Optimization of Zinc Ions Removal by Modified Phoenix Dactylifera L. Seeds Using Response Surface Methodology

2019 ◽  
Vol 41 (1) ◽  
pp. 78-78
Author(s):  
Ainy Hafeez Ainy Hafeez ◽  
Syed Mohsin Ali Kazmi Syed Mohsin Ali Kazmi ◽  
Muhammad Sulaiman Muhammad Sulaiman ◽  
Chaudhry Haider Ali and Nadeem Feroze Chaudhry Haider Ali and Nadeem Feroze

The current study investigates the role of Phoenix Dactylifera L. (date palm) seeds as an effective biosorbent for removing Zn+2, a toxic heavy metal pollutant usually found in the waste streams of industries like fertilizer, mining and galvanizing etc. Date palm seeds were washed, dried, crushed in 170-300 um and modified by acidic treatment (0.1 MHNO3). The effect of most important parameters i.e., pH (3.5-6.1), initial zinc ion concentration (5-100mg/l), biosorbent dosage (0.1-1g) and contact time (0.5-60sec) have been studied via design expert software (version 8.0.6) of response surface methodology. The Box-Bhenken Design (BBD) was used in Response Surface Methodology (RSM) for designing the experiments and a number of 29 experiments were run. The model suggested by the design expert software was quadratic as it had maximum R2- value (0.9235) which indicated that the predicted values of quadratic model were best fitted to the experimental values. The significance of the factors was indicated by Analysis of Variance (ANOVA). The results showed that the metal uptake increased by increasing initial zinc concentration and decreasing in biosorbent dosage and pH while the contact time had negligible effect on the response surface. The parameters were numerically optimized and the optimum input parameters obtained were pH = 3.52, initial zinc ion concentration = 59.11ppm, biosorbent dosage = 0.1g and contact time = 60min with a metal uptake of 26.84mg/g. Therefore, (Phoenix Dactylifera L.) seeds substantially removed zinc ions under optimum conditions.

LWT ◽  
2021 ◽  
Vol 140 ◽  
pp. 110816
Author(s):  
Ibrahim A. Almusallam ◽  
Isam A. Mohamed Ahmed ◽  
Elfadil E. Babiker ◽  
Fahad Y. Al Juhaimi ◽  
Gbemisola J. Fadimu ◽  
...  

2010 ◽  
Vol 121 (2) ◽  
pp. 627-633 ◽  
Author(s):  
Riadh Ben Salah ◽  
Kacem Chaari ◽  
Souhail Besbes ◽  
Naourez Ktari ◽  
Christophe Blecker ◽  
...  

2016 ◽  
Vol 42 (2) ◽  
pp. 33-43 ◽  
Author(s):  
Masoud Moradi ◽  
Mehdi Fazlzadehdavil ◽  
Meghdad Pirsaheb ◽  
Yadollah Mansouri ◽  
Touba Khosravi ◽  
...  

Abstract This research was conducted to study the adsorption of ammonium ions onto pumice as a natural and low-cost adsorbent. The physico-chemical properties of the pumice granular were characterized by X-ray diffraction (XRD), Fourier transforms infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). Modeling and optimization of a NH4+ sorption process was accomplished by varying four independent parameters (pumice dosage, initial ammonium ion concentration, mixing rate and contact time) using a central composite design (CCD) under response surface methodology (RSM). The optimum conditions for maximum removal of NH4+ (70.3%) were found to be 100 g, 20 mg/l, 300 rpm and 180 min, for pumice dosage, initial NH4+ ion concentration, mixing rate and contact time. It was found that the NH4+ adsorption on the pumice granular was dependent on adsorbent dosage and initial ammonium ion concentration. NH4+ was increased due to decrease the initial concentration of NH4 and increase the contact time, mixing rate and amount of adsorbent.


2019 ◽  
Vol 7 (3) ◽  
pp. 74 ◽  
Author(s):  
Fedia Ben Mefteh ◽  
Fakher Frikha ◽  
Amal Daoud ◽  
Ali Chenari Bouket ◽  
Lenka Luptakova ◽  
...  

To explore proteolytic activity of endophytic fungi inhabiting date palm roots, a Penicillium bilaiae isolate, displaying the highest level of protease production, has been recovered. Response surface methodology (RSM) was applied to optimize culture conditions for protease production by the fungus. Plackett-Burman design allowed for screening of variables effective in protease production. Results indicated that temperature, initial pH and glucose concentration dramatically affect protease yield. These factors were further optimized using a Box-Behnken design and RSM. A combination of initial pH (6.26), temperature (24.5 °C), glucose (13.75 g/L), NaNO3 (1.5 g/L), MgSO4 (0.2 g/L), KH2PO4 (0.5 g/L) and KCl (0.5 g/L) were optimum for maximum production of protease. A 1086-fold enhancement of protease production was gained after optimization. Biochemical properties of fungal protease including the effect of pH and temperature on the activity and the stability of proteolytic enzyme were determined. Moreover, the influence of carbon and nitrogen sources, metal ions, detergents as well as enzyme inhibitors was investigated. Our results highlighted that protease of Penicillium bilaiae isolate TDPEF30 could be considered as a promising candidate for industrial applications.


2020 ◽  
Vol 9 (1) ◽  
pp. 4
Author(s):  
Amin Mojiri ◽  
Maedeh Baharlooeian ◽  
Reza Andasht Kazeroon ◽  
Hossein Farraji ◽  
Ziyang Lou

Using microalgae to remove pharmaceuticals and personal care products (PPCPs) micropollutants (MPs) have attracted considerable interest. However, high concentrations of persistent PPCPs can reduce the performance of microalgae in remediating PPCPs. Three persistent PPCPs, namely, carbamazepine (CBZ), sulfamethazine (SMT) and tramadol (TRA), were treated with a combination of Chaetoceros muelleri and biochar in a photobioreactor during this study. Two reactors were run. The first reactor comprised Chaetoceros muelleri, as the control, and the second reactor comprised Chaetoceros muelleri and biochar. The second reactor showed a better performance in removing PPCPs. Through the response surface methodology, 68.9% (0.330 mg L−1) of CBZ, 64.8% (0.311 mg L−1) of SMT and 69.3% (0.332 mg L−1) of TRA were removed at the initial concentrations of MPs (0.48 mg L−1) and contact time of 8.1 days. An artificial neural network was used in optimising elimination efficiency for each MP. The rational mean squared errors and high R2 values showed that the removal of PPCPs was optimised. Moreover, the effects of PPCPs concentration (0–100 mg L−1) on Chaetoceros muelleri were studied. Low PPCP concentrations (<40 mg L−1) increased the amounts of chlorophyll and proteins in the microalgae. However, cell viability, chlorophyll and protein contents dramatically decreased with increasing PPCPs concentrations (>40 mg L−1).


Energies ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 595
Author(s):  
Mahir Faris Abdullah ◽  
Rozli Zulkifli ◽  
Hazim Moria ◽  
Asmaa Soheil Najm ◽  
Zambri Harun ◽  
...  

Impinging jets are considered to be a well-known technique that offers high local heat transfer rates. No correlation could be established in the literature between the significant parameters and the Nusselt number, and investigation of the interactions between the correlated factors has not been conducted before. An experimental analysis based on the twin impingement jet mechanism was achieved to study the heat transfer rate pertaining to the surface plate. In the current paper, four influential parameters were studied: the spacing between nozzles, velocity, concentration of Nano solution coating and nozzle-plate distance, which are considered to be effective parameters for the thermal conductivity and the heat transfer coefficient of TiO2 nanoparticle, an X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM) analysis were done, which highlighted the structure and showed that the nanosolution coated the surface homogenously. Moreover, a comparison was done for the experimental results with that of the predicted responses generated by the Design Expert software, Version 7 User’s Guide, USA. A response surface methodology (RSM) was employed to improve a mathematical model by accounting for a D-optimal design. In addition, the analysis of variance (ANOVA) was employed for testing the significance of the models. The maximum Nu of 91.47, where H = S = 1 cm; Reynolds number of 17,000, and TiO2 nanoparticle concentration of 0.5% M. The highest improvement rate in Nusselt was about 26%, achieved with TiO2 Nanoparticle, when S = 3 cm, H = 6 cm and TiO2 nanoparticle = 0.5 M. Furthermore, based on the statistical analysis, the expected values were found to be in satisfactory agreement with that of the empirical data, which was conducted by accounting for the proposed models’ excellent predictability. Multivariate approaches are very useful for researchers, as well as for applications in industrial processes, as they lead to increased efficiency and reduced costs, so the presented results of this work could encourage the overall uses of multivariate methods in these fields. Hypotheses: A comparison was done for the predicted responses generated by the Design Expert software with the experimental results and then studied to verify the following hypotheses: ► Preparation of three concentrations of TiO2 nanosolution was done and studied. ► The heat transfer rate could be increased by surface coating with TiO2 nanoparticle. ► The heat transfer could be improved by the impingement jet technique with suitable adjustments.


LWT ◽  
2021 ◽  
pp. 111762
Author(s):  
Ibrahim A. Almusallam ◽  
Isam A. Mohamed Ahmed ◽  
Elfadil E. Babiker ◽  
Fahad Y. Al-Juhaimi ◽  
Ali Saleh ◽  
...  

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