scholarly journals Thermodynamic investigation of disperse dyes sorption on polyester fibers

2020 ◽  
Vol 9 (2) ◽  
pp. 41-47
Author(s):  
Marija Kodrić ◽  
Arianit Reka ◽  
Čedomir Dimić ◽  
Anita Tarbuk ◽  
Dragan Đorđević
Keyword(s):  
Thermodynamic Parameters ◽  
Batch Process ◽  
Disperse Dyes ◽  
Disperse Dye ◽  
Thermodynamic Investigation ◽  
Method Of Calculation ◽  
Dyeing Process ◽  
Standard Procedures ◽  
Polyester Fibers ◽  
Thermodynamics Of Sorption

The thermodynamics of sorption during the dyeing process of raw polyester fibers with disperse dye was studied in this article. Dyeing of fibers is carried out by a discontinuous batch process, according to standard procedures with varying of the initial dye concentration and the dyeing temperature. Several of the accepted models for calculation of thermodynamic parameters were used which define and clarify the sorption of disperse dyes on polyester fibers. High functionality of variables for the calculation of basic thermodynamic parameters was determined, which confirmed the validity of the results. Depending on the method of calculation , the change of free energy during the dyeing of the polyester was negative (-10-40 kJ·mol-1), which corresponds to the spontaneous and mainly the physical process of sorption. A positive value for the change in enthalpy during dyeing (1.1×10-2-2.9×10 1 kJ·mol-1) reflects the endothermic nature of the interactions, and a relatively lower value characterizes the physisorption phenomenon. A positive value for the change in entropy (1.1×10-4-1.5×10-1 kJ·mol-1 ·K-1) confirms that it is a physical sorption.

Modification of Polyester Textiles for Easier Dyeing with Disperse Dyes

2020 ◽  
Vol 7 (5) ◽  
pp. 9-16
Author(s):  
Marija Kodric ◽  
Dragan Djordjevic
Keyword(s):  
Differential Scanning Calorimetry ◽  
Polyester Fabric ◽  
Disperse Dyes ◽  
Disperse Dye ◽  
Primary Alcohols ◽  
Scanning Calorimetry ◽  
Absorption Properties ◽  
Fiber Modification ◽  
Polyester Fibers ◽  
Polyester Dyeing

Modification of polyester fibers for more economical dyeing at lower temperatures without a carrier are considered in this study. Polyester dyeing is carried out industrially under rigorous conditions at high temperatures and under increased air pressure, and are treated with various solvents (primary alcohols) to make the fibers more permeable. As a result, the sorption properties, as well as the disperse dye dyeing ability, are improved. Dyeing of a modified polyester fabric at lower temperatures yielded better results than the standard dyeing of the unmodified polyester under the same conditions. The effects of fiber modification were analyzed through water absorption properties, wetting, swelling, differential scanning calorimetry (DSC), and Fourier transform infrared (FTIR) methods, and the degree of dyeing of the fabric was evaluated using CIELab parameters.

Structure and dyeing properties of jade fibre

2014 ◽  
Vol 43 (3) ◽  
pp. 139-144
Author(s):  
Shuling Cui
Keyword(s):  
Adsorption Mechanism ◽  
Polyester Fibre ◽  
Cationic Dyes ◽  
Disperse Dyes ◽  
Disperse Dye ◽  
Cationic Dye ◽  
Absorption Mechanism ◽  
Dyeing Properties ◽  
Content Type ◽  
Dyeing Process

Purpose – Based on clarifying the structural difference between jade fibre and general polyester fibre, this paper aims to study the dyeing properties and dyeing adsorption mechanism of jade fibre with disperse dye and cationic dye. Design/methodology/approach – The chemical structure and microstructure of jade fibre were briefly explained comparing with ordinary polyester fibre. The dyeing rate curve and dyeing adsorption isotherm of disperse dyes and cationic dyes on jade fibre were, respectively, studied. The dyeing uptake, dyeing absorption mechanism, and the main dyeing process parameters were proposed. Findings – Jade fibre can be dyed with cationic dye and disperse dye. The suitable exhaust dyeing process is 110°C and 40 minutes for disperse dye, 100°C and 60 minutes for cationic dye. The dyeing uptake on jade fibre with both disperse dyes or cationic dyes is much higher than that on general polyester fibre and acrylic fibre, and the dyeing adsorption mechanism belongs to the combination of Langmuir and Nernst adsorption for disperse dyes and Langmuir adsorption for cationic dyes. Comparing with ordinary polyester fibre, jade fibre has the advantage of low temperature dyeing and reduced effluent, as is significant to energy-saving and emission reduction. Originality/value – Jade fibre is a new type of modified polyester fibre with the function of health protection and energy conservation. There are little technical data in the literature at present about the dyeing property of jade fibre.

Study on the Dyeing of PET Fiber with Disperse Dyes in D5 Media

2011 ◽  
Vol 331 ◽  
pp. 334-337 ◽  
Author(s):  
Shen Zheng Li ◽  
Jin Qiang Liu ◽  
Yong Qiang Li ◽  
Li Ming Li
Keyword(s):  
New Method ◽  
Disperse Dyes ◽  
Disperse Dye ◽  
Water Addition ◽  
Environmental Media ◽  
Dyeing Process ◽  
Adsorption Amount

This experiment selected a new kind of environmental media (D5) instead of using water on the dyeing of PET, this work provided a new method for non-aqueous dyeing. The effects of the water addition, temperature, dyeing time and reagents on adsorption amount of disperse dye were studied, one good dyeing process is, adding 0.5mL water and 0.3mL ethanol into 20mL D5 system, the temperature of dyeing was 130°C, the preservation time of dyeing was 60min.

scholarly journals Influence of different acids for adjusting the dyebath ph value on the dyeability of polyester knitwear dyed with disperse yellow 23

2011 ◽  
Vol 65 (3) ◽  
pp. 257-261
Author(s):  
Milena Miljkovic ◽  
Milovan Purenovic ◽  
Dragan Djordjevic ◽  
Milica Petrovic
Keyword(s):  
Acetic Acid ◽  
Oxalic Acid ◽  
Surface Structure ◽  
Ph Value ◽  
Polyester Fabric ◽  
Disperse Dye ◽  
Dyeing Process ◽  
Color Differences ◽  
Polyester Fibers ◽  
Oxalic Acids

In this paper the influence of the formic and oxalic acids, as substances for dyebath pH adjusting, on the dyeability of polyester fabric dyed with disperse dye Disperse Yellow 23 was examined. The polyester undyed knitwear samples were dyed in baths containing the acids under the same dyeing conditions. Color differences of the samples were assessed using the reflectiometry technique and expressed in terms of CIELcoordinates. The influence of the tested acids on the surface structure of dyed polyester fibers was examined using the scanning electron microscopy (SEM). It was found that the differences in obtained dyeabilities, in the presence of both formic and oxalic acid, are acceptable according to both M&S 83A and CMC (2:1) standards which was not the case with acetic acid. Therefore, acetic acid can be replaced with either formic or oxalic acid as substances for dyebath pH adjusting in the dyeing process described in this paper. SEM micrographs showed small differences in the surface structure of dyed fibers, as well as differences in the shape of undyed samples? reflectance curves in presence of the acids. Since all of the color differences were quite small, it can be concluded that the influence of formic and oxalic acids on the polyester knitwear dyeability is not significantly different than that of acetic acid.

scholarly journals One-bath One-step Dyeing of Polyester/Cotton (PC) Blends Fabric With Disperse Dyes After Acetylation of Cotton

2021 ◽  
Author(s):  
Girmaye Kumsa Bana ◽  
Gemeda Gebino Gelebo ◽  
Gezu Ketema Janka
Keyword(s):  
Tensile Strength ◽  
Surface Modification ◽  
Disperse Dyes ◽  
Disperse Dye ◽  
Color Strength ◽  
Acetyl Content ◽  
Dyeing Process ◽  
One Step ◽  
The One ◽  
Dyed Fabric

Usually, the two-bath dyeing process using disperse dyes and reactive dyes separately was employed for the dyeing of PC blends. The cost of the double bath, dyeing cycle, energy consumption and chemical consumption is quite higher than the one-step or single bath dyeing methods. In this study, the one-bath dyeing process using one kind of dye was investigated. Polyester cotton blends dyed in one-bath one-step dyeing methods with disperse dye after surface modifications of cotton by acetylation methods were studied. Surface modification of cotton was carried out using fibrous acetylation methods. The effect of acetic anhydride and time on percent acetyl content at room temperature was studied. Modified polyester/cotton was carried out in HTHP dyeing machine incorporates with different dye concentrations and dyeing temperature. Surface chemistry, thermal decomposition property and moisture regain of modified polyester/ cotton blend are evaluated. The color strength of the dyed fabrics and their fastness properties to washing, light, and rubbing as well as tear strength and abrasion resistance were evaluated. The effect of dye concentration and temperature color strength, tensile strength warp and weft direction was assessed. The optimum value for surface modification was obtained with a concentration of acetylation agent 16% and time of reaction 2.5 hours, gave percent acetylation of 34. An FTIR spectrum shows acetylation resonance. The experiment result of dyeing showed that the optimum value was obtained with dye concentration above 1% at a temperature of 120oC, warp tensile strength decreased by 12% and weft tensile strength was decreased by 9% from the control half-bleached fabric. Results of this study showed that a one-step one-bath dyed modified polyester/cotton blend with disperse dye fabric presents good fastness property compared with conventional two-bath dyed fabric as well as colour strength values.

scholarly journals Modelling of polyester fabric dyeing in the presence of ultrasonic waves

2017 ◽  
Vol 23 (1) ◽  
pp. 131-139 ◽  
Author(s):  
Marija Kodric ◽  
Sandra Stojanovic ◽  
Branka Markovic ◽  
Dragan Djordjevic
Keyword(s):  
Polyester Fabric ◽  
Ultrasonic Waves ◽  
Disperse Dyes ◽  
Disperse Dye ◽  
Precise Description ◽  
Additional Energy ◽  
Initial Concentration ◽  
Dyeing Process ◽  
Pseudo Second Order ◽  
Polyester Dyeing

In this paper, modelling of dyeing, i.e. adsorptive behaviour of disperse dyes on polyester fibres (dyeing), under the influence of ultrasound has been considered with the aim of getting the data about mechanisms of binding the dyes and defining the conditions of dyeing process of this synthetic fibres along with additional energy source without the use of carriers, compounds that increase permeability of the fibres and help dyeing. Dyeing - adsorption is conducted under different conditions, and the concentration of dyes, mass of the substrate, recipes and time of dyeing were being varied. It has been established that ultrasound allows dyeing without carriers and the efficiency of dyeing depends on the time of contact, initial concentration of the dye and the amount of absorbent - material. There is the continuity of growth of the amount of bound dye to the mass of the absorbent. Characteristic graphs, obtained from Langmuir isotherm, have confirmed that this model ensures precise description of polyester dyeing by disperse dye. Kinetic of dyeing has been remarkably interpreted by pseudo second-order in regards to the high functionality.

Energy Level and Chemical Class of Disperse Dyes—Plausible Characteristics of Level Dyeing Performance

2021 ◽  
Vol 8 (4) ◽  
pp. 15-19
Author(s):  
Salima Sultana Shimo ◽  
Md. Zulhash Uddin
Keyword(s):  
Energy Level ◽  
Low Energy ◽  
Disperse Dyes ◽  
Disperse Dye ◽  
Migration Process ◽  
Migration Index ◽  
Dyeing Performance ◽  
Fabric Surface ◽  
Chemical Class

The level dyeing index (LDI) is a measure of dye performance influenced by the dye migration process, ensuring the maximum uniformity of dye redistribution onto the fabric surface. The current study evaluates the level dyeing performance on polyester according to the energy level (low and high) and chemical classes (azo and anthraquinone based) of the three disperse dyes studied. The best levelness was obtained using C.I. Disperse Red 73 (an azo-based, low-energy level disperse dye), which exhibited the highest migration index (MI%) value. LDI results were obtained from the ratio of the exhaustion at the critical dyeing temperature (ECDT% and the final exhaustion Ef%), and the migration index (MI%). Each dye's LDI can be used to determine the compatibility of disperse dyes for combination dyeing.

A novel functional disperse dye doped with graphene oxide for improving antistatic properties of polyester fabric using one-bath dyeing method

2019 ◽  
Vol 90 (5-6) ◽  
pp. 655-665 ◽  
Author(s):  
Lihua Fan ◽  
Yongsong Tan ◽  
Jeremiah Amesimeku ◽  
Yunjie Yin ◽  
Chaoxia Wang
Keyword(s):  
Graphene Oxide ◽  
Polyester Fabric ◽  
Disperse Dye ◽  
Reduction Time ◽  
Dyeing Process ◽  
Functional Dyes ◽  
One Bath Dyeing ◽  
Dyeing Method ◽  
Dyed Fabric ◽  
Microscopic Morphology

A novel functional disperse dye doped with graphene oxide for antistatic properties of polyester fabric was achieved, which means that the dyeing and antistatic finishing can be simultaneously obtained by a one-bath method. Functional dyes were used to dye polyester fabric by a high-temperature, high-pressure dyeing method. The surface microscopic morphology of the dyed polyester fabric, and the dispersion properties of the disperse dye, graphene oxide, and the functional disperse dye, were characterized by scanning electron microscopy. The effects of the dyeing temperature on the particle sizes of three dyeing liquors were explored; this revealed that the temperature of the dyeing process had no effect on particle size. The dosage and reduction time of graphene oxide were investigated. The surface electrical resistance of the dyed fabric, 9.8 × 106 Ω, obtained at a condition of 2% (o.m.f) graphene oxide with a reduction time of 30 min, achieved A-grade antistatic standard. Furthermore, the rubbing and washing fastness of the treated fabric were 4- and 4 ∼ 5 grades, respectively. This preparation of the functional disperse dye provides a possibility in one-bath dyeing and antistatic finishing of polyester fabric.

scholarly journals Dyeing of Polyester with 4-Fluorosulfonylphenylazo-5-pyrazolone Disperse Dyes and Application of Environment-Friendly Aftertreatment for Their High Color Fastness

Materials ◽  
2019 ◽  
Vol 12 (24) ◽  
pp. 4209 ◽  
Author(s):  
Sanghyun Yoon ◽  
Byunghun Choi ◽  
Md Morshedur Rahman ◽  
Santosh Kumar ◽  
Shekh Md Mamun Kabir ◽  
...  
Keyword(s):  
Nitro Group ◽  
Oxygen Demand ◽  
Biological Oxygen Demand ◽  
Disperse Dyes ◽  
Color Fastness ◽  
Fastness Properties ◽  
Environment Friendly ◽  
Dyeing Process ◽  
Pyrazolone Derivatives ◽  
Dyeing Effluent

Dyeing and fastness properties of a series of 4-fluorosulfonylphenylazo-5-pyrazolone dyes on polyester were investigated in this study. The 4-nitrophenylazo-5-pyrazolone dyes were also synthesized to compare their dyeing and fastness properties on polyester with those of fluorosulfonyl-substituted analogues. The substantivity of 4-arylazo-5-pyrazolone derivatives containing a p-fluorosulfonyl group in the diazo component was lower than that of their nitro analogues which have a higher extinction coefficient and higher affinity because of the polar nitro group. They showed relatively hypsochromic color and lower chroma on polyester compared with their nitro analogues because of the relatively weaker electron-accepting power of the fluorosulfonyl group compared to the nitro group. Disperse dyeing of polyester with 4-fluorosulfonylphenylazo-5-pyrazolone disperse dyes achieved high color fastness and reduces the adverse environmental impact of the dyeing process by providing the option of performing alkali clearing instead of reductive clearing, which has high biological oxygen demand when discharged into the dyeing effluent and generates carcinogenic aromatic amines.

Development of Dyeing Process for Sulphatoethylsulphone Reactive-Disperse Dye on Natural and Synthetic Fibers

2020 ◽  
Vol 1005 ◽  
pp. 116-122
Author(s):  
Juthapak Pukngam ◽  
Porntip Tooptompong ◽  
Jantip Setthayanond ◽  
Pimonrat Hansakulwat
Keyword(s):  
Coupling Agent ◽  
Diazonium Salt ◽  
Coupling Reaction ◽  
Disperse Dye ◽  
Color Fastness ◽  
Synthetic Fibers ◽  
Dyeing Process ◽  
Pet Fibers ◽  
Excellent Color ◽  
Natural And Synthetic

Sulphatoethylsulphone reactive-disperse dye was synthesized via diazotization reaction of aminophenyl-4-(β-sulphatoethylsulphone) followed by coupling reaction of the diazonium salt with phenol as a coupling agent. The synthesized dye was well dyeable on both natural and synthetic fibers with providing orange shade on cotton, silk and nylon, while the dyed PLA and PET fibers appeared in yellow shade. The dyeing conditions for cotton and silk could be conducted using 60 g/l Na2SO4 and 20 g/l Na2CO3 at 60°C for 90 minutes whereas dyeing on PLA and PET fibers was optimally done at 110°C for 30 and 45 minutes for PLA and PET, respectively. In case of nylon, it could be dyed at 100°C for 15 minutes. The synthesized reactive-disperse dye could well dye on these 5 fibers with excellent color fastness to washing.

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