Almost any single one of the techniques employed in the investigations suffices to reveal the elaborateness of the deception which was perpetrated at Piltdown. The anatomical examination, the tests for fluorine and nitrogen bear particularly good witness to this; even the radio-activity results taken alone, led the physicists to remark on the ‘great range of activity shown by specimens from this one little site’; ‘it is difficult to avoid the conclusion that the different bones in the Piltdown assemblage have had very different geological and chemical histories’. We have merely to take account of the stained condition of the whole assemblage, to realize the thoroughness of the fraud. From the Vandyke brown colour of the unnaturally abraded canine we infer with certainty that it was deliberately ‘planted’. The superficiality of the iron impregnation, combined with the chromium, tells as much as regards the orang jaw. And it is this iron-staining which finally shows that the rest, human and animal, was without doubt, all ‘planted’. The iron-staining has two peculiar features. It seems probable that ferric ammonium sulphate (iron alum) was the salt employed. This salt is slightly acid. The peculiarity of this salt (and, indeed, of any acid sulphate) is that in bone which contains little organic matter such as the cranium of Piltdown I, or Piltdown II, the beaver bones and hippo teeth, it brings about a detectable change in the crystal structure of the bone. In the apatite in which the calcium of the bone is held, the phosphate is replaced by sulphate to form gypsum. This change is quite unnatural, for neither gypsum nor sufficient sulphate occur in the gravels at Piltdown to bring it about. So the iron-sulphate-staining is an integral part of the forger’s necessary technique. He also used chromium compounds to aid the iron-staining probably because he thought it would assist the production of iron oxide. Chromium compounds are oxidizing. The basic strategy underlying the Piltdown series of forgeries now seems reasonably clear. Two main elements in the plan taken together explain nearly all the features of the affair quite satisfactorily.
Pre- and post-pyrolysis effects on iron impregnation of ultrasound pre-treated softwood biochar for potential catalysis applications
