Contact-Mediated Nucleation of Subcooled Droplets in Melt Emulsions: A Microfluidic Approach

The production of melt emulsions is mainly influenced by the crystallization step, as every single droplet needs to crystallize to obtain a stable product with a long shelf life. However, the crystallization of dispersed droplets requires high subcooling, resulting in a time, energy and cost intensive production processes. Contact-mediated nucleation (CMN) may be used to intensify the nucleation process, enabling crystallization at higher temperatures. It describes the successful inoculation of a subcooled liquid droplet by a crystalline particle. Surfactants are added to emulsions/suspensions for their stabilization against coalescence or aggregation. They cover the interface, lower the specific interfacial energy and form micelles in the continuous phase. It may be assumed that micelles and high concentrations of surfactant monomers in the continuous phase delay or even hinder CMN as the two reaction partners cannot get in touch. Experiments were carried out in a microfluidic chip, allowing for the controlled contact between a single subcooled liquid droplet and a single crystallized droplet. We were able to demonstrate the impact of the surfactant concentration on the CMN. Following an increase in the aqueous micelle concentrations, the time needed to inoculate the liquid droplet increased or CMN was prevented entirely.

Scanning polarization lidar LOSA-M3: opportunity for research of crystalline particle orientation in the ice clouds

The article describes a scanning polarization lidar, LOSA-M3, developed at the V. E. Zuev Institute of Atmospheric Optics, the Siberian Branch of the Russian Academy of Sciences (IAO SB RAS), as part of the common use center “Atmosphere”. The first results of studying the crystalline particle orientation by means of this lidar are presented herein. The main features of the LOSA-M3 lidar are the following: (1) an automatic scanning device, which allows changing the sensing direction in the upper hemisphere at the speed up to 1.5∘ s−1 with the accuracy of the angle measurement setting of at least 1 arcmin, (2) separation of the polarization components of the received radiation that is carried out directly behind the receiving telescope without installing the elements distorting polarization, such as dichroic mirrors and beam splitters, and (3) continuous alternation of the initial polarization state (linear–circular) from pulse to pulse that makes it possible to evaluate some elements of the scattering matrix. For testing lidar performance several series of measurements of the ice cloud structure in the zenith scan mode were carried out in Tomsk in April–June 2018. The results show that the degree of horizontal orientation of particles can vary significantly in different parts of the cloud. The dependence of signal intensity on the tilt angle reflects the distribution of particle deflection relative to the horizontal plane and is well described by the exponential dependence. The values of the cross-polarized component in most cases show a weak decline of intensity with the angle. However, these variations are smaller than the measurement errors. We can conclude that they are practically independent of the tilt angle. In most cases the scattering intensity at the wavelength of 532 nm has a wider distribution than at 1064 nm.

Interfacial properties of lipid sponge-like nanoparticles and the role of stabilizer on particle structure and surface interactions

Stabilizer P80 concentrated to lipid liquid crystalline particle surface, but contributes also to the inner sponge phase structure. Particles spread on surfaces to form bilayers.

Fabrication of Micro-Parts with High-Aspect Ratio Micro-Hole Array by Micro-Powder Injection Molding

The present study investigated high-aspect ratio micro-hole array parts which were made by ZrO2 micro-powder with different particle sizes and micro-powder injection molding technology. It analysed the influence of particle sizes on feedstock, debinding and sintering of ceramic nozzles with multi-micro-holes. The forming quality of ceramic nozzles with multi-micro-holes was discussed in this paper. The results show that the two mixed ZrO2 feedstocks have fine uniformity. The average deviation of the feedstock made with 200 nm powder was −2%, and the average deviation of the feedstock made with 100 nm powder was −7.1%. The sample showed certain sintering characteristics which provided better strength (11.10 MPa) to parts after debinding. The linear shrinkage and the density of the two powder samples at different sintering temperatures increased as the sintering temperature increased. If the temperature continued to increase, the linear shrinkage and the density decreased. The highest hardness and flexural strength values of the ZrO2 sample with 200 nm powder used were: 1265.5 HV and 453.4 MPa, and the crystalline particle size was 0.36 μm. The highest hardness and flexural strength values of the ZrO2 sample with 100 nm powder used were: 1425.8 HV and 503.6 MPa, and the crystalline particle size was 0.18 μm. The ceramic nozzles with multi-micro holes shrunk to nearly the same axial, radial and circumferential directions during sintering. After sintering, the roundness of ceramic micro-hole met the user requirements, and the circular hole had a high parallelism in the axial direction. The micropore diameter was 450 ± 5 μm, and it was possible to control the dimensional accuracy within 1.5% after sintering. The study presented a superior application prospect for high-aspect ratio micro hole array parts in aerospace, electronics and biomedicine.