Instrumental Methods for Cage Occupancy Estimation of Gas Hydrate

Studies revealed that gas hydrate cages, especially small cages, are incompletely filled with guest gas molecules, primarily associated with pressure and gas composition. The ratio of hydrate cages occupied by guest molecules, defined as cage occupancy, is a critical parameter to estimate the resource amount of a natural gas hydrate reservoir and evaluate the storage capacity of methane or hydrogen hydrate as an energy storage medium and carbon dioxide hydrate as a carbon sequestration matrix. As the result, methods have been developed to investigate the cage occupancy of gas hydrate. In this review, several instrument methods widely applied for gas hydrate analysis are introduced, including Raman, NMR, XRD, neutron diffraction, and the approaches to estimate cage occupancy are summarized.

A Solution to Sand Production from Natural Gas Hydrate Deposits with Radial Wells: Combined Gravel Packing and Sand Screen

Sand production is one of the main problems restricting the safe, efficient and sustainable exploitation of marine natural gas hydrate. To explore the sand-control effects of gravel packing, experiments that simulate hydrate extraction in the water-rich environment were conducted with designed hydrate synthesis and exploitation devices. Three sand control completion methods, including 120 mesh sand screen, 400 mesh sand screen, 120 mesh sand screen combined with gravel packing, are adopted. Sand and gas production rates were compared under different well types and sand control completion methods. Results show that the gas production modes of radial wells and vertical wells are almost the same at the same time due to the small experimental scale and high permeability. The sand production of the vertical well with gravel packing combined with a sand-control screen is 50% lower than that of the vertical well with sand-control screens only. Radial well with gravel packing combined with sand-control screens produced 87% less sand than screen mesh alone. The cumulative gas production and recovery rates of a radial well with the composite sand control method are better than those without gravel packing in the same development time.

Controlled Production of Natural Gas Hydrates in an Experimental Device with an Internal Circulation Circuit

For countries with limited access to conventional hydrocarbon gases, methane hydrates have emerged as a potential energy source. In view of the European Union’s requirements to reduce the energy intensity of technological processes and increase energy security, it appears promising to accumulate natural gas and biomethane in the form of hydrate structures and release them if necessary. Storing gas in this form in an energy-efficient manner creates interest in developing and innovating technologies in this area. Hydrates that form in gas pipelines are generated by a more or less random process and are an undesirable phenomenon in gas transportation. In our case, the process implemented in the proposed experimental device is a controlled process, which can generate hydrates in orders of magnitude shorter times compared to the classical methods of generating natural gas hydrates in autoclaves by saturating water only. The recirculation of gas-saturated water has been shown to be the most significant factor in reducing the energy consumption of natural gas hydrate generation. Not only is the energy intensity of generation reduced, but also its generation time. In this paper, a circuit diagram for an experimental device for natural gas hydrate generation is shown with complete description, principle of operation, and measurement methodology. The natural gas hydrate formation process is analyzed using a mathematical model that correlates well with the measured hydrate formation times. Hydrates may become a current challenge in the future and, once verified, may find applications in various fields of technology or industry.

Sensitivity and Resolution of Controlled-Source Electromagnetic Method for Gas Hydrate Stable Zone

Natural gas hydrate is one of the most important clean energies and part of carbon cycle, due to the least carbon content. Natural gas hydrates depend on high pressure and low temperatures, located under seabed or permafrost. Small changes in temperature and pressure may lead gas hydrates to separate into water and gas, commonly as methane. As a powerful greenhouse gas, methane is much stronger than carbon dioxide. Therefore, it is necessary to detect the gas hydrates stable zone (GHSZ) before the methane gas escapes from GHSZ. Marine controlled source electromagnetic method (CSEM) is a useful tool to detect gas hydrate in offshore. The results from 3D CSEM method are a resistivity cube to describe the distribution of gas hydrates. In order to study the detectability of CSEM method, we simulate the sensitivity and resolution of marine CSEM synthetic data. By using the sensitivity and resolution, a simple statement may be quickly judged on the existence and occurrence range of the natural gas hydrate. In this paper, we compare the resolution of marine CSEM method with various transverse resistance. This information may help researchers find out whether the GHSZ exists or not.