Review: Effects of soil organic matters on Fenton reaction

2021 ◽  
Vol 1 (1) ◽  
Author(s):  
Somayeh Akbari ◽  
Segaheyedeh P Jalilian. Ahmadkalaei

Heterogeneous Fenton reaction has been widely known to destruct organic contaminants, in its basic application definition, by applying one or more Fe2+ or Fe3+-containing source(s) with hydrogen peroxide for producing the strong hydroxyl radicals. Comprehensive experiments in the Fenton reaction area have been done for over 100 years, and considerable progress has been achieved. Achieved removal efficiency by Fenton reaction is usually studied by evaluating the effects of parameters such as initial reagents concentrations, pH, and soil organic matter (SOM). Among them, the results related to the effect of SOM sometimes seem conflicting, as its effects are reported either promoting or inhibiting and sometimes both. Reaction parameters such as initial reagents and pH are the most studied and effective ones in evaluating the effects of SOM on Fenton reaction for organic pollutants. This review intends to give a comprehensive survey of the impact of SOM on the Fenton reaction, with the focus on the heterogeneous Fenton reaction in the soil and solid. For this purpose, the general effects of pH and initial reagents on the Fenton reaction are reviewed in the beginning. Keywords: Fenton reaction, Hydrogen peroxide, pH, Soil organic matter (SOM), The removal efficiency

10.52319/1001 ◽  
2021 ◽  
Vol 1 (1) ◽  
Author(s):  
Somayeh Akbari ◽  
Segaheyedeh P Jalilian. Ahmadkalaei

Heterogeneous Fenton reaction has been widely known to destruct organic contaminants, in its basic application definition, by applying one or more Fe2+ or Fe3+-containing source(s) with hydrogen peroxide for producing the strong hydroxyl radicals. Comprehensive experiments in the Fenton reaction area have been done for over 100 years, and considerable progress has been achieved. Achieved removal efficiency by Fenton reaction is usually studied by evaluating the effects of parameters such as initial reagents concentrations, pH, and soil organic matter (SOM). Among them, the results related to the effect of SOM sometimes seem conflicting, as its effects are reported either promoting or inhibiting and sometimes both. Reaction parameters such as initial reagents and pH are the most studied and effective ones in evaluating the effects of SOM on Fenton reaction for organic pollutants. This review intends to give a comprehensive survey of the impact of SOM on the Fenton reaction, with the focus on the heterogeneous Fenton reaction in the soil and solid. For this purpose, the general effects of pH and initial reagents on the Fenton reaction are reviewed in the beginning


2018 ◽  
Vol 8 (1) ◽  
Author(s):  
Kuan-Ting Lee ◽  
Yu-Jen Lu ◽  
Shao-Chieh Chiu ◽  
Wen-Chi Chang ◽  
Er-Yuan Chuang ◽  
...  

2020 ◽  
Vol 23 (3) ◽  
pp. 117-124
Author(s):  
Dušan Šrank ◽  
Vladimír Šimanský

The effort to achieve the sustainable farming system in arable soil led to the intensive search for a new solution but an inspiration can also be found in the application of traditional methods of soil fertility improvement as it is shown in numerous examples in history. Recently many scientific teams have focused their attention on the evaluation of biochar effects on soil properties and crop yields. Since there are a lot of knowledge gaps, especially in explanations how biochar can affect soil organic matter (SOM) and humus substances, we aimed this study at the solution of these questions. Therefore, the objective of the experiment was to evaluate the impact of two biochar substrates (B1 – biochar blended with sheep manure, and B2 – biochar blended with sheep manure and the residue from the biogas station) at two rates (10 and 20 t ha-1) applied alone or in combination with mineral fertilizers (Urea was applied in 2018, at rate 100 kg ha-1, and Urea at rate 100 kg ha-1 + AMOFOS NP 12-52 at 100 kg ha-1 were applied in 2019) on the quantity and quality of SOM and humus of sandy soil (Arenosol, Dolná Streda, Slovakia). The results showed that application of the biochar substrates together with mineral fertilizers (MF) had more pronounced effect on the organic matter mineralization in the sandy soil which resulted in low accumulation of soil organic carbon (Corg) and labile carbon compared to biochar substrates treatments without MF. The share of humic substances in Corg significantly decreased by 16, 50, 16 and 24% in B1 at 10 t ha-1, B1 at 20 t ha-1, B2 at 10 t ha-1 and B2 at 20 t ha-1 treatments, respectively, compared to the control. A similar tendency was observed for biochar substrates treatments + MF, compared to MF control. The carbon content of humic substances (CHS) was equal to 4.40 – 5.80 g kg-1 and the biochar substrates had statistically significant influence on CHS content. On average, there was a smaller decrease of CHS in B1 at rate 10 t ha-1 than at rate 20 t ha-1 and no effect of B2 compared to control. The carbon content of fulvic acid (CFA) was 9% higher in B1 at 10 t ha-1, and 20 t ha-1, 47% higher in B2 at 10 t ha-1 and 17% higher in B2 at 20 t ha-1 compared to control. As a result of biochar substrates + MF application, the reduction in CFA was observed. The results showed a decrease of CHA : CFA ratio with association to biochar substrates alone application compared to control on one hand, and a wider of CHA : CFA ratio in biochar substrates + MF treatments in comparison to MF control on the other hand. Humus stability was increased in biochar substrates alone treatments compared to control, on the other hand, compared to MF control, the application of biochar substrates + MF resulted in a lower humus stability.


2018 ◽  
Vol 5 (8) ◽  
pp. 1943-1950 ◽  
Author(s):  
Xike Tian ◽  
Xiaoyu He ◽  
Yulun Nie ◽  
Zhaoxin Zhou ◽  
Chao Yang ◽  
...  

Atomically dispersed FeCp anchored on Sep was prepared for efficient photo-Fenton degradation of OFX with good stability.


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