Solvent effect and Activation Parameters: A Kinetic Reaction of Ethyl Caprylate in Water-Acetone Media

The kinetic result of hydrolysis of Ethyl Caprlyate has been investigated at different composition of aqueous-organic solvent with Acetone (30-70% v/v) over the temperature range of 20 to 400c. The calculated result follows second order kinetics and is observed that the rate decreases with increasing proportion of Acetone. This behavior is attributed electrostatic nature that various solvent-solute interaction in reaction media. Linear plots of Logk against water concentration shows that equilibrium shifted from dense form to bulky form. Iso-kinetic temperature has been determined with the help of slopes of (ΔH*) versus (ΔS*). Thermodynamic parameter has been calculated with the help of Wynne-Jones and Eyring equation.

Comparative between different Natural Sources of Activated Carbon for the Removal Reactive Green Dye from Aqueous Solution

Water pollution is one of the biggest problems facing us, so it requires the need to develop a very high-efficiency and inexpensive absorbent material from natural surfaces and compare it with expensive commercial sorbents. Where in this study an absorbent substance was prepared from the natural surfaces of Syzgium Aromaticum Flower Bud (SAFB), Nigella Sativa (NS) Converted to activated carbon to activated carbon Activated (SAFB), and Activated (NS), as these surfaces are characterized by high porosity, cheap price and very high efficiency in removing dye. The composite was illustrated via different analysis apparatus included FTIR, and FE-SEM, The adsorption result were fitted with Freundlich isotherms. The experimental kinetic result at different primary reactive green dye concentrations, were also analyzed through first model, second model and Elovich model. The obtained data appear that the model pseudo-first model fits the adsorption kinetic result through R2 0.96028, R2 0.9486, R2 0.9016 and R2 0.9620 of SAFB and ACTIVE-SAFB and Nigella Sativa (NS) and Activated (NS) in the same order.

A COMPARISON BETWEEN BIOSORPTION AND BIOACCUMULATION OF FLUORIDE FROM WASTE WATER.

Objective: The comparison between the properties of two removal methods viz. adsorptive removal (biosorption) and simultaneous adsorption and bioaccumulation (SAB) of fluoride from waste water was investigated.Methods: In the present study, bioaccumulation study was done on Sweet Lemon peel. Acinetobacter baumannii (Mtcc no-11451) is a water living microorganism which survives in waste water. Microorganism (Acinetobacter baumannii (Mtcc no-11451)) immobilized on the surface of Sweet Lemon peel. The size of microorganism is greater than the pore size of adsorbent. Active sites of the adsorbent are blocked due to immobilization of microorganism on the surface of adsorbent. Different optimizing parameters are studied during the experiments like adsorbent dose, pH, initial concentration and contact time for bio bioaccumulation process.Results: It was observed that adsorption and bioaccumulation process execute simultaneously but mainly bioaccumulation is responsible for removal of fluoride. The removal efficiency of fluoride sees a drastic increase from 59.59 % to 99.49 % in optimum conditions. It is to be noted that simple adsorption process removal efficiency was 95.795 % at optimum time (60 min), pH 4.0 and dose 10 g/l. Adsorption isotherm parameters are well fitted for Freundlich whereas simple adsorption follow Langmuir isotherm model.Conclusion: The removal of fluoride occurred due to the accumulation by bacteria. Kinetic result revealed that bioaccumulation is a slower process. Bioaccumulation process increase the removal efficiency but it is very time consuming and costly as compare to the simple adsorption process.

Degradation and Persistence of Carbofuran in Peanut and Soil in Field Trails as Determined by GC-MS

This paper investigated the analytical method of degradation and persistence of carbofuran, its metabolite 3-hydroxy carbofuran in peanut seeds, fronds and soils in field trial using gas chromatography mass spectrometry (GC-MS). Carbofuran 3GR formulation (3g a.i./100g) was applied at dosages of 2250 and 3375g ha-1in furrow at sowing peanut seeds in the fields of Langfang, Hebei province and Jinan, Shandong province, China, respectively. The soil and the plant samples were collected at different intervals and the residues of carbofuran and 3-hydroxy carbofuran were analyzed by GC-MS. The degradation kinetic result showed that the degradation of carbofuran in peanut fronds in Jinan and Langfang can be well predicted with equation: C=1.2839e-0.1733tand C=0.5731e-0.1567t, with a half-life about 4.0 and 4.4 days respectively. For the degradation of carbofuran in soils, the result coincides well with equations: C= 4.2057e-0.2229t, and C= 5.4014e-0.1499t, with half-life of 3.1 and 4.6 days for Jinan and Langfang, respectively. The pH, organic matter and clay content as well as the climatic temperature play an important role in the degradation of carbofuran in soils. 3-hydroxy carbofuran dissipated rapidly both in peanut fronds and soils, it was not detectable 7 days after treatment for all treatment, the concentration of carbofuran and 3-hydroxy carbofuran in peanut seeds at harvest time were lower than either the maximum residue limit in China or the EUs maximum residue limit of 0.1 mg kg1. Based on the data from this investigation, the use of carbofuran in peanut could be considered to be safe.

Decolorisation of Methyl Orange Solution with KIO3 under UV Irradiation

This report has shown that the dye of Methyl Orange (MO) in water can be decolorized effectively in the presence of KIO3 under UV irradiation. Decolorisation efficiency of MO increases as the loading of KIO3 increases and has no an optimal amount of KIO3 in this case. The kinetic result shows that the decolorisation reaction is a pseudo first-order reaction when the concentration of MO is below 10 mgL-1. The influences of the pH value and hydroxyl radical scavengers on the decolorisation reaction were investigated in detailed. Several observations indicate that the mechanism is not the attack of hydroxyl radicals in MO decolorisation with KIO3 under UV irradiation. More considerations should be focused on the underlying possible decolorisation mechanism of MO with KIO3 under UV irradiation.