Droplet Flow Assisted Electrocatalytic Oxidation of Selected Alcohols under Ambient Condition

This study reports using a droplet flow assisted mechanism to enhance the electrocatalytic oxidation of benzyl alcohol, 2-phenoxyethanol, and hydroxymethylfurfural at room temperature. Cobalt phosphide (CoP) was employed as an active electrocatalyst to promote the oxidation of each of the individual substrates. Surface analysis of the CoP electrocatalyst using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), as well as electrochemical characterization, revealed that it had excellent catalytic activity for each of the substrates studied. The combined droplet flow with the continuous flow electrochemical oxidation approach significantly enhanced the conversion and selectivity of the transformation reactions. The results of this investigation show that at an electrolysis potential of 1.3 V and ambient conditions, both the selectivity and yield of aldehyde from substrate conversion can reach 97.0%.

Ultra-dispersed particles of water-soluble and water-insoluble substances formed from gas-droplet flows

The work is devoted to the experimental study of the ultra dispersed particles formation process, which is essentially a fundamental problem of heat and mass transfer in gas-droplet flows under phase transformation conditions. Various methods of generating and controlling the gas-droplet flow parameters are considered. The description of the created equipment and diagnostic methods for studying gas-droplet flows is given. The particle size distribution functions are obtained using an aerosol particle spectrometer. The possibility of controlling the parameters of ultrafine particles of water-soluble and water-insoluble substances (medications) formed under evaporation of microdroplets of solutions and suspensions is shown experimentally. An attempt to reconstruct the distribution functions of microdroplets and their average dimension from measurements of the parameters of ultrafine particles formed after complete evaporation of the droplets is made.

Study on the process of droplet formation when liquid flows out of a capillary

This article presents the theoretical background for the justification of the parameters of the rotating sprayer. Theoretical studies show that an increase in the rotation frequency of the disk at a constant air flow velocity leads to a minimum median mass diameter of the droplets. Therefore, when justifying the diameter of the sprayed droplets, it is necessary to consider the combination of the disk rotation speed and the axial velocity of the air flow. To obtain high-quality air-droplet flow, the initial speed of the main droplets discharged from the periphery of the spray disc should be less than the air velocity and rotational frequency Pavlovskyi spray is recommended to be applied with in ω=60… 200 c1.

Interaction of a liquid jet with a co-current gas flow inside the nozzle and under ejection into vacuum

The structure of a gas-droplet flow arising under gas outflow with liquid jet injected into it from a supersonic nozzle into vacuum is studied experimentally. Possibility of the flow structure control in order to obtain droplets of a certain size, composition, and velocity, is considered. The liquid was injected into the co-current gas flow in the prechamber of the supersonic nozzle and then flowed out into the vacuum chamber in the form of a gas-droplet jet. Using the developed technique of droplet deposition on paper substrates, the effect of the Reynolds number of the gas and the pressure in the vacuum chamber on the angular distribution of droplet phase behind the nozzle exit is investigated.

Spontaneous motion of droplet in tubes: The effects of surface wettability and segment length

This work studies the spontaneous droplet flow in tubes with different wettability gradient and number of segments by using a particle-based numerical method, many-body dissipative particle dynamics (MDPD). The study aims to understand how the different contact angle sets (gradient contact angle distribution along with different segments of a tube) and the number of segments could affect the droplet flow velocity and time to reaching a stable state. Simulation results show that even with the same wettability gap, a contact angle set with higher values of contact angle along the tube segments can drive the droplet to flow faster in the tubes; moreover, with the same contact angle set and tube length, the tubes with fewer segments can allow a faster flow of droplet, thus a shorter time to reaching the stable state. The numerical findings in this work can provide a new idea and direction for the design of droplet-based microfluidic systems.