scholarly journals PETROGENESIS, MAJOR OXIDES AND TRACE ELEMENTS GEOCHEMISTRY OF MIGMATITE IN AJUBA, KWARA STATE, NIGERIA

2021 ◽  
Vol 2 (2) ◽  
pp. 20-32
Author(s):  
A. D. Adedoyin ◽  
A. G. Atat ◽  
J. G. Atat

Petrogenesis, major oxides and trace elements geochemical study was carried out on migmatite in Ajuba. The study area is located on Latitudes 8° 05'N and 8°13'N and Longitudes 5°23'E and 5°30'E. Five rock samples were taken from the migmatite outcrops and used for petrographic and geochemical analyses. The geochemical analysis was done using X-ray Fluorescence Spectrometer technique. The dominant rock type is migmatite; gneiss and granite outcrops were also found in sparse distribution.  Ptygmatic folds, which constitute the palaeosome, is the common structure observed on the migmatite rock. The petrographic analysis shows that the migmatite consists of quartz, biotite, plagioclase, hornblende and microcline. The major oxides analysis indicates SiO2 as the dominant oxide with concentration range values (70.71 wt. % - 79.32 wt. %) and average of 74.80 wt. %. Al2O3 (14.98 wt. % - 16.44 wt. %, average: 15.70 wt. %) and Fe2O3 (9.10 wt. % - 15.41 wt. %, average: 12.39 wt. %), K2O (6.67 wt. % - 8.86 wt. %, average: 7.50 wt. %) and CaO (0.49 Wt. % - 4.64 wt. %. average: 2.73 wt. %). P2O5, MnO and TiO2 are less than 1.0 wt. %. The trace elements analysis indicates the concentration distributions: Rb (0.11-0.15 ppm, average 0.13 ppm), Co (0.04-0.17 ppm, average 0.10 ppm). Trace elements ˂ 0.10 ppm are Zn, W, Ni, Cu, V and Pb. From the petrographic and geochemical assessment, the petrogenesis of the migmatite has silica-rich igneous parentage. Moreover, the plots of SiO2-CaO and K2O-SiO2 placed the migmatite on the “upper boundary field of Francisian Greywacke” protolith and Shoshonite series, respectively.

2019 ◽  
Vol 70 (3) ◽  
pp. 382 ◽  
Author(s):  
Nidia I. Tobón Velázquez ◽  
Mario Rebolledo Vieyra ◽  
Adina Paytan ◽  
Kyle H. Broach ◽  
Laura M. Hernández Terrones

The aim of the study is to determine the distribution of trace and major elements in the water and in the sediments of the south part of the Bacalar Lagoon and to identify the sources of the trace elements and their changes over time. The western part of the lagoon water column is characterised by high concentrations of Ca2+, HCO3– and Sr2+, derived from groundwater input. In contrast, the eastern part of the lagoon is characterised by high concentrations of Mg2+, Na+ and Cl–. The lagoon is not affected by present-day seawater intrusion. Water column and sediment geochemical analyses performed in Bacalar Lagoon show clear spatial distribution of different parameters. The saturation index of the water column indicates three main groups: (1) a zone oversaturated with regard to aragonite, calcite and dolomite; (2) an undersaturated area where all three minerals are dissolving; and (3) an area with calcite equilibrium and undersaturation with regard to the other minerals. Herein we present the first measurements of trace element (Ba2+, Mn2+, K+, Ni2+, Zn2+) concentrations in carbonates obtained from sediments in Bacalar Lagoon. In order to evaluate whether the trace elements are derived from natural or anthropogenic sources, four pollution indices were calculated. The results confirmed that Bacalar Lagoon sediments are not contaminated with Ni2+, K+, Mn2+ and Ba2+, and that the Zn2+ seems to have a predominantly anthropogenic origin.


2009 ◽  
Vol 60 (6) ◽  
pp. 1303-1316 ◽  
Author(s):  
Faruque Ahmed ◽  
M. Hawa Bibi ◽  
Hiroaki Ishiga ◽  
Takehiko Fukushima ◽  
Teruyuki Maruoka

2015 ◽  
Vol 45 (1) ◽  
pp. 127-141 ◽  
Author(s):  
Hermínio Arias Nalini Júnior ◽  
Rômulo Machado ◽  
Essaid Bilal

The Urucum suite (582 ± 2 Ma, zircon U-Pb age), situated in the Mid-Rio Doce Valley, eastern part of Minas Gerais State, is characterized by elongated, NW-SE and N-S trending granitic massifs associated with the Conselho Peña-Resplendor high-angle shear zone. It corresponds to a syn to late collisional magmatism that presents dominant solid-state foliation. Four facies are distinguished within the Urucum suite: (i) a porphyritic (Urucum); (ii) a medium- to coarse nequigranular (Palmital); (iii) a tourmaline-bearing; and (iv) a pegmatitic facies. These facies are peraluminous, with alumina saturation index varying from 0.98 to 1.38. SiO2 contents vary from 70.7 to 73.7 wt%, with K2O values ranging from 3.5 to 5.7 wt%, Na2O from 1.9 to 4.4 wt%, MgO from 0.6 to 1.2 wt%, and CaO from 0.3 to 0.9%. Harker-type diagrams show rather continuous trends from the less-evolved Urucum facies to the more evolved tourmaline-bearing and pegmatitic facies. The behavior of several major oxides and trace elements (Fe2O3, MgO, MnO, CaO, TiO2, Al2O3, K2O, Rb and Ba) reflects the role played by fractionation of ferromagnesian minerals, feldspars and accessory minerals. Initial Sr87/Sr86 ratios vary from 0.711 to 0.716, with εNd (580 Ma) values between -7.4 to -8.2, and Sm-Nd TDM model ages ranging from 2290 to 1840 Ma.


2015 ◽  
Vol 175 ◽  
pp. 212-217 ◽  
Author(s):  
José Tiago P. Barbosa ◽  
Clarissa M.M. Santos ◽  
Vanessa N. Peralva ◽  
Erico M.M. Flores ◽  
Mauro Korn ◽  
...  

2015 ◽  
Vol 45 (1) ◽  
pp. 79-93 ◽  
Author(s):  
Saulo Gobbo Menezes ◽  
Rogério Guitarrari Azzone ◽  
Gaston Eduardo Enrich Rojas ◽  
Excelso Ruberti ◽  
Renata Cagliarani ◽  
...  

The question of whether the antecryst assemblage affects the bulk composition of lamprophyre dykes, and could be responsible for the compositional zonation between their centers and borders is addressed through a detailed study involving four monchiquite and camptonite dykes (basanites and tephrites) representative of the Arco de Ponta Grossa and Serra do Mar alkaline provinces. In them, antecrysts are interpreted as early-crystallized minerals that are no longer in equilibrium with their host-liquid, albeit still linked to the same magmatic system. They represent recycled crystals of earlier stages of the magmatic system at depth. The antecryst microtextures, such as zoned clinopyroxene megacrysts (augite cores and titanaugite rims) with partly corroded cores, olivine crystals with corroded rims surrounded by biotite coronas, chrome-spinel inclusions in clinopyroxene and olivine megacryst cores, and titanomagnetite crystals surrounded by biotite coronas, suggest chemical re-equilibrium with the matrix. The greatest antecryst cargo in these dykes is found in their centers. After subtracting the antecryst volume from the center analyses of each body, the calculated compositions are very similar to the border analyses. The mafic antecryst cargo of each occurrence proportionally leads to enrichment of MgO, FeO, TiO2, CaO, compatible trace elements (Cr, Ni and Co), and depletion of SiO2, K2O, Na2O, Al2O3 and incompatible trace elements (Ba, Sr and REE). The whole-rock geochemical analyses of each dyke represent the combination of accumulated crystals and melt. The compositional zonation of the studied dykes is associated with the antecryst cargo rather than different magmatic pulses.


2014 ◽  
Vol 2014 ◽  
pp. 1-7 ◽  
Author(s):  
Bo Gao ◽  
Xin Wei ◽  
Huaidong Zhou ◽  
Jin Lu ◽  
Hong Hao ◽  
...  

A geochemical study of Three Gorges Reservoir (TGR) sediments was carried out to analyze the concentrations, distribution, accumulation, and potential sources of the seldom monitored trace elements (SMTEs). The mean concentrations of Li, B, Be, Bi, V, Co, Ga, Sn, Sb, and Tl were 47.08, 2.47, 59.15, 0.50, 119.20, 17.83, 30.31, 3.25, 4.14, and 0.58 mg/kg, respectively. The concentrations of total SMTEs, together with their spatial distribution, showed that the SMTEs were mainly due to anthropogenic inputs in the region of TGR. The assessment by Geoaccumulation Index indicates that Tl, Be, V, Co, and Fe are at the unpolluted level; Bi, Li, Ga, and Sn were at the “uncontaminated to moderately contaminated” level. However, B was classified as “moderately contaminated” level and Sb was ranked as “strongly contaminated” level. The pollution level of the SMTEs is Sb>B>Bi>Li>Ga>Sn>Tl>Be>V>Co>Fe. The results of Correlation Analysis and Principal Component Analysis indicated Be, V, Co, Ga, Sn, Tl, Bi, and Fe in sediments have a natural source. B and Li were positively correlated with each other and mainly attributed into similar anthropogenic input. In addition, Sb has less relationship with other SMTEs, indicating that Sb has another kind of anthropogenic source.


2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
Elarina N. Dkhar ◽  
Paul S. Dkhar ◽  
Jasha Momo H. Anal

Determination of the certain major and trace elements was carried out in drinking water supply scheme in three districts of Meghalaya. This work aims to identify trends resulting in the deterioration of drinking water which is also a potential source of environmental contaminants. About 50 samples, each from one district, were collected both from the source and various tanks and tap. The elements determined are Li, Na, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Rb, Ag, Au, Pb, Cd, Se, Ca, K, and Mg. The pH is slightly lower than neutral pH of 7 while the turbidity is very high even after treatment. The concentrations of Ca and Mg are found to be deficient. The elements Cr, Fe, Co, Ni, Zn, Mo, and Pb decrease after treatment while Mn, Cu, and Cd increase slightly after treatment. Se concentration is found to be much higher than expected. The results were compared with the standard recommendation values for the quality of drinking water. This study provides a general indication of where water-quality constituent concentrations met or exceeded water-quality standards and the data presented in this report will be useful from public health point of view.


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