Carbon Dioxide Chemistry, Capture and Oil Recovery

2018 ◽  
Keyword(s):  
Carbon Dioxide ◽  
Oil Recovery ◽  
Carbon Dioxide Chemistry

scholarly journals Laboratory evaluation of hybrid chemical enhanced oil recovery methods coupled with carbon dioxide

2021 ◽  
Vol 7 ◽  
pp. 960-967
Author(s):  
Mohammad Hossein Ahmadi ◽  
S.M. Alizadeh ◽  
Dmitry Tananykhin ◽  
Saba Karbalaei Hadi ◽  
Pavel Iliushin ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Laboratory Evaluation ◽  
Recovery Methods

Saturated carbon dioxide nanofluids enhanced oil recovery in carbonate reservoir cores using nuclear magnetic resonance

2021 ◽  
Author(s):  
Yongsheng Tan ◽  
Qi Li ◽  
Liang Xu ◽  
Xiaoyan Zhang ◽  
Tao Yu
Keyword(s):  
Carbon Dioxide ◽  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Carbonate Reservoir ◽  
Carbonate Reservoirs ◽  
Residual Oil ◽  
Core Flooding ◽  
Nuclear Magnetic

<p>The wettability, fingering effect and strong heterogeneity of carbonate reservoirs lead to low oil recovery. However, carbon dioxide (CO<sub>2</sub>) displacement is an effective method to improve oil recovery for carbonate reservoirs. Saturated CO<sub>2</sub> nanofluids combines the advantages of CO<sub>2</sub> and nanofluids, which can change the reservoir wettability and improve the sweep area to achieve the purpose of enhanced oil recovery (EOR), so it is a promising technique in petroleum industry. In this study, comparative experiments of CO<sub>2</sub> flooding and saturated CO<sub>2</sub> nanofluids flooding were carried out in carbonate reservoir cores. The nuclear magnetic resonance (NMR) instrument was used to clarify oil distribution during core flooding processes. For the CO<sub>2</sub> displacement experiment, the results show that viscous fingering and channeling are obvious during CO<sub>2</sub> flooding, the oil is mainly produced from the big pores, and the residual oil is trapped in the small pores. For the saturated CO<sub>2</sub> nanofluids displacement experiment, the results show that saturated CO<sub>2</sub> nanofluids inhibit CO<sub>2</sub> channeling and fingering, the oil is produced from the big pores and small pores, the residual oil is still trapped in the small pores, but the NMR signal intensity of the residual oil is significantly reduced. The final oil recovery of saturated CO<sub>2</sub> nanofluids displacement is higher than that of CO<sub>2</sub> displacement. This study provides a significant reference for EOR in carbonate reservoirs. Meanwhile, it promotes the application of nanofluids in energy exploitation and CO<sub>2</sub> utilization.</p>

A Laboratory Investigation of the Effect of Ethanol-Treated Carbon Dioxide Injection on Oil Recovery and Carbon Dioxide Storage

SPE Journal ◽  
2021 ◽  
pp. 1-17
Author(s):  
Saira ◽  
Emmanuel Ajoma ◽  
Furqan Le-Hussain
Keyword(s):  
Carbon Dioxide ◽  
Oil Recovery ◽  
Carbon Capture ◽  
Molar Fraction ◽  
Co2 Injection ◽  
Carbon Dioxide Injection ◽  
Treated Carbon ◽  
Carbon Dioxide Co2 ◽  
And Storage ◽  
Experimental Runs

Summary Carbon dioxide (CO2) enhanced oil recovery is the most economical technique for carbon capture, usage, and storage. In depleted reservoirs, full or near-miscibility of injected CO2 with oil is difficult to achieve, and immiscible CO2 injection leaves a large volume of oil behind and limits available pore volume (PV) for storing CO2. In this paper, we present an experimental study to delineate the effect of ethanol-treated CO2 injection on oil recovery, net CO2 stored, and amount of ethanol left in the reservoir. We inject CO2 and ethanol-treated CO2 into Bentheimer Sandstone cores representing reservoirs. The oil phase consists of a mixture of 0.65 hexane and 0.35 decane (C6-C10 mixture) by molar fraction in one set of experimental runs, and pure decane (C10) in the other set of experimental runs. All experimental runs are conducted at constant temperature 70°C and various pressures to exhibit immiscibility (9.0 MPa for the C6-C10 mixture and 9.6 MPa for pure C10) or near-miscibility (11.7 MPa for the C6-C10 mixture and 12.1 MPa for pure C10). Pressure differences across the core, oil recovery, and compositions and rates of the produced fluids are recorded during the experimental runs. Ultimate oil recovery under immiscibility is found to be 9 to 15% greater using ethanol-treated CO2 injection than that using pure CO2 injection. Net CO2 stored for pure C10 under immiscibility is found to be 0.134 PV greater during ethanol-treated CO2 injection than during pure CO2 injection. For the C6-C10 mixture under immiscibility, both ethanol-treated CO2 injection and CO2 injection yield the same net CO2 stored. However, for the C6-C10 mixture under near-miscibility,ethanol-treated CO2 injection is found to yield 0.161 PV less net CO2 stored than does pure CO2 injection. These results suggest potential improvement in oil recovery and net CO2 stored using ethanol-treated CO2 injection instead of pure CO2 injection. If economically viable, ethanol-treated CO2 injection could be used as a carbon capture, usage, and storage method in low-pressure reservoirs, for which pure CO2 injection would be infeasible.

A Simulation Study of Steamflood Process with Co-Injection of Steam-Carbon Dioxide for Oil Recovery

2021 ◽  
Vol 1 (1) ◽  
Author(s):  
Pradini Rahalintar ◽  
◽  
Erdila Indriani
Keyword(s):  
Carbon Dioxide ◽  
Oil Recovery ◽  
Simulation Study

Carbon Emission Reduction via HNGLRP CC&S Technology

2021 ◽  
Author(s):  
Sultan Ahmari ◽  
Abdullatef Mufti
Keyword(s):  
Carbon Dioxide ◽  
Oil Recovery ◽  
Water Reuse ◽  
Carbon Emission ◽  
Ventilation System ◽  
Acid Gas ◽  
Gas Removal ◽  
Saudi Aramco ◽  
Supercritical Phase ◽  
Incineration Process

Abstract The paper objective is to present the successful achievement by Saudi Aramco gas operations to reduce the carbon emission at Hawyiah NGL Recovery Plant (HNGLRP) after successful operation & maintainability of the newly state of the art Carbon Capture & Sequestration (CC&S) technology. This is in line with the Kingdom of Saudi Arabia (KSA) 2030 vision to increase the resources sustainability for future growth and part of Saudi Aramco circular economy in action examples. Saudi Aramco CC&S started in June 2015 at HNGLRP with main objective to capture the carbon dioxide (CO2) from Acid Gas Removal Units (AGRUs) and then inject an annual mass of nearly 750 Kton of carbon dioxide into oil wells for sequestration and enhanced oil recovery maintainability. This is to replace the typical acid gas incineration process after AGRUs operation to reduce carbon footprint. CC&S consists of the followings: integrally geared multistage compressor, standalone dehydration system using Tri-Ethylene Glycol (TEG), CO2 vapor recovery unit (VRU), Granulated Activated Carbon (GAC) to treat water generated from compression and dehydration systems for reuse purpose, and special dense phase pump that transfers the dehydrated CO2 at supercritical phase through 85 km pipeline to replace the typical sea water injection methodology in enhancing oil recovery. CC&S has several new technologies and experiences represented by the compressor capacity, supercritical phase fluid pumping, using mechanical ejector application to maximize carbon recovery, and CO2/TEG dehydration system as non-typical dehydration system. CC&S design considered the occupational health hazards generated from the compressor operation by installing engineering enclosure with proper ventilation system to minimize the noise hazard. CC&S helped HNGLRP to reduce the overall Greenhouse Gas (GHG) emission resulted from typical CO2 incineration process (thermal oxidizing). (2) The total GHG resulted from combustion sources at HNGLRP reduced by nearly 30% since CC&S technology in operation. The fuel gas consumption to run the thermal oxidizers in AGRUs reduced by 75% and sent as sales gas instead. The Energy Intensity Index (EII) reduced by 8% since 2015, water reuse index (WRI) increased by 12%. In conclusion, the project shows significant reduction in the carbon emission, noticeable increase in the production, and considerable water reuse.

scholarly journals Application of Sustainable Foaming Agents to Control the Mobility of Carbon Dioxide in Enhanced Oil Recovery

2012 ◽  
Author(s):  
Roozbeh Rafati ◽  
Hossein Hamidi ◽  
Ahmad Kamal Idris
Keyword(s):  
Carbon Dioxide ◽  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Foaming Agents

scholarly journals Carbon dioxide adsorption and interaction with formation fluids of Jordanian unconventional reservoirs

2021 ◽  
Author(s):  
H. Samara ◽  
T. V. Ostrowski ◽  
F. Ayad Abdulkareem ◽  
E. Padmanabhan ◽  
P. Jaeger
Keyword(s):  
Carbon Dioxide ◽  
Contact Angle ◽  
Interfacial Tension ◽  
Oil Recovery ◽  
Gas Adsorption ◽  
Sessile Drop ◽  
Global Climate ◽  
Gravimetric Method ◽  
Rock Surface ◽  
Operating Pressure

AbstractShales are mostly unexploited energy resources. However, the extraction and production of their hydrocarbons require innovative methods. Applications involving carbon dioxide in shales could combine its potential use in oil recovery with its storage in view of its impact on global climate. The success of these approaches highly depends on various mechanisms taking place in the rock pores simultaneously. In this work, properties governing these mechanisms are presented at technically relevant conditions. The pendant and sessile drop methods are utilized to measure interfacial tension and wettability, respectively. The gravimetric method is used to quantify CO2 adsorption capacity of shale and gas adsorption kinetics is evaluated to determine diffusion coefficients. It is found that interfacial properties are strongly affected by the operating pressure. The oil-CO2 interfacial tension shows a decrease from approx. 21 mN/m at 0.1 MPa to around 3 mN/m at 20 MPa. A similar trend is observed in brine-CO2 systems. The diffusion coefficient is observed to slightly increase with pressure at supercritical conditions. Finally, the contact angle is found to be directly related to the gas adsorption at the rock surface: Up to 3.8 wt% of CO2 is adsorbed on the shale surface at 20 MPa and 60 °C where a maximum in contact angle is also found. To the best of the author’s knowledge, the affinity of calcite-rich surfaces toward CO2 adsorption is linked experimentally to the wetting behavior for the first time. The results are discussed in terms of CO2 storage scenarios occurring optimally at 20 MPa.

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