Determination of Optimal Diffusion Coefficients in Lake Zirahuén through a Local Inverse Problem

In this study, optimal diffusion coefficients for Lake Zirahuén, Mexico, were found under particular conditions based on images taken with a drone of a dye release experiment. First, the dye patch concentration was discretized using image processing tools, and it was then approximated by an ellipse, finding the optimal major and minor axes. The inverse problem was implemented by comparing these observational data with the concentration obtained numerically from the 2D advection–diffusion equation, varying the diffusion tensor. When the tensor was isotropic, values of K11=K22≈0.003 m2/s were found; when nonequal coefficients were considered, it was found that K11≈0.005 m2/s and K22≈0.002 m2/s, and the cross-term K12 influenced the results of the orientation of the ellipse. It is important to mention that, with this simple technique, the parameter estimation had consequences of great importance as the value for the diffusion coefficient was bounded significantly under particular conditions for this site of study.

Chitosan as a Protective Matrix for the Squaraine Dye

Chitosan was used as a protective matrix for the photosensitive dye-squaraine (2,4-bis[4-(dimethylamino)phenyl]cyclobutane-1,3-diol). The physicochemical properties of the obtained systems, both in solution and in a solid-state, were investigated. However, it was found that diluted chitosan solutions with a few percent additions of dye show an intense fluorescence, which is suppressed in the solid-state. This is related to the morphology of the heterogeneous modified chitosan films. The important advantage of using a biopolymer matrix is the prevention of dye degradation under the influence of high energy ultraviolet (UV) radiation while the dye presence improves the chitosan heat resistance. It is caused by mutual interactions between macromolecules and dye. Owing to the protective action of chitosan, the dye release in liquid medium is limited. Chitosan solutions with a few percent additions of squaraine can be used in biomedical imaging thanks to the ability to emit light, while chitosan films can be protective coatings resistant to high temperatures and UV radiation.

Dispersion in the Open Ocean Seasonal Pycnocline at Scales of 1–10 km and 1–6 days

Results are presented from two dye release experiments conducted in the seasonal thermocline of the Sargasso Sea, one in a region of low horizontal strain rate (~10−6 s−1), the second in a region of intermediate horizontal strain rate (~10−5 s−1). Both experiments lasted ~6 days, covering spatial scales of 1–10 and 1–50 km for the low and intermediate strain rate regimes, respectively. Diapycnal diffusivities estimated from the two experiments were κz = (2–5) × 10−6 m2 s−1, while isopycnal diffusivities were κH = (0.2–3) m2 s−1, with the range in κH being less a reflection of site-to-site variability, and more due to uncertainties in the background strain rate acting on the patch combined with uncertain time dependence. The Site I (low strain) experiment exhibited minimal stretching, elongating to approximately 10 km over 6 days while maintaining a width of ~5 km, and with a notable vertical tilt in the meridional direction. By contrast, the Site II (intermediate strain) experiment exhibited significant stretching, elongating to more than 50 km in length and advecting more than 150 km while still maintaining a width of order 3–5 km. Early surveys from both experiments showed patchy distributions indicative of small-scale stirring at scales of order a few hundred meters. Later surveys show relatively smooth, coherent distributions with only occasional patchiness, suggestive of a diffusive rather than stirring process at the scales of the now larger patches. Together the two experiments provide important clues as to the rates and underlying processes driving diapycnal and isopycnal mixing at these scales.

Controlled dye release from a metal–organic framework: a new luminescent sensor for water

A turn-on trace water sensor was obtained via the single-crystal to single-crystal transformation process of a metal–organic framework.

Cross-Shore Deformation of a Surfzone-Released Dye Plume by an Internal Tide on the Inner Shelf

An inner-shelf (IS) dye plume that formed following a 3.84-h early morning surfzone (SZ) dye release off of Imperial Beach, California, is analyzed with in situ and aerial remotely sensed observations. Midmorning, 5 h after release start, the IS plume extended 800 m offshore (or ≈8Lsz, where Lsz is the surfzone width) and was surface intensified. Over the next ≈2 h, the IS plume deformed (narrowed) cross-shore with the offshore front progressing onshore at ≈5 cm s−1, deepened by up to 3 m, and elongated alongshore at ≈4.5 cm s−1 km−1 (at ≈2.5Lsz). Coincident with IS plume deformation and deepening, IS isotherms also deepened, with relatively stable IS plume joint dye and temperature statistics. Offshore tracer transport and subsequent IS plume deformation and deepening likely resulted from two phases of the diurnal internal tide (DIT). During and after deformation, the IS plume did not reenter the warm surfzone, which potentially acted as a thermal barrier. High-frequency internal waves (HF IWs) propagated through the IS plume at ≈9 cm s−1 and dissipated onshore of 4Lsz. Surface HF IW signal was elevated in the plume elongation region, suggesting a linkage between plume elongation and either the DIT or HF IW. This IS plume evolution differs from previous SZ tracer releases, highlighting the effects of release timing relative to the solar cycle or the internal tide.