Properties and Characteristic of Amine-Polymer Blend Membrane

2019 ◽  
Vol 41 (2) ◽  
pp. 230-230
Author(s):  
Asim Mushtaq Asim Mushtaq ◽  
Hilmi Mukhtar and Azmi Mohd Shariff Hilmi Mukhtar and Azmi Mohd Shariff

Polymer blend technology has earned a significant position in the field of polymer science. Current membrane technology can easily and simply remove and separates carbon dioxide as pressure, temperature, costs, and energy requirements are low. There is also no corrosion problem from the straightforward process of removing CO2 from natural gas, especially in remote or offshore locations that are easily scaled up. However, glassy polymeric membranes suffer from a lack of permeability causing performance degradation and higher selectivity. Nevertheless, amine solutions are capable of purifying naturally acidic gas. Within this framework, the blending of the polysulfone (PSU) glassy polymer with amines such as diethanolamine (DEA), methyl diethanolamine (MDEA), and monoethanolamine (MEA) in a dimethylacetamide solvent, resulted in the development of flat sheet membranes with the desired properties. The findings showed good miscibility between PSU and amines blends, all the original functional groups were shown by FTIR. The synthesized amine polymer blend membrane were found to have homogenous surfaces and a packed bed sphere structure (PBSS) as shown by FESEM images. Furthermore the addition of different amine solution, have increased the size of PBSS due to incorporation of amine molecule into the sphere.

2017 ◽  
Vol 363 ◽  
pp. 384-391 ◽  
Author(s):  
Anne Freitag ◽  
Manfred Stamm ◽  
Leonid Ionov

2017 ◽  
Vol 8 (1) ◽  
Author(s):  
A. L. Ahmad ◽  
A. R. Sunarti ◽  
K. T. Lee ◽  
W. J. N. Fernando

The objective of this study was to investigate the potential process of the removal of carbon dioxide (CO2) from flue gases by using developed membrane gas absorption system. The experiments were performed in membrane gas absorption system consisted 0.45 μm pore size microporous polyvinylidenefluoride (PVDF) flat sheet membrane. Diethanolamine (DEA) solution was employed as the liquid absorbent. The operating parameters such as the gas and liquid flow rate were setup at 100 cm3/min and 25 cm3/min and liquid absorbent was at room temperature. The effect of DEA concentration was studied with variation in range 1 M to 5 M. In addition, the experiments were carried out with 20%, 40% and 100% gas ratio CO2 to N2. The results show that hydrophobic polymeric membranes such as PVDF can be efficiently used for gas absorption with optimized concentration of DEA.


2015 ◽  
Vol 3 (39) ◽  
pp. 19718-19727 ◽  
Author(s):  
Varij Panwar ◽  
Jin-Han Jeon ◽  
Gopinathan Anoop ◽  
Hyeon Jun Lee ◽  
Il-Kwon Oh ◽  
...  

An actuator based on a miscible [P(VDF-TrFE)]/PVP/PSSA polymer blend membrane shows a large actuation displacement and force at a low voltage of 1 V compared to those of commercial Nafion and PVDF based actuators.


1996 ◽  
Vol 29 (20) ◽  
pp. 6629-6633 ◽  
Author(s):  
R. M. Conforti ◽  
T. A. Barbari ◽  
M. E. Pozo de Fernandes

2014 ◽  
Vol 625 ◽  
pp. 701-703 ◽  
Author(s):  
Marjan Farnam ◽  
Hilmi Mukhtar ◽  
Azmi Mohd Shariff

Polymeric membranes are widely used for gas separation purposes but their performance is restricted by the upper bound trade-off discovered by Robeson in 1991. The polymeric membrane can be glassy, rubbery or a blend of these two polymers. This review paper discusses the properties of glassy polymer membranes and their performance in gas separation. The area of improvement for glassy membrane with development of mixed matrix membrane is also highlighted.


Membranes ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 47 ◽  
Author(s):  
Maryam Y. Ghadhban ◽  
Hasan Shaker Majdi ◽  
Khalid T. Rashid ◽  
Qusay F. Alsalhy ◽  
D. Shanthana Lakshmi ◽  
...  

In this work, a flat-sheet blend membrane was fabricated by a traditional phase inversion method, using the polymer blends poly phenyl sulfone (PPSU) and polyether sulfone (PES) for the ultrafiltration (UF) application. It was hypothesized that adding PES to the PPSU polymer blend would improve the properties of the PPSU membrane. The effect of the PES concentration on the blend membrane properties was investigated extensively. The characteristics of PPSU-PES blend membranes were investigated using atomic force microscopy (AFM), scanning electron microscopy (SEM), contact angle measure, and contaminant (dye) elimination efficiency. This study showed that PES clearly affected the structural formation of the blended membranes. A considerable increase in the average roughness (about 93%) was observed with the addition of 4% PES, with a higher mean pore size accompanied by a rise in the pores’ density on the surface of the membrane. The addition of up to 4% PES had a significant influence on the hydrophilic character of the PPSU-PES membrane, by lowering the value of the contact angle (CA) (i.e., to 56.9°). The performance of the PPSU-PES composite membranes’ UF performance was systematically investigated, and the membrane pure water permeability (PWP) was enhanced by 25% with the addition of 4% PES. The best separation removal factor achieved in the current investigation for dye (Drupel Black NT) was 96.62% for a PPSU-PES (16:4 wt./wt.%) membrane with a 50% feed dye concentration.


2020 ◽  
Vol MA2020-02 (35) ◽  
pp. 2263-2263
Author(s):  
Byungchan Hwang ◽  
Shoichi Kondo ◽  
Takamasa Kikuchi ◽  
Kazunari Sasaki ◽  
Akari Hayashi ◽  
...  

Ionics ◽  
2020 ◽  
Vol 26 (7) ◽  
pp. 3447-3458 ◽  
Author(s):  
P. Martina ◽  
R. Gayathri ◽  
M. Raja Pugalenthi ◽  
Guozhong Cao ◽  
Chaofeng Liu ◽  
...  

2019 ◽  
Vol 6 (11) ◽  
pp. 115336
Author(s):  
J B Arul Joseph Helen Therese ◽  
R Gayathri ◽  
K Selvakumar ◽  
M Ramesh Prabhu ◽  
P Sivakumar

Sign in / Sign up

Export Citation Format

Share Document