Contact Angle Hysteresis – Advantages and Disadvantages: A Critical Review

2020 ◽  
Vol 8 (1) ◽  
pp. 47-67
Author(s):  
Andrew Terhemen Tyowua ◽  
Stephen Gbaoron Yiase
Keyword(s):  
Contact Angle ◽  
Contact Angle Hysteresis ◽  
Theoretical Models ◽  
Contact Angles ◽  
Solid Surfaces ◽  
Advantages And Disadvantages ◽  
Volatile Liquid ◽  
Receding Contact ◽  
Rain Drops ◽  
The Difference

The existence of contact angle hysteresis – the difference between the values of the advancing and receding contact angles – is evident in nature (e.g. sticking of rain drops to car windscreens and window panes) and many industrial processes (e.g. surface coating, spraying, and dyeing of fabrics). This phenomenon is often viewed as a nuisance, but it is advantageous in many processes including dip and spin coating, spraying, and painting. With the early theoretical framework of Thomas Young, Robert Wenzel, and A. B. D. Cassie and S. Baxter, describing the wettability of solid surfaces and by extension contact angle, contact angle hysteresis has been deeply investigated. We review here the various ways of measuring contact angle and, consequently, contact angle hysteresis as well as related theoretical models. The successes and limitations of these models are highlighted. We conclude with the advantages and disadvantages of contact angle hysteresis whose presence in many processes is often considered as a nuisance, especially when "coffee stain" forms from the evaporation of a volatile liquid drop containing nonvolatile components.

The Surface Modification with Fluorocarbon Thin Films for the Prevention of Stiction in Mems

1998 ◽  
Vol 518 ◽  
Author(s):  
Sang-Ho Lee ◽  
Myong-Jong Kwon ◽  
Jin-Goo Park ◽  
Yong-Kweon Kim ◽  
Hyung-Jae Shin
Keyword(s):  
Contact Angle ◽  
Contact Angle Hysteresis ◽  
Contact Angles ◽  
Fluorocarbon Films ◽  
Perfluorodecanoic Acid ◽  
Large Hysteresis ◽  
Static Contact ◽  
Receding Contact ◽  
Highly Hydrophobic ◽  
Receding Contact Angle

AbstractHighly hydrophobic fluorocarbon films were prepared by the vapor phase (VP) deposition method in a vacuum chamber using both liquid (3M's FC40, FC722) and solid sources (perfluorodecanoic acid (CF3(CF2)8COOH), perfluorododecane (C12F26)) on Al, Si and oxide coated wafers. The highest static contact angles of water were measured on films deposited on aluminum substrate. But relatively lower contact angles were obtained on the films on Si and oxide wafers. The advancing and receding contact angle analysis using a captive drop method showed a large contact angle hysteresis (ΔH) on the VP deposited fluorocarbon films. AFM study showed poor film coverage on the surface with large hysteresis. FTIR-ATR analysis positively revealed the stretching band of CF2 groups on the VP deposited substrates. The thermal stability of films was measured at 150°C in air and nitrogen atmospheres as a function of time. The rapid decrease of contact angles was observed on VP deposited FC and PFDA films in air. However, no decrease of contact angle on them was observed in N2.

Degradation of Hydrophobic Surface Coatings Under Water Exposure

2018 ◽  
Author(s):  
Matthew A. Trapuzzano ◽  
Rasim Guldiken ◽  
Andrés Tejada-Martínez ◽  
Nathan B. Crane
Keyword(s):  
Contact Angle ◽  
Material Selection ◽  
Contact Angle Hysteresis ◽  
Hydrophobic Surface ◽  
Contact Angles ◽  
Water Exposure ◽  
Angle Measurements ◽  
Degradation Rates ◽  
Contact Angle Measurements ◽  
Receding Contact

Many important processes depend on the wetting of liquids on surfaces. Wetting is commonly controlled through material selection, coatings, and/or surface texture, however these means are sensitive to environmental conditions. Some “hydrophobic” fluoropolymer coatings are sensitive to extended water exposure as evidenced by declining contact angles and increasing contact angle hysteresis. Understanding degradation of these coatings is critical to processes that employ them. To accomplish this, contact angle measurements were taken before, during, and after slides coated with FluoroSyl 3750 or Cytop were submerged in water, or vibrated while covered in water. Both methods demonstrated similar changes in advancing contact angle though vibration increased degradation rates significantly. However, it does not simply accelerate the process as different trends are apparent in receding contact angles. The FluoroSyl 3750 showed no clear degradation under either condition. Surface profilometry did not detect any surface morphology differences that might cause contact angle change.

Wetting

Surfactants ◽  
2019 ◽  
pp. 427-464
Author(s):  
Bob Aveyard
Keyword(s):  
Contact Angle ◽  
Solid Surface ◽  
Contact Angles ◽  
Surface Forces ◽  
Solid Surfaces ◽  
Surface Topology ◽  
Spreading Coefficient ◽  
Surfactant Solutions ◽  
Receding Contact ◽  
Solid Liquid

Wetting of one liquid by another can be understood in terms of the spreading coefficient; the relevance of surface forces to wetting is also explained. If a small liquid drop does not spread, it forms a lens whose shape is determined by the various interfacial tensions. The wetting of solids is characterized by the contact angle θ‎ of the liquid with the solid surface; θ‎ usually depends on how a configuration is reached and advancing and receding contact angles are defined. It is often useful notionally to split solid/liquid tensions into polar and nonpolar contributions in the treatment of wetting. Effects of surfactant on the wetting of both hydrophobic and hydrophilic solids by water are explored. Surface topology can greatly influence wettability, and superhydrophobic solid surfaces exist widely in nature. Finally some dynamic aspects of wetting of solid surfaces by surfactant solutions are described briefly.

CHARACTERIZATION OF DYNAMIC WETTING OF PLASMA-TREATED PTFE FILM

2007 ◽  
Vol 14 (04) ◽  
pp. 821-825 ◽  
Author(s):  
Q. F. WEI ◽  
Y. LIU ◽  
F. L. HUANG ◽  
S. H. HONG
Keyword(s):  
Contact Angle ◽  
Plasma Treatment ◽  
Surface Properties ◽  
Contact Angle Hysteresis ◽  
Frictional Coefficient ◽  
Dynamic Contact Angle ◽  
Contact Angles ◽  
Dynamic Wetting ◽  
Ptfe Film ◽  
Receding Contact

Polytetrafluoroethylene (PTFE) has been increasingly used in many industries due to its low frictional coefficient and excellent chemical inertness. The surface properties of PTFE are of importance in various applications. The surface properties of PTFE can be modified by different techniques. In this study, PTFE film was treated in oxygen plasma for improving surface wettability. The effects of plasma treatment on dynamic wetting behavior were characterized using Scanning Probe Microscopy (SPM), Fourier transform infrared spectroscopy (FTIR), and dynamic contact angle (DCA) measurements. SPM observations revealed the etching effect of the plasma treatment on the film. The introduction of hydrophilic groups by plasma treatment was detected by FTIR. The roughened and functionalized surface resulted in the change in both advancing and receding contact angles. Advancing and receding contact angles were significantly reduced, but the contact angle hysteresis was obviously increased after plasma treatment.

Contact-angle hysteresis induced by pulmonary surfactants

1983 ◽  
Vol 54 (2) ◽  
pp. 420-426 ◽  
Author(s):  
B. A. Hills
Keyword(s):  
Contact Angle ◽  
Pulmonary Surfactant ◽  
Contact Angle Hysteresis ◽  
Hysteresis Loops ◽  
Contact Angles ◽  
Published Data ◽  
Hydrophilic Surfaces ◽  
Glass Slides ◽  
Dipalmitoyl Lecithin ◽  
Receding Contact

Hydrophilic surfaces in the form of glass slides have been coated with monolayers of three of the major components of pulmonary surfactant, and the wettabilities of the resulting surfaces have been studied by applying a single drop of saline. As fluid was added and removed over successive cycles, there was much hysteresis between the contact angle measured by a goniometer and the location of the triple point. All three surfactants, especially dipalmitoyl lecithin, were found to impart antiwetting properties, with maximum (advancing) contact angles sometimes exceeding 90 degrees and minimum (receding) contact angles seldom less than 28 degrees. In all cases (216 cycles on 36 films) fluid receded to expose the dry subphase. The hysteresis loops agree well with a similar loop calculated from published data for a cat lung in which the pressure-volume cycle has been established for both liquid and air inflation. Contact-angle hysteresis is offered as a possible alternative to surface tension as the surface parameter primarily responsible for the interfacial contribution to compliance hysteresis in the excised lung.

Tensiometric studies on wetting. I. Some effects of surface roughness (theoretical)

1981 ◽  
Vol 59 (13) ◽  
pp. 1954-1961 ◽  
Author(s):  
Erdal Bayramli ◽  
Theodore G. M. van de Ven ◽  
Stanley G. Mason
Keyword(s):  
Surface Roughness ◽  
Contact Angle ◽  
Contact Angle Hysteresis ◽  
Solid Surfaces ◽  
Surface Slopes ◽  
Receding Contact ◽  
Receding Contact Angle ◽  
Wetting Hysteresis ◽  
Non Equilibrium ◽  
Roughness Size

The effect of roughness on the wettability of an axisymmetric cylinder is investigated theoretically by making use of equilibrium meniscus shapes on solid surfaces analogously to previous studies for drops on horizontal surfaces. Employing circumferential sinusoidal and saw-toothed grooved structure, and using mechanistic arguments, one can explain wetting hysteresis, the formation of composite surfaces, and the presence of non-equilibrium jumps during contact line motion.On unidirectionally random surfaces the maximum surface slopes mainly determine the value of the advancing, and the minimum slopes of the receding contact angle. These effects of surface slopes diminish with decreasing roughness size. Diminishing roughness size also gives rise to numerous small non-equilibrium jumps imposed upon larger jumps during wetting. The contact angle hysteresis is found to show a nearly linear relationship with the spread in the distribution of solid surface slopes.

Studying of Contact Angle Friction and Contact Angle Hysteresis (CAH) Though Force Measurements

2012 ◽  
Author(s):  
Qi Ni ◽  
Timo Marschke ◽  
Samuel Steele ◽  
Najafi Seyed ◽  
Nathan B. Crane
Keyword(s):  
Contact Angle ◽  
Contact Line ◽  
Contact Angle Hysteresis ◽  
Contact Angles ◽  
Force Measurements ◽  
Droplet Motion ◽  
Characterization Methods ◽  
Receding Contact ◽  
Novel Method ◽  
Contact Line Friction

A novel method of measuring contact line friction and contact angle hysteresis is described. In this method, a droplet is constrained between two surfaces while the surface of interest initiates motion. The results are compared to conventional characterization methods such as measuring the angle of inclined plane for droplet motion and measuring advancing and receding contact angles by infusing/withdrawing liquid from the substrate. At slow speeds, the proposed method provides a measure of the hysteresis but can also capture information about the contact line friction and viscous affects. Droplet force dependence on droplet size (height/width) is also investigated.

Anisotropic Wetting Characteristics of Biomimetic Rice Leaf Surface with Asymmetric Asperities

2020 ◽  
Vol 20 (7) ◽  
pp. 4331-4335
Author(s):  
Mu-Yeon Jang ◽  
Jeong-Woo Park ◽  
Seung-Yub Baek ◽  
Tae-Wan Kim
Keyword(s):  
Contact Angle ◽  
Leaf Surface ◽  
Contact Angle Hysteresis ◽  
Dynamic Contact ◽  
Contact Angles ◽  
Droplet Flow ◽  
Biomimetic Surfaces ◽  
Rice Leaf ◽  
The Difference ◽  
Inclined Angle

Rice leaf surface has known as having functional performances such as self cleaning and antifouling as well as directional flowing due to a unique micro structure with groove. In this study, we investigated the effects of asymmetrical cone protrusions on the surface of droplet flow through the contact angle and contact angle hysteresis of the droplet. First, static and dynamic contact angles of droplet on the rice leaf are measured. We found that the rice leaf surface has a directional flow characteristic through the difference of the contact angle hysteresis with flow directions. We also fabricated the rice leaf-like surfaces with asymmetric asperities along microgrooves using rapid prototyping technique and evaluated anisotropic wettability properties for the produced biomimetic surfaces. The experimental results show that the direction of the micro asperity tip relative to the droplet flow and its inclined angle has a very important influence on the anisotropic flow. This research can help to clarify the anisotropic wettability by the surface structure.

scholarly journals Biomimetic Approach for the Elaboration of Highly Hydrophobic Surfaces: Study of the Links between Morphology and Wettability

Biomimetics ◽  
2021 ◽  
Vol 6 (2) ◽  
pp. 38
Author(s):  
Quentin Legrand ◽  
Stephane Benayoun ◽  
Stephane Valette
Keyword(s):  
Contact Angle ◽  
Ginkgo Biloba ◽  
Contact Angle Hysteresis ◽  
Contact Angles ◽  
Textured Surfaces ◽  
Replication Process ◽  
Wetting Behavior ◽  
Static Contact ◽  
Biomimetic Approach ◽  
Highly Hydrophobic

This investigation of morphology-wetting links was performed using a biomimetic approach. Three natural leaves’ surfaces were studied: two bamboo varieties and Ginkgo Biloba. Multiscale surface topographies were analyzed by SEM observations, FFT, and Gaussian filtering. A PDMS replicating protocol of natural surfaces was proposed in order to study the purely morphological contribution to wetting. High static contact angles, close to 135∘, were measured on PDMS replicated surfaces. Compared to flat PDMS, the increase in static contact angle due to purely morphological contribution was around 20∘. Such an increase in contact angle was obtained despite loss of the nanometric scale during the replication process. Moreover, a significant decrease of the hysteresis contact angle was measured on PDMS replicas. The value of the contact angle hysteresis moved from 40∘ for flat PDMS to less than 10∘ for textured replicated surfaces. The wetting behavior of multiscale textured surfaces was then studied in the frame of the Wenzel and Cassie–Baxter models. Whereas the classical laws made it possible to describe the wetting behavior of the ginkgo biloba replications, a hierarchical model was developed to depict the wetting behavior of both bamboo species.

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