Ore Mineralogy, Geochemistry, and Dating (Re-Os, Ar-Ar) of the El Volcán Porphyry/Epithermal System, Maricunga Gold Belt, Northern Chile

2022 ◽  
Vol 117 (1) ◽  
pp. 25-55
Author(s):  
Stephanie Lohmeier ◽  
Bernd Lehmann ◽  
Albrecht Schneider ◽  
Andrew Hodgkin ◽  
Raymond Burgess
Keyword(s):  
Hydrothermal System ◽  
Volcanic Complex ◽  
Northern Chile ◽  
Bulk Rock ◽  
Mineral Assemblages ◽  
Ore Mineralogy ◽  
Arc Setting ◽  
Rock Column ◽  
Drill Holes ◽  
Ore Zones

Abstract The El Volcán gold project (8.9 Moz Au @ 0.71 g/t Au) is located in the Maricunga gold belt in northern Chile, on the flank of the large Cenozoic Copiapó Volcanic Complex. Precious metal mineralization is hosted in two zones (Dorado and Ojo de Agua) of (pervasively) altered Miocene porphyry intrusions and lava flows of andesitic to rhyolitic composition, and in breccias. The ore zones reflect an evolving magmatic-hydrothermal system with mineral assemblages of magnetite-ilmenite-pyrite-molybdenite (early), bornite-chalcopyrite-pyrite-rutile (stage I), chalcocite-chalcopyrite-enargite-fahlore-pyrite (stage II), and chalcopyrite-covellite-pyrite (stage III). Alteration is dominantly of Maricunga-style (illite-smectite-chlorite ± kaolinite), partly obscured by quartz-kaolinite-alunite ± illite ± smectite alteration. Powdery quartz-alunite-kaolinite alteration with native sulfur and cinnabar forms shallow steam-heated zones. Early K-feldspar ± biotite alteration is preserved only in small porphyry cores and in deep drill holes. Most gold is submicrometer size and is in banded quartz veinlets, which are characteristic of the Maricunga gold belt. However, some gold is disseminated in zones of pervasive quartz-kaolinite-alunite alteration, with and without banded quartz veinlets. Minor visible gold is related to disseminated chalcocite-chalcopyrite-enargite-fahlore-pyrite. The lithogeochemical database identifies a pronounced Au-Te-Re signature (>100× bulk crust) of the hydrothermal system. Molybdenum-rich bulk rock (100–400 ppm Mo) has an Re-Os age of 10.94 ± 0.17 Ma (2σ). 40Ar-39Ar ages on deep K-feldspar alteration and on alunite altered rock have the same age within error and yield a combined age of 11.20 ± 0.25 Ma (2σ). The formation of the El Volcán gold deposit took place during the establishment of the Chilean flat-slab setting in a time of increasing crustal thickness when hydrous magmas were formed in a mature arc setting. The vigorous nature of the hydrothermal system is expressed by abundant one-phase vapor fluid inclusions recording magmatic vapor streaming through a large rock column with a vertical extent of ≥1,500 m.

The occurrence of gold in Voia deposit, South Apuseni Mountains, Romania

2021 ◽  
Author(s):  
Elena-Luisa Iatan
Keyword(s):  
Iron Oxides ◽  
Base Metal ◽  
Mineral Assemblage ◽  
Native Gold ◽  
Metal Sulfides ◽  
Volcanic Complex ◽  
Apuseni Mountains ◽  
Base Metal Sulfides ◽  
Mineral Assemblages ◽  
Phyllic Alteration

<p>Voia deposit belongs to the Săcărâmb-Cetraș-Cordurea Miocene volcano-tectonic alignment of the South Apuseni Mountains, Romania. This large volcanic complex represents a Sarmatian-Pannonian magmatic-hydrothemal mega-system of around 5 km<sup>2</sup> with an estimated 3–4 Ma time-space evolution, consisting of seven andesitic volcanic structures grouped in a circle, three subvolcanic andesite-quartz porphyry microdiorite and associated porphyry Cu-Au(Mo), pyrite Ca-Mg skarns and epithermal Au-Ag-Pb-Zn-Cu mineralizations.</p><p>The mineral assemblages of alteration and mineralization processes belong to several mineralized zones on a vertical scale, according to sampling evidence and laboratory studies. HS products are found in the upper part of the structure (300-500 m), with dominant advanced and intermediate argillic alterations and sulfide-sulfate gold-poor veins (pyrite, marcasite, base metal sulfides, Fe-Ti oxides, vuggy quartz, alunite, gypsum, anhydrite). Within the 500-1200 m depth, the HS mineral assemblages gradually decrease in favor of IS and LS products. It is characterized by the coexistence of gold-rich LS assemblage (native gold, base metal sulfide, adularia, sericite-illite, chlorite, carbonates ± anhydrite veins), with the IS assemblage (iron oxides, chalcopyrite, pyrite, quartz, anhydrite). These assemblages overprint the HS mineral associations, resulting in a transition zone characterized by gold - pyrite - chalcopyrite - iron oxides - quartz - anhydrite mineral assemblage characteristic for HS and native gold - pyrite - base metal sulfides - carbonates - quartz mineral assemblage corresponding to IS+LS type.</p><p>Gold is present in all of the identified mineralization forms: porphyry-epithermal Cu-Au, epi-mesothermal carbonate veins with gold - base metal sulfides, quartz veins with pyrite - chalcopyrite - magnetite ± hematite ± anhydrite, anhydrite veins with base metal sulfides and sulfosalts, anhydrite veins with pyrite - anhydrite ± quartz, vuggy quartz (silica residue) with gold-poor pyrite veins and impregnations in porphyry systems.</p><p>Drilling core samples revealed that in Voia deposit, gold is concentrated in chalcopyrite (drills no. 7, 19, 37) along with pyrite - magnetite - hematite - quartz assemblage from the late potassic stage. The major amount of gold associated with chalcopyrite tends to be mainly submicroscopic. Pyrite from anhydrite veins of the early potassic stage ± phyllic alteration is relatively poor in gold (drills no. 1-6, 8-14). However, the highest gold contents are present in pentagonal dodecahedron pyrites (drills no. 33, 38, 39) of pyrite-chalcopyrite-magnetite ± hematite-quartz assemblage from late potassic stage ± phyllic alteration. Pyrite associated with magnetite from anhydrite veins tends to be poor in gold (drills no. 8, 11, 15, 28, 29). A carbonate vein containing gold-bearing base metal sulfides that was intercepted at 960,00-960,30m depth by drill no. 17 is one of the richest in gold.</p><p>Native gold occurs as fine inclusions in ore minerals (5-20 μm). Large irregular grains of native gold (>50 μm) appear at mineral boundaries and along the fissures. The gold color is bright yellow and has a measured Au:Ag ratio of 5:1, suggesting that native gold has been formed at a relatively high temperature.</p><p>Acknowledgments: This work was supported by two Romanian Ministry of Research and Innovation grants: PN-III-P4-ID-PCCF-2016-4-0014 and PN-III-P1-1.2-PCCDI-2017-0346/29.</p>

Porphyry Copper Discovery Beneath the Valeriano Lithocap, Chile

SEG Discovery ◽  
2016 ◽  
pp. 1-20
Author(s):  
Richard H. Sillitoe ◽  
Claudio Burgoa ◽  
David R. Hopper
Keyword(s):  
Gold Mineralization ◽  
Porphyry Copper ◽  
Northern Chile ◽  
Porphyry Copper Deposits ◽  
Copper Deposits ◽  
Alteration Zones ◽  
Copper Gold ◽  
Drill Holes

ABSTRACT Exploration for porphyry copper deposits beneath barren or poorly mineralized, advanced argillic lithocaps is becoming common­place; however, there have been few discoveries except in cases where the copper ± gold ± molybdenum mineralization has been partly exposed, typically as a result of partial lithocap erosion. At Valeriano, in the high Andes of northern Chile, completely concealed Miocene porphyry copper-gold mineralization was recently discovered beneath a lithocap. Here, the results of the staged drilling program that led to the discovery are summarized, with emphasis on the key geologic, alteration, and mineralization features that provided guidance. The final deep drill holes of the 16-hole program cut well-defined advanced argillic and sericitic alteration zones before entering chalcopyrite ± bornite–bearing, potassic-altered porphyry, with grades of 0.7 to 1.2% Cu equiv, at depths of ~1,000 to >1,800 m.

The Westwood Deposit, Southern Abitibi Greenstone Belt, Canada: An Archean Au-Rich Polymetallic Magmatic-Hydrothermal System—Part II. Hydrothermal Alteration, Mineralization, and Geologic Model

2021 ◽  
Author(s):  
D. Yergeau ◽  
P. Mercier-Langevin ◽  
B. Dubé ◽  
V. McNicoll ◽  
S. E. Jackson ◽  
...  
Keyword(s):  
Hydrothermal System ◽  
Greenstone Belt ◽  
Massive Sulfide ◽  
Alteration Zone ◽  
Intrusive Complex ◽  
Calc Alkaline ◽  
Abitibi Greenstone Belt ◽  
The North ◽  
Vms Deposits ◽  
Ore Zones

Abstract The Westwood deposit, located in the Archean Doyon-Bousquet-LaRonde mining camp in the southern Archean Abitibi greenstone belt, contains 4.5 Moz (140 metric t) of gold. The deposit is hosted in the 2699–2695 Ma submarine, tholeiitic to calc-alkaline volcanic, volcaniclastic, and intrusive rocks of the Bousquet Formation. The deposit is located near the synvolcanic (ca. 2699–2696 Ma) Mooshla Intrusive Complex that hosts the Doyon epizonal intrusion-related Au ± Cu deposit, whereas several Au-rich volcanogenic massive sulfide (VMS) deposits are present east of the Westwood deposit. The Westwood deposit consists of stratigraphically stacked, contrasting, and overprinting mineralization styles that share analogies with both the intrusion-related and VMS deposits of the camp. The ore zones form three distinct, slightly discordant to stratabound corridors that are, from north (base) to south (top), the Zone 2 Extension, the North Corridor, and the Westwood Corridor. Syn- to late-main regional deformation and upper greenschist to lower amphibolite facies regional metamorphism affect the ore zones, alteration assemblages, and host rocks. The Zone 2 Extension consists of Au ± Cu sulfide (pyrite-chalcopyrite)-quartz veins and zones of disseminated to semimassive sulfides. The ore zones are spatially associated with a series of calc-alkaline felsic sills and dikes that crosscut the mafic to intermediate, tholeiitic to transitional, lower Bousquet Formation volcanic rocks. The metamorphosed proximal alteration consists of muscovite-quartz-pyrite ± gypsum-andalusite-kyanite-pyrophyllite argillic to advanced argillic-style tabular envelope that is up to a few tens of meters thick. The North Corridor consists of auriferous semimassive to massive sulfide veins, zones of sulfide stringers, and disseminated sulfides that are hosted in intermediate volcaniclastic rocks at the base of the upper Bousquet Formation. The Westwood Corridor consists of semimassive to massive sulfide lenses, veins, zones of sulfide stringers, and disseminated sulfides that are located higher in the stratigraphic sequence, at or near the contact between calc-alkaline dacite domes and overlying calc-alkaline rhyodacite of the upper Bousquet Formation. A large, semiconformable distal alteration zone that encompasses the North Corridor is present in the footwall and vicinity of the Westwood Corridor. This metamorphosed alteration zone consists of an assemblage of biotite-Mn garnet-chlorite-carbonate ± muscovite-albite. A proximal muscovite-quartz-chlorite-pyrite argillic-style alteration assemblage is associated with both corridors. The Zone 2 Extension ore zones and associated alteration are considered synvolcanic based on crosscutting relationships and U-Pb geochronology and are interpreted as being the distal expression of an epizonal magmatic-hydrothermal system that is centered on the upper part of the synvolcanic Mooshla Intrusive Complex. The North and Westwood corridors consist of bimodal-felsic Au-rich VMS-type mineralization and alteration produced by the convective circulation of modified seawater that included a magmatic contribution from the coeval epizonal Zone 2 Extension magmatic-hydrothermal system. The Westwood Au deposit represents one of the very few documented examples of an Archean magmatic-hydrothermal system—or at least of such systems formed in a subaqueous environment. The study of the Westwood deposit resulted in a better understanding of the critical role of magmatic fluid input toward the formation of Archean epizonal intrusion-related Au ± Cu and seafloor/subseafloor Au-rich VMS-type mineralization.

Geochemistry of gas and water discharge from the magmatic-hydrothermal system of Guallatiri volcano, northern Chile

2020 ◽  
Vol 82 (7) ◽  
Author(s):  
Manuel Inostroza ◽  
Franco Tassi ◽  
Felipe Aguilera ◽  
José Pablo Sepúlveda ◽  
Francesco Capecchiacci ◽  
...  
Keyword(s):  
Hydrothermal System ◽  
Water Discharge ◽  
Northern Chile

The great escape: Petrogenesis of low-silica volcanism of Pliocene to Quaternary age associated with the Altiplano-Puna Volcanic Complex of northern Chile (21°10′-22°50′S)

Lithos ◽  
2019 ◽  
Vol 346-347 ◽  
pp. 105162 ◽  
Author(s):  
Osvaldo González-Maurel ◽  
Petrus le Roux ◽  
Benigno Godoy ◽  
Valentin R. Troll ◽  
Frances M. Deegan ◽  
...  
Keyword(s):  
Volcanic Complex ◽  
Northern Chile

The ’Little’ Fish Canyon Tuff in Romania: Rejuvenation of granodioritic crystal mush resulting in homogeneous dacite recorded by the Haramul Mic lava dome (Ciomadul)

2020 ◽  
Author(s):  
Emese Pánczél ◽  
Maurizio Petrelli ◽  
Réka Lukács ◽  
Szabolcs Harangi
Keyword(s):  
Lava Dome ◽  
Thermal Evolution ◽  
Bulk Composition ◽  
Volcanic Complex ◽  
Bulk Rock ◽  
Crystal Mush ◽  
Magmatic System ◽  
Zircon Core ◽  
Accessory Zircon ◽  
Zircon Crystallization

<p>Long-dormant volcanoes (quiescence time is several 100’s to 10’s thousand years between eruptions) pose a particular hazard, since the long repose time decreases the awareness and there is mostly a lack of monitoring. The Haramul Mic, a pancake-shaped flat dacitic lava dome is part of the Ciomadul Volcanic Complex in eastern-central Europe (Romania) and serves as an excellent example of such volcanoes. The Haramul Mic lava dome is the earliest product of the Young Ciomadul Eruption Period (YCEP), when the activity recrudesced in the area after about 200.000 years quiescence time. Eruption age of the dome determined by (U-Th)/He dating on zircon gave 154 +/- 16 ka that is in agreement with the youngest zircon U-Th outer rim date (142 +18/-16 ka). In the YCEP zircon crystallization dates record typically long, up to 350-400 kyr lifetime of the magmatic plumbing system, in case of  Haramul Mic the oldest zircon core is 306 +/- 37 ka old.</p><p>The 880.7 m high lava dome covers an area of 1.1 km<sup>2</sup> and has a volume of ~0.15 km<sup>3</sup>. It is composed of crystal-rich homogeneous high-K dacite. The average crystal content is 35-40% and consists of plagioclase, amphibole, biotite and accessory zircon, apatite, titanite and Fe-Ti oxides. The groundmass is mainly built up by perlitic glass with some microlites. The dacite includes mafic enclaves having plagioclase and amphibole besides a large amount of biotite crystals, that eventuates K-rich, shoshonitic bulk composition. The dacite contains abundant felsic crystal clots which comprise plagioclase, amphibole, biotite and interstitial vesicular glass.</p><p>Amphiboles are relatively homogeneous in chemical composition. They are low-Al hornblendes suggesting 700-800 <sup>o</sup>C crystallization condition at 200-300 MPa compared with experimental data. Al-in-hornblende geobarometer and amphibole-plagioclase geothermometer calculations give results reproducing these temperature and pressure ranges. Although the Kis-Haram dacite is fairly rich in 25-45 anorthite mol% plagioclase, no negative Eu anomaly can be observed in the bulk rock and the glass. Similarities between Fish Canyon Tuff and Kis-Haram rocks can be strikingly noted regarding the major and trace element contents of mineral phases, glass and bulk rock that all refer to a wet oxidised calc-alkaline magmatic system. The relatively small volume Kis-Haram lava dome represents a rejuvenated low-temperature granodioritic crystal mush having similar features as the large volume silicic eruption of Fish Canyon Tuff. Their recorded almost similarly long zircon crystallization intervals give an interesting aspect with regard to the thermal evolution of the magmatic system and eruption volumes.</p><p>This research was financed by the Hungarian National Research, Development and Innovation Fund (NKFIH) within No. K116528 project and was supported by the ÚNKP-19-1 New National Excellence Program of the Ministry for Innovation and Technology.</p>

Geochemical model of a magmatic–hydrothermal system at the Lastarria volcano, northern Chile

2011 ◽  
Vol 74 (1) ◽  
pp. 119-134 ◽  
Author(s):  
Felipe Aguilera ◽  
F. Tassi ◽  
T. Darrah ◽  
S. Moune ◽  
O. Vaselli
Keyword(s):  
Hydrothermal System ◽  
Northern Chile ◽  
Geochemical Model

GEOCHEMICAL ZONING OF THE PESCHANKA PORPHYRYEPITHERMAL SYSTEM, THE WESTERN CHUKCHI PENINSULA

2018 ◽  
pp. 40-47
Author(s):  
G. T. Dzhedzheya ◽  
Yu. N. Sidorina
Keyword(s):  
Porphyry Copper ◽  
Chukchi Peninsula ◽  
Geochemical Model ◽  
Geochemical Zoning ◽  
Erosion Level ◽  
Mineral Assemblages ◽  
Drill Holes ◽  
Gis Software ◽  
Elemental Associations ◽  
Vertical Zoning

To identify geochemical zoning of the Peschanka porphyry-epithermal system geochemical and mineralogical data for 266 drill holes were used. By means of factor analysis and GIS software 3D geochemical model was developed to map spatial distribution of elemental associations and mineral assemblages. Lateral and longitudinal zoning patterns were described. The ratio AgPbZn:CuAuMo was suggested as an indicator of vertical zoning allowing assessing erosion level of porphyry copper stockworks.

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