scholarly journals The content of copper and heavy metals in the multilayer soil mud from the Buchim lake under the Buchim mine's waste dump, Republic North Macedonia

Tehnika ◽  
2020 ◽  
Vol 75 (4) ◽  
pp. 297-304
Author(s):  
Todor Serafimovski ◽  
Goran Tasev ◽  
Trajce Stafilov
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Porphyry Copper ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Pollution Load ◽  
Mining Areas ◽  
Target Value ◽  
Standard Values ◽  
Almost All

The intense mineral extraction in mining areas during the last several decades has produced a large amount of waste material and tailings, which release toxic elements to the environment. The aim of the study was to determine in two vertical profiles/sections (1 and 2) the heavy metal contents of samples derived from six samples, three from each section located in the porphyry copper mine Buchim area, Republic North Macedonia. The results have been compared to new Dutchlist (DL) and Kabata-Pendias (KP) standards and the following was concluded: As values ranged 14.985÷60.131 mg kg-1 with 4 samples above the target value of the DL (29 mg kg-1 As) and 6 above standard values given in KP value (5 mg kg-1 As), in that context Co values ranged 11 ÷57 mg kg-1 with 6 values above the target value of the DL (9 mg kg-1 Co) and 5 above standard values given in KP value (12 mg kg-1 Co), Cr with range 29.32÷75.76 mg kg-1 with 6 over KP value (10 mg kg-1 Cr) and none above the target value of the DL (100 mg kg-1 Cr), Cu with range 2694÷6749 mg kg-1 with 6 samples above the target value of the DL (36 mg kg-1 Cu) and 6 above standard values given in KP value (20 mg kg-1 Cu), Ni with range 59.57÷105.98 mg kg-1 with 6 samples above the target value of the DL (35 mg kg-1 Ni) and 6 above standard values given in KP value (20 mg kg-1 Ni), Pb with range 27.06 ÷96.08 mg kg-1 with 1 sample above the target value of the DL (85 mg kg-1Pb) and 6 above standard values given in KP value (25 mg kg-1Pb), Zn with range 147÷273 mg kg-1 with 6 over target value of the DL (140 mg kg-1 Zn) and 6 above standard KP value (64 mg kg-1 Zn), V with range 34.44÷92.57 mg kg-1 with 5 over target value of the DL (42 mg kg-1 V) and one above KP value (90 mg kg-1 V).In order to compare the level of contamination, the contamination factor (𝐶𝑓 𝑖 ), degree of contamination (Cd), and pollution load index (PLI) were computed. Serious numbers were found for Cu, as, Zn, Co and Ni, which exceeded standard values at almost all samples from both vertical sections. Compared from section 1 and section 2, pollution load index increased by 13.43%, which in almost all samples was classified as heavily polluted to extremely polluted. The fact that mining activities at the Buchim Mine last for almost 40 years, the presence of heavy metals in soils at a serious level is understandable. The high level of contamination is a result of heavy metal persistence and non-biodegradability.

scholarly journals Assessment of soil heavy metal pollution in a former mining area – before and after the end of mining activities

2017 ◽  
Vol 12 (No. 4) ◽  
pp. 229-236 ◽  
Author(s):  
L. Demková ◽  
T. Jezný ◽  
L. Bobuľská
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Contamination Factor ◽  
Mining Area ◽  
Pollution Load Index ◽  
Mining Activities ◽  
Pollution Load ◽  
Limit Values ◽  
Mining Areas ◽  
Factor C

Toxicity and persistence of heavy metals, which are accumulated in the environment as the result of diverse industrial activities, represent serious environmental problem worldwide. The intense mineral extraction in mining areas has produced a large amount of waste material and tailings, which release toxic elements to the environment. The aim of the study was to determine in two time horizons (1997, 2015) the heavy metal contents of samples derived from ten sampling sites located in the former mining area of Central Spiš (Slovakia). In order to compare the level of contamination, the contamination factor (C<sup>i</sup><sub>f</sub>), degree of contamination (C<sub>d</sub>), and pollution load index (PLI) were computed. Spearman’s correlation coefficient was used in order to detect the relationships among heavy metals. A serious situation was found for Hg, Zn, and Cd, which exceeded limit values at all sampling sites within both studied years. In 1997, the average values of contamination factor have shown very high contamination with all studied heavy metals, and moderate contamination with Co. In 2015, the study area was classified as very highly contaminated with As, Hg, Zn, Cu, considerably contaminated with Ni, Cr, Pb, and Cd, while Co contamination was not detected. Since 1997 till 2015 the pollution load index decreased by about 38%, nevertheless even then almost all sampling sites were classified as heavily polluted. Despite the fact that mining activities were stopped or limited at the beginning of the 21<sup>st</sup> century, the presence of heavy metals in soils remains at a serious level. The high level of contamination is a result of heavy metal persistence and non-biodegradability.

scholarly journals Pollution Load Index (PLI) of field irrigated with wastewater of Mawaiya Drain in Naini suburbs of Allahabad District

2018 ◽  
Vol 13 (1) ◽  
pp. 159-164
Author(s):  
Arti Yadav ◽  
Pawan Kumar Yadav
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Metal Contamination ◽  
Metal Accumulation ◽  
Heavy Metal Contamination ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Heavy Metal Accumulation ◽  
Pollution Load ◽  
Maximum Accumulation

Wastewater irrigation is practiced in outskirts of several cities of India. Enhanced growth and productivity of crops possess threat of heavy metal accumulation while irrigated with wastewater. Assessment of heavy metal accumulation in soil flooded with wastewater of Mawaiya drain in Naini region of Allahabad district, using parameter of contamination factor and pollution load index (PLI). Samples of soil were taken from the fields irrigated with wastewater and analyzed for heavy metals by using Atomic Absorption Spectroscopy (AAS). The maximum accumulation of heavy metal was observed for iron in soil. Heavy metal contamination is soil was assessed by estimation of contamination factor which was observed for Cu (0.7858), Fe (296.1864), Zn (0.4304), Pb (1.1661) and Ni (1.8912). Pollution load index (PLI) used for assessment of soil contamination and observed that maximum contamination (PLI, 74.31) was in water stressed conditions of summer. Heavy metals concentration in wastewater and accumulation in soil found within WHO limits in present study which may increase if unmanaged wastewater flooding continued.

Heavy Metal Contamination in the Floodplains Along Mula River, Pune District, Maharashtra State, India

2019 ◽  
Vol 3 (1) ◽  
pp. 12-21
Author(s):  
Ashwini Supekar ◽  
Ashok Issac ◽  
Ashwini Rane
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Metal Contamination ◽  
Surface Sediments ◽  
Heavy Metal Contamination ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Pollution Load ◽  
Urban Sites

Pre-urban, urban and post-urban stretch of the Mula River in Pune District of Maharashtra (India) is examined for quantification of heavy metals (Cr, Co, Ni, Cu, Zn and Cd), calculation of the Pollution Load Index (PLI) and Contamination Factor (CF). They were estimated from the surface sediments (0-5 cm) at 10 sampling sites along the Mula river. High Cr anomaly (Max. 388.20 ppm) followed by Co (Max. 104.91 ppm), Ni (Max. 167.44 ppm), Cu (Max. 391.35 ppm), Zn (Max. 507.91 ppm) and Cd (Max. 2.38 ppm) is seen at various locations mostly encompassing the urban stretch. PLI is found to be high i.e., >1 in urban sites like Khadki, Kalyaninagar and Kharadi than the rural downstream sites. There is negligible mobility of the heavy metals and the urban floodplains are increasingly accumulating the heavy metals to a highly hazardous level.

scholarly journals Evaluation of heavy metals in agricultural soils from Katsina state Nigeria

2020 ◽  
Vol 8 (2) ◽  
Author(s):  
Aliyu Ibrahim Yaradua ◽  
Adamu Jibrin Alhassan ◽  
Abdullahi Nasir ◽  
Kabir Ibrahim Matazu ◽  
Aminu Usman ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Enrichment Factor ◽  
Agricultural Soil ◽  
Agricultural Soils ◽  
Sampling Site ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Soil Samples ◽  
Pollution Load

This work contributes to the monitoring of Agricultural soil pollution in Katsina State, North western Nigeria by assessing the degree of heavy metal pollution in Agricultural soil samples. The study was conducted in the year 2017 within some catchment areas located within the 3 senatorial zones that constitute to make up the state (Katsina senatorial zone: Birchi, Dutsinma and Katsina; Daura senatorial zone: Daura, Ingawa and Zango; Funtua senatorial zone: Dabai, Funtua, Kafur, Malunfashi and Matazu).  Analysis for the concentration of these heavy metals; Cr, Cd, Fe, Ni, Mn, Pb and Zn was conducted by the use of AAS (by Atomic Absorption Spectrophotometry) method. . Several indices were used to assess the metal contamination levels in the Agricultural soil samples, namely; Geo-accumulation Index (Igeo), Enrichment Factor (EF), Contamination Factor (CF), Degree of Contamination (Cd) and Pollution Load Index (PLI). The result of this study has shown that generally among the heavy metals evaluated, the highest concentration was observed for Fe (range: 20.195-38.347 ppm), followed by Zn (range: 0.528-1.134 ppm), Pb (range: 0.256-0.627 ppm), Mn (range: 0.261-0.572 ppm) and Cr (range: 0.093-0.344 ppm). While Cd has the lowest concentration (range: 0.022-0.043 ppm). For all the site sampled the heavy metal Ni was below detection level (BDL). From the results of heavy metals I-geo values, according to Muller’s classification,  soil samples from Birchi, Daura, Dutsinma, Kafur and Zango were unpolluted (class 0) while soil samples from Dabai, Funtua, Ingawa, Katsina, Malunfashi and Matazu are moderately polluted (class 1). The result for the enrichment factor has shown that with the exception of the heavy metal Fe, which shows significant enrichment for all the sites sampled all the other heavy metals show deficiency to minimal enrichment. Also based on the contamination factors for all soil samples the heavy metal Fe has a CF values range of 1.2861-2.3240, indicating that the Agricultural soil samples are moderately contaminated with Fe. In contrast, the rest of the heavy metals exhibit low contamination in general. The value of PLI ranges from 0.2408 to 0.4935, indicating unpolluted to moderate pollution, with the sampling site for Katsina displaying the highest PLI value while the sampling site of Ingawa has the lowest PLI. The Eri values for all samples are all < 40, presenting low ecological risk.  The results suggest that the Agricultural soils samples from Katsina state has low contamination by the heavy metals evaluated.Key words: Agricultural soils, Heavy metals, Katsina state, Pollution load index, Contamination factor.

Environmental Susceptibility: Soil Contamination of Heavy Metals in the Territory of E-Waste Recycling Area

2017 ◽  
Vol 3 (01) ◽  
pp. 25-31 ◽  
Author(s):  
Charu Gangwar ◽  
Aprajita Singh ◽  
Raina Pal ◽  
Atul Kumar ◽  
Saloni Sharma ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Metal Contamination ◽  
Heavy Metal Contamination ◽  
Negative Impact ◽  
Contamination Factor ◽  
Industrial Area ◽  
Waste Recycling ◽  
Pollution Load Index ◽  
Physiological Analysis

E-waste is a popular name given to those electronic products nearing the end of their useful life which has become a major source of heavy metal contamination in soil and hence, became the global concern. Various samples of soil were collected from different sites and were determined for heavy metal analysis by the ICP-AAS after the digestion process. The main source of contamination is illegal e-waste recycling activities such as burning of PCB's acid baths etc. Different soil indices like contamination factor, I-geo, pollution load index, were calculated to determine the quality of the soil. Results indicate that e-waste recycling and industrial area are strongly contaminated by the heavy metals. Physiological analysis of soil revealed that e-waste processing and industrial activities decrease the soil pH and organic matter while enhancing the electrical conductivity of soil. The exceedance of metal contamination imposed negative impact to the soil environment and human health.

scholarly journals Assessment of heavy metals with ecological risk of soils in the industrial vicinity of Tangail district, Bangladesh

2018 ◽  
Vol 6 (1) ◽  
pp. 108 ◽  
Author(s):  
Ram Proshad ◽  
Md. Saiful Islam ◽  
Tapos Kormoker
Keyword(s):  
Heavy Metals ◽  
Enrichment Factor ◽  
Ecological Risk ◽  
Contamination Factor ◽  
Principal Component ◽  
Potential Ecological Risk ◽  
Pollution Load Index ◽  
Pollution Load ◽  
Cd Contamination ◽  
The Mean

This study was conducted to assess the ecological risk of heavy metals in soils collected from the industrial vicinity of Tangail district in Bangladesh. In this study, the levels of six heavy metals namely chromium (Cr), nickel (Ni), copper (Cu), arsenic (As), cadmium (Cd), and lead (Pb) in 15 sampling sites around the industrial vicinity of Tangail district in Bangladesh were assessed. The mean concentration of Cr, Ni, Cu, As, Cd and Pb in studied soils were 11.56, 23.92, 37.27, 6.11, 2.01, and 17.46 mg/kg, respectively. Certain indices, including the enrichment factor (EF), contamination factor (Cif), geoaccumulation index (Igeo), pollution load index (PLI), toxic unit analysis, and principal component analysis (PCA) were used to assess the ecological risk. The enrichment factor of all the studied metals for all sampling sites were in the descending order of Cd > Cu > As > Pb >Ni > Cr. The contamination factor values revealed that the studied soils were highly impacted by Cd. The pollution load index (PLI) values of Cd were higher than 1, indicating the progressive deterioration of soil due to Cd contamination. In the context of potential ecological risk (PER), soils from all sampling sites showed moderate to very high potential ecological risk.

scholarly journals Accumulation and toxicological risk assessment of Cd, As, Pb, Hg, and Cu from topsoils of school playgrounds at Obio-Akpor LGA Rivers State Nigeria

2017 ◽  
Vol 5 (1) ◽  
pp. 38 ◽  
Author(s):  
Okereke Chioma ◽  
Agomuo Emmanuel ◽  
Amadi Peter
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Hazard Quotient ◽  
Hazard Index ◽  
Contamination Factor ◽  
Enrichment Factors ◽  
Pollution Load Index ◽  
Anthropogenic Sources ◽  
Adverse Health Effects ◽  
School Playgrounds

The adverse health effects associated with heavy metal pollution have become a subject of topical discussion. Using standard methods, this study evaluated the accumulation and toxicological risks of heavy metal deposition on top soils of school playgrounds in Obio-Akpor LGA. Results obtained from the top soils, sampled from 10 different schools showed that the concentration of heavy metals assessed, followed the trend; Hg<As<Cd<Pb<Cu. Marginal differences between the test and control samples were observed for the geoaccumulation index of the heavy metals except for copper. For the contamination factor, FCUA had the least results for cadmium (0.31) but highest in arsenic (0.016) while OPS, UDPS and RBPS recorded the highest contamination factor for lead, mercury, and copper respectively. The results for the pollution load index and degree of contamination of the test sites showed that the sites were unpolluted and had low contamination status, while the enrichment factors showed the deposition of only cadmium to be of a natural origin, and the rest of the heavy metals resulted from anthropogenic sources. The trend from the hazard quotient was Pb>Hg>Cu>Cd>As while the highest (0.0213) and least (0.0162) total hazard index value occurred at RBPS and MOM respectively. These values obtained for this study indicate that the school playground's soils are still within the recommended heavy metal content safe levels.

Monitoring and assessing heavy metals in topsoils as potential diffuse pollutants in the Pyeongchang River Basin, Korea

2010 ◽  
Vol 61 (12) ◽  
pp. 3156-3161 ◽  
Author(s):  
M. I. Kabir ◽  
H. Lee ◽  
G. Kim ◽  
T. Jun
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Ecological Risk ◽  
Metal Contamination ◽  
Heavy Metal Contamination ◽  
Risk Index ◽  
Significant Risk ◽  
Pollution Load Index ◽  
Pollution Load ◽  
Ecological Risk Index

Topsoils, mainly from crop fields, orchards, forests, and barns around the Pyeongchang River, were collected to investigate their heavy metal concentrations. Pollution load index, ecological risk index, and enrichment factor were applied to assess levels of heavy metal contamination for topsoils. The concentrations of cadmium (Cd) (1.7 mg/kg) and chromium (Cr) (4.1 mg/kg) exceeded the troublesome level in one site, whereas zinc (Zn) (396.7 to 711.1 mg/kg) and nickel (Ni) (40.1 to 95.3 mg/kg) in several topsoils exceeded the troublesome to countermeasure levels, according to soil contamination standards for the study areas. A significant risk of contamination was observed for mercury (Hg) by all indices, although the concentration in most of the topsoils was below the guideline. As expected, a positive linear correlation was observed for the values of pollution load index and ecological risk index, demonstrating lower heavy metal contamination in upstream areas compared to those downstream. High to extremely high ecological risk was observed in several samples for Zn and Ni, while all of the soils were unpolluted to slightly polluted, according to the pollution load index. A baseline study was not performed earlier for these sites, so these assessed values of heavy metals should be used as reference values for further assessment.

scholarly journals Risk and Toxicity Assessments of Heavy Metals in Tympanotonus fuscatus and Sediments from Iko River, Akwa Ibom State, Nigeria

2020 ◽  
pp. 38-47
Author(s):  
U. U. Ubong ◽  
I. O. Ekwere ◽  
E. E. Ikpe
Keyword(s):  
Heavy Metals ◽  
Risk Assessment ◽  
Dietary Intake ◽  
Human Health ◽  
Geoaccumulation Index ◽  
Hazard Index ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Pollution Load ◽  
High Degree

This study evaluates the physico-chemical parameters and heavy metals in water, sediments and Tympanotonus fuscatus obtained from three sample sites along Iko River in Eastern Obolo LGA, AkwaIbom State. The heavy metal analysis results on Pb, Cd and Ni in sediments and Tympanotonus fuscatus were used to estimate the human health and ecological risk assessment of the study area. The human health risk assessment tools utilized in this study were estimated dietary intake (EDI), total hazard quotient (THQ) and hazard index (HI) while sediment pollution parameters evaluated were contamination factor (CF), contamination degree (CD), pollution load index (PLI) and geoaccumulation index (Igeo). Results obtained showed that EDI of Cd in periwinkle in the study sites ranged from 0.2 – 6.4 µg/kg-bw/day and exceeded the provisional tolerable dietary intake (PTDI), while EDI for Pb (0.0004 – 2.6 µg/kg-bw/day) and Ni (0.32 – 2 µg/kg-bw/day) was within the limit for all sites, except Ni in site II (34 µg/kg-bw/day) which was higher than the PTDI of 5 µg/kg-bw/day. The THQ of Cd in all sites was greater than 1, while Pb and Ni generally recorded THQ < 1. The hazard index (HI) was as follows: site I (2.36), sites II (24.44) and site III (6.5), highlighting a potential hazardous effect to humans as a result of the consumption of Tympanotonus fuscatus obtained from site II and III. The sediment pollution assessment revealed that the contamination factor (CF) and geoaccumulation index, Igeo of Cd were far above the permissible limits while Pb and Ni were mostly within limits. The estimated contamination degree (CD) and pollution load index (PLI) showed a high degree of pollution, which can be mainly attributed to the high degree of Cd contamination in the sediment. Therefore, the area under investigation is highly polluted and the periwinkle obtained from Iko river in the study area is unfit for human consumption.

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