scholarly journals A Spatially-Resolved operando High-Energy Confocal X-ray Diffraction Method for Observing Non-Uniform Degradation Phenomena in a Practical Cylindrical Lithium-ion Battery

2020 ◽  
Vol 88 (2) ◽  
pp. 63-68
Author(s):  
Teruhisa BABA ◽  
Naoki TAKAO ◽  
Yoshitake HONDA ◽  
Masazumi ARAO ◽  
Masashi MATSUMOTO ◽  
...  
Keyword(s):  
Lithium Ion Battery ◽  
Diffraction Method ◽  
Lithium Ion ◽  
High Energy ◽  
X Ray Diffraction ◽  
X Ray ◽  
Spatially Resolved

In situ high-energy X-ray diffraction to study overcharge abuse of 18650-size lithium-ion battery

2013 ◽  
Vol 230 ◽  
pp. 32-37 ◽  
Author(s):  
Chi-Kai Lin ◽  
Yang Ren ◽  
Khalil Amine ◽  
Yan Qin ◽  
Zonghai Chen
Keyword(s):  
Lithium Ion Battery ◽  
Lithium Ion ◽  
High Energy ◽  
X Ray Diffraction ◽  
X Ray

scholarly journals Spatially Resolved Forming Mechanisms Detection in Single Point Incremental Forming Using Synchrotron Based Texture Analysis

2021 ◽  
Author(s):  
Mateus Dobecki ◽  
Alexander Poeche ◽  
Walter Reimers
Keyword(s):  
Texture Analysis ◽  
Incremental Forming ◽  
Single Point ◽  
High Energy ◽  
X Ray Diffraction ◽  
X Ray ◽  
Forming Mechanism ◽  
Spatially Resolved ◽  
Step Down ◽  
Stress States

AbstractDespite the ongoing success of understanding the deformation states in sheets manufactured by single-point incremental forming (SPIF), the unawareness of the spatially resolved influence of the forming mechanisms on the residual stress states of incrementally formed sheet metal parts impedes their application-optimized use. In this study, a well-founded experimental proof of the occurring forming mechanisms shear, bending and stretching is presented using spatially resolved, high-energy synchrotron x-ray diffraction-based texture analysis in transmission mode. The measuring method allows even near-surface areas to be examined without any impairment of microstructural influences due to tribological reactions. The depth-resolved texture evolution for different sets of forming parameters offers insights into the forming mechanisms acting in SPIF. Therefore, the forming mechanisms are triggered explicitly by adjusting the vertical step-down increment Δz for groove, plate and truncated cone geometries. The texture analysis reveals that the process parameters and the specimen geometries used lead to characteristic changes in the crystallites’ orientation distribution in the formed parts due to plastic deformation. These forming-induced reorientations of the crystallites could be assigned to the forming mechanisms by means of defined reference states. It was found that for groove, plate and truncated cone geometries, a decreasing magnitude of step-down increments leads to a more pronounced shear deformation, which causes an increasing work hardening especially at the tool contact area of the formed parts. Larger step-down increments, on the other hand, induce a greater bending deformation. The plastic deformation by bending leads to a complex stress field that involves alternating residual tensile stresses on the tool and residual compressive stresses on the tool-averted side incrementally formed sheets. The present study demonstrates the potential of high-energy synchrotron x-ray diffraction for the spatially resolved forming mechanism research in SPIF. Controlling the residual stress states by optimizing the process parameters necessitates knowledge of the fundamental forming mechanism action.

Phase composition depth profiles using spatially resolved energy dispersive X-ray diffraction

2004 ◽  
Vol 37 (6) ◽  
pp. 967-976 ◽  
Author(s):  
Andrew C. Jupe ◽  
Stuart R. Stock ◽  
Peter L. Lee ◽  
Nikhila N. Naik ◽  
Kimberly E. Kurtis ◽  
...  
Keyword(s):  
Phase Composition ◽  
Spatial Resolution ◽  
Zinc Coating ◽  
High Energy ◽  
Sulfate Attack ◽  
Energy Dispersive ◽  
X Ray Diffraction ◽  
X Ray ◽  
Spatially Resolved ◽  
Composition Profiles

Spatially resolved energy dispersive X-ray diffraction, using high-energy synchrotron radiation (∼35–80 keV), was used nondestructively to obtain phase composition profiles along the radii of cylindrical cement paste samples to characterize the progress of the chemical changes associated with sulfate attack on the cement. Phase distributions were acquired to depths of ∼4 mm below the specimen surface with sufficient spatial resolution to discern features less than 200 µm thick. The experimental and data analysis methods employed to obtain quantitative composition profiles are described. The spatial resolution that could be achieved is illustrated using data obtained from copper cylinders with a thin zinc coating. The measurements demonstrate that this approach is useful for nondestructively visualizing the sometimes complex transformations that take place during sulfate attack on cement-based materials. These transformations can be spatially related to microstructure as seen by computed microtomography.

Ball-Milled Graphite-Tin Composite Anode Materials for Lithium-Ion Battery

2012 ◽  
Vol 736 ◽  
pp. 127-132
Author(s):  
Kuldeep Rana ◽  
Anjan Sil ◽  
Subrata Ray
Keyword(s):  
Lithium Ion Battery ◽  
Anode Materials ◽  
High Capacity ◽  
Lithium Ion ◽  
Composite Anode ◽  
X Ray Diffraction ◽  
Promising Alternative ◽  
X Ray ◽  
Initial Discharge ◽  
Lithium Ion Cell

Lithium alloying compounds as an anode materials have been a focused for high capacity lithium ion battery due to their highenergy capacity and safety characteristics. Here we report on the preparation of graphite-tin composite by using ball-milling in liquid media. The composite material has been characterized by scanning electron microscope, energy depressive X-ray spectroscopy, X-ray diffraction and Raman spectra. The lithium-ion cell made from graphite-tin composite presented initial discharge capacity of 1065 mAh/g and charge capacity 538 mAh/g, which becomes 528 mAh/g in the second cycle. The composite of graphite-tin with higher capacity compared to pristine graphite is a promising alternative anode material for lithium-ion battery.

scholarly journals Making and Characterization of Limnpo4 Using Solid State Reaction Method for Lithium Ion Battery Cathodes

2019 ◽  
pp. 583-588
Author(s):  
Adelyna Oktavia ◽  
Kurnia Sembiring ◽  
Slamet Priyono
Keyword(s):  
Solid State ◽  
Lithium Ion Battery ◽  
Lithium Ion ◽  
Solid State Reaction Method ◽  
Raw Material ◽  
X Ray Diffraction ◽  
Solid State Method ◽  
X Ray ◽  
General Investigation

Hospho-material of olivine, LiMnPO4 identified as promising for cathode material generation next Lithium-ion battery and has been successfully synthesized by solid-state method with Li2Co3, 2MnO2, 2NH4H2PO4 as raw material. The influence of initial concentration of precursors at kalsinasi temperatures (400-800 ° C) flows with nitrogen. The purity and composition phase verified by x-ray diffraction analysis (XRD), scanning electron microscopy (SEM), spectroscopy, energy Dispersive x-ray Analysis (EDS), Raman spectra. General investigation shows that there is a correlation between the concentration of precursors, the temperature and the temperature of sintering kalsinasi that can be exploited to design lithium-ion next generation.

scholarly journals High-Energy X-Ray Compton Scattering Imaging of 18650-Type Lithium-Ion Battery Cell

2019 ◽  
Vol 4 (3) ◽  
pp. 66 ◽  
Author(s):  
Kosuke Suzuki ◽  
Ari-Pekka Honkanen ◽  
Naruki Tsuji ◽  
Kirsi Jalkanen ◽  
Jari Koskinen ◽  
...  
Keyword(s):  
Energy Spectrum ◽  
Lithium Ion Battery ◽  
Compton Scattering ◽  
Present Method ◽  
Large Scale ◽  
Lithium Ion ◽  
High Energy ◽  
The Other ◽  
Battery Cell ◽  
X Ray

High-energy synchrotron X-ray Compton scattering imaging was applied to a commercial 18650-type cell, which is a cylindrical lithium-ion battery in wide current use. By measuring the Compton scattering X-ray energy spectrum non-destructively, the lithiation state in both fresh and aged cells was obtained from two different regions of the cell, one near the outer casing and the other near the center of the cell. Our technique has the advantage that it can reveal the lithiation state with a micron-scale spatial resolution even in large cells. The present method enables us to monitor the operation of large-scale cells and can thus accelerate the development of advanced lithium-ion batteries.

Nano structure of low crystallinity carbon materials analyzed by using high energy X-ray diffraction

Open Physics ◽  
2009 ◽  
Vol 7 (2) ◽  
Author(s):  
Kyoichi Oshida ◽  
Tatsuo Nakazawa ◽  
Kozo Osawa ◽  
Morinobu Endo
Keyword(s):  
Carbon Materials ◽  
Lithium Ion ◽  
High Energy ◽  
Experimental Results ◽  
Disordered Materials ◽  
X Ray Diffraction ◽  
Structural Units ◽  
Nano Structure ◽  
X Ray ◽  
Low Crystallinity

AbstractIn this study, we tried to characterize a kind of low crystallinity carbon materials. The structure of polyparaphenylene(PPP)-based carbon was analyzed by means of high energy X-ray diffraction using the apparatus of SPring-8. The experimental results revealed the existence of basic structural units (BSU) in the highly disordered materials like PPP-based carbon. It is thought that the PPP-based carbons consist of small turbostratic particles, which have a few piled up poly-aromatic layers. The structure of the PPP-based carbon which seemed to be amorphous was estimated to have hexagonal carbon layers with the size of up to 1 nm. The pores in the PPP-based carbon seem to be clearances formed among the BSUs and amorphous carbon. The pore size of PPP-based carbon was estimated from the result of N2 absorption measurement. The experimental results suggested that the lithium ion charge mechanism in the PPP-based carbon differs from that in graphite.

scholarly journals Quantifying lithium concentration gradients in the graphite electrode of Li-ion cells using operando energy dispersive X-ray diffraction

2019 ◽  
Vol 12 (2) ◽  
pp. 656-665 ◽  
Author(s):  
Koffi P. C. Yao ◽  
John S. Okasinski ◽  
Kaushik Kalaga ◽  
Ilya A. Shkrob ◽  
Daniel P. Abraham
Keyword(s):  
Spatial Distribution ◽  
Lithium Ion Battery ◽  
Graphite Electrode ◽  
Lithium Concentration ◽  
Lithium Ion ◽  
Energy Dispersive ◽  
X Ray Diffraction ◽  
Concentration Gradients ◽  
X Ray ◽  
Li Ion

Spatial distribution of lithium cations in the graphite electrode of a lithium-ion battery is quantified using operando energy dispersive X-ray diffraction.

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