %/year (2004/06–2017/18). The annual geodetic mass balance showed a loss increasing from −0.2 ± 0.1 m w.e./year (1969–2002) to –0.8 m ±0.1 w.e./year (2004/06–2017/18) with an interim peak in 2002–2004/06 at −1.5 ± 0.7 m w.e./year. Identifying the glacier outlines offers a wide range of possible interpretations of former glaciers that have evolved into small and now totally debris-covered cryogenic geomorphological structures. Only the patterns and amounts of volume changes allow us to estimate the area of the buried glacier remnants. To keep track of the buried ice and its fate, and to distinguish increasing debris cover from ice loss, we recommend inventory repeat frequencies of three to five years and surface elevation data with a spatial resolution of one metre.

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