Peptide-Mediated Synthesis of Zeolitic Imidazolate Framework-8: Effect of Molecular Hydrophobicity, Charge Number and Charge Location

Three amphiphilic peptides with varied molecular hydrophobicity, charge number and charge location have been designed as regulators to modulate the crystal growth of zeolitic imidazolate framework-8 (ZIF-8). All three peptides can interact with ZIF-8 to inhibit {100} facet growth and produce truncated cubic crystals. The peptide’s molecular hydrophobicity plays a dominant role in defining the final morphology and size of the ZIF-8 crystals. The peptides with less charge and higher hydrophobicity can promote nuclei formation and crystal growth to give smaller ZIF-8 crystals. However, the charge located in the center of the molecular hydrophobic region has little effect on the crystal nucleation and growth due to the shielding of its charge by molecular aggregation. The study provides insights into the effect of molecular charge and hydrophobicity on ZIF-8 crystal growth and is helpful for guiding the molecular design for regulating the synthesis of metal-organic framework materials.

Broadband generation of perfect Poincaré beams via dielectric spin-multiplexed metasurface

The term Poincaré beam, which describes the space-variant polarization of a light beam carrying spin angular momentum (SAM) and orbital angular momentum (OAM), plays an important role in various optical applications. Since the radius of a Poincaré beam conventionally depends on the topological charge number, it is difficult to generate a stable and high-quality Poincaré beam by two optical vortices with different topological charge numbers, as the Poincaré beam formed in this way collapses upon propagation. Here, based on an all-dielectric metasurface platform, we experimentally demonstrate broadband generation of a generalized perfect Poincaré beam (PPB), whose radius is independent of the topological charge number. By utilizing a phase-only modulation approach, a single-layer spin-multiplexed metasurface is shown to achieve all the states of PPBs on the hybrid-order Poincaré Sphere for visible light. Furthermore, as a proof-of-concept demonstration, a metasurface encoding multidimensional SAM and OAM states in the parallel channels of elliptical and circular PPBs is implemented for optical information encryption. We envision that this work will provide a compact and efficient platform for generation of PPBs for visible light, and may promote their applications in optical communications, information encryption, optical data storage and quantum information sciences.

The Nakano–Nishijima–Gell-Mann Formula from Discrete Galois Fields

The well known Nakano–Nishijima–Gell-Mann (NNG) formula relates certain quantum numbers of elementary particles to their charge number. This equation, which phenomenologically introduces the quantum numbers Iz (isospin), S (strangeness), etc., is constructed using group theory with real numbers R. But, using a discrete Galois field Fp instead of R and assuring the fundamental invariance laws such as unitarity, Lorentz invariance, and gauge invariance, we derive the NNG formula deductively from Meson (two quarks) and Baryon (three quarks) representations in a unified way. Moreover, we show that quark confinement ascribes to the inevitable fractionality caused by coprimeness between half-integer (1/2) of isospin and number of composite particles (e.g., three).

CHARGE-NUMBER OF PULSES-CONVERTER

It is described the charge-number of pulses-converter, which was successfully applied in the ”Program-apparatus complex for investigation of gamma- and X-rays radiations, generated by relativistic electrons in crystals” [1] at Kharkiv linear electron accelerators. This device is in the condition for high energy electron (positron) beam charge measurements with accuracy 2·10−10 C and current measurements in the range of 10−10...10−8 A.

Analysis of Bending-Induced Degradation of Orbital Angular Momentum Modes in Optical Fibers

In this work, bending-induced deterioration of orbital angular momentum (OAM) modes in ring core fiber (RCF), photonic crystal fiber (PCF), and vortex fiber (VF) was theoretically investigated: Bending losses, coupling losses, and intermodal crosstalk at the interface between straight and bent optical fibers were investigated from the modal analysis of those three types of OAM mode fibers. In addition, the degradation of a topological charge number of an OAM mode due to the bending-induced birefringence and horizontal mode asymmetry was also investigated. Our investigation revealed that, in all aspects, the PCF is most robust to bending among the three types of optical fibers, and the most serious bending-induced problem in the VF and the RCF is the degradation of the topological charge number. The allowed minimum bending radii of VF and RCF appeared to be ~15 and ~45 mm, respectively, for the specific structures considered in this work. We expect that the methodology and results of our quantitative analysis on bending-induced degradation of OAM modes will be of great use in the design of OAM mode fibers for practical use.