Accessibility of Pores to Methane in New Albany Shale Samples of Varying Maturity Determined Using SANS and USANS

The accessibility of pores to methane has been investigated in Devonian New Albany Shale Formation early-mature (Ro = 0.50%) to post-mature (Ro = 1.40%) samples. A Marcellus Shale Formation sample was included to expand the maturation range to Ro 2.50%. These are organic matter-rich rocks with total organic carbon (TOC) values of 3.4 to 14.4% and porosity values of 2.19 to 6.88%. Contrast matching small-angle neutron scattering (SANS) and ultra-small angle neutron scattering (USANS) techniques were used to generate porosity-related data before and after pressure cycling under hydrostatic (in a vacuum and at 500 bar of deuterated methane) and uniaxial stress (0 to ca. 350 bar) conditions. Our results showed that the accessible porosity was small for the samples studied, ranging from zero to 2.9%. No correlation between the accessible porosity and TOC or mineralogical composition was revealed, and the most likely explanation for porosity variation was related to the thermal transformation of organic matter and hydrocarbon generation. Pressure caused improvements in accessible porosity for most samples, except the oil window sample (Ro = 0.84%). Our data show that densification of methane occurs in nanopores, generally starting at diameters smaller than 20 nm, and that the distribution of methane density is affected by pressure cycling.

Hypozonal gold mineralisation in shear zone hosted deposits driven by fault valve action and fluid mixing: the Nalunaq deposit, Greenland

The Nalunaq deposit, Greenland, is a hypozonal, shear zone-hosted, Au deposit. The shear zone has previously been interpreted to have undergone 4 stages of deformation, accompanied by fluid flow,and vein formation. Coupled with previous trapping T estimates, fluid inclusion data are consistent with trapping of fluids with salinities between 28-45 wt. % NaCl eq., from 300-475°C during D2 and D3, with pressure varying between ∼800 and 100Mpa. The range reflects pressure cycling during seismic slip related depressurisation events. D4 fluids were lower salinity and trapped from 200-300°C, at ∼50-200Mpa during late stage normal faulting. The variation in major element chemistry is consistent with ingress of hypersaline, granitoid equilibrated fluids into the shear zone system and mixing with fluids that had reacted with the host metamorphic rocks. D4 stage fluids represent ingress of meteoric fluids into the system. Gold contents in inclusion fluids range from ∼300-10mg/kg. These data are consistent with the high P-T solubility of Au as AuHS(H2S)30 complexes, and Au deposition by decompression and cooling. The high salinities also suggest Au transport as chloride complexes may have been possible. Gold distribution was modified by the release of chemically bound or nanoscale Au during sulphide oxidation at the D4 stage.Supplementary material at https://doi.org/10.6084/m9.figshare.c.5635812

Numerical Investigation of Pressure-Cycling Induced Fatigue Failure of Wrinkled Energy Pipelines

Wrinkle defects can be complex pipeline deformities to assess and can present the potential to initiate a pipeline release incident as a result of fatigue failure due to pressure cycling, if not dealt with accordingly. Specifically, the stress distribution arising due to applied loads such as internal pressure can vary rapidly due to the complex shape along the wrinkle profile, which may introduce complexities in subsequent assessments such as fatigue life analysis. This paper presents a methodology using numerical simulation for evaluating stress concentration factors of wrinkle defects of varying geometries. A nonlinear finite element model is developed to evaluate stress concentration factors induced by wrinkle defects within steel pipelines subjected to internal pressure. Afterwards, data from full-scale laboratory tests for the wrinkled pipe specimens subjected to cyclic pressure fatigue loading is analyzed to evaluate stress concentration factors for comparable wrinkle profiles. Lastly, a comparison between the results of the stress concentration factors evaluated using finite element method and test data is provided, followed with a brief discussion of potential sources of discrepancies between results obtained from these methods.

High Crystal Number Densities From Mechanical Damage

Laboratory experiments investigating syn-eruptive crystallization are fundamental for interpreting crystal and vesicle textures in pyroclasts. Previous experiments have advanced our understanding by varying decompression and cooling pathways, volatile components, and melt composition. However, they have largely failed to produce the high crystal number densities seen in many cryptodome and dome samples. This is feasibly due to the relatively simple decompression pathways employed in experimental studies. In this study, we approach the problem by exploring non-linear decompression pathways. We present two series of experiments: (1) decompression from low initial starting pressure and (2) a compression-and-release step after the initial decompression. The purpose of each series was to simulate (1) decompression of magma that stalls during ascent and (2) pressure cycling that occurs in non-erupted magma during episodic explosive activity. The experiments were carried out on a synthetic rhyodacite (SiO2 = 69 wt%) held initially at 50 MPa and 885°C then decompressed at rates of 0.026 and 0.05 MPa s−1 to 10 MPa A subset of experiments was then subjected to a compression step to 110 MPa followed by near-instantaneous release back to 10 MPa. A substantial volume fraction of dendritic microlites (ϕxtl = 0.27–0.32, Na = 4.79 × 103 mm–2) formed during the initial hold at 50 MPa; additional crystallization during subsequent decompression to ≥ 10 MPa was minimal, as evidenced by only small increases in crystallinity (ϕxtl = 0.28–0.33) and comparable crystal number densities (4.11–7.81 × 103 mm–2). Samples that underwent recompression followed by a second decompression showed no increase in crystal volume fraction but did show extensive disruption of the initial dendritic, box-work microlite structures that produced high number densities (Na = 43.5–87.2 × 103 mm–2) of small individual crystals. The disruption was driven by a combination of rapid vesiculation, expansion and resulting shear along the capsule walls. From these results, we suggest that high crystal number densities may be a signature of rapid deformation occurring after magma stalling in the subsurface, perhaps related to pressure cycling and accompanying rapid changes in vesicularity during repeated small and shallow-sourced explosions. We compare our experiments to pyroclasts from shallow intrusions that preceded the 18 May 1980 eruption of Mount St Helens. These pyroclasts were erupted both prior to 18 May, during episodic precursory explosive activity, and by the 18 May initial lateral blast. The pattern of precursory activity indicates multiple episodes of pressurization (prior to explosive events) and rapid decompression (during explosive events) that we use to illustrate the significance of our experimental results.

Episodic fluid pressure cycling controls earthquake sequences on subduction megathrusts

<p>A major goal in earthquake physics is to derive a constitutive framework for fault slip that captures the dependence of friction on lithology, sliding velocity, temperature, and pore fluid pressure. Here, we present a newly-developed two-phase flow numerical model — which couples solid rock deformation and pervasive fluid flow — to show how crustal stresses and fluid pressures within subducting megathrust evolve before and during slow slip and fast events. This unified 2D numerical framework couples inertial mechanical deformation and fluid flow by using finite difference methods, marker-in-cell technique, and poro-visco-elasto-plastic rheology. An adaptive time stepping allows the correct resolution of both long- and short-time scales, ranging from years to milliseconds during the dynamic propagation of dynamic rupture.</p><p>We investigate how permeability and its spatial distribution control the interseismic coupling along the megathrust interface, the interplay between seismic and aseismic slip, and the nucleation of large earthquakes. While a constant permeability leads to more regular seismic cycles, a depth dependent permeability contributes substantially to the development of two distinct megathrust zones: a shallow, locked seismogenic zone and a deep, narrow aseismic segment characterized by slow-slip events. Furthermore, we show that without requiring any specific friction law, our models reveal that permeability, episodic stress transfer and fluid pressure cycling control the predominant slip mode along the subduction megathrust. Furthermore, we analyze how rate dependent strength and dilatation affect rupture propagation and arrest. Our preliminary results show that fluid-solid poro-visco-elasto-plastic coupling behaves similarly to rate- and state-dependent friction. In this context, fluid pressure plays the role of state parameter whose time evolution is governed by: (i) the short-term elasto-plastic collapse of pores inside faults during the rupture (coseismic self-pressurization of faults) and (ii) the long-term pore-pressure diffusion from the faults into surrounding rocks (post- and interseismic relaxation of fluid pressure). This newly-developed numerical framework contributes to improve our understanding of the physical mechanisms underlying large megathrust earthquakes, and demonstrate that fluid play a key role in controlling the interplay between seismic and aseismic slip.</p>

Repair of Leaks in Thin Wall High Pressure Pipelines Using Composite Reinforcing Technologies

A study was conducted to evaluate two composite repair technologies used to reinforce severe corrosion and thru-wall leaking defects in thin-walled pipe materials; conditions where the welding of conventional Type B steel sleeves cannot be conducted. This program involved the reinforcement of simulated 85% corrosion defects in 6.625-inch × 0.157-inch, Grade X52 pipe materials subjected to cyclic pressure and burst testing. The test matrix also included repaired pipe samples with thru-wall defects that were pressurized using nitrogen gas and buried for 90 days. The program was comprehensive in that it evaluated the following elements involving a total of 81 reinforced corrosion defects. • Corrosion features with a depth of 85% of the pipe’s nominal wall thickness in thin-walled pipe material (i.e., 0.157 inches, or 4 mm). • Thru-wall defects having a diameter of 0.125 inches (3 mm). • Repairs made with leaking defects having 100 psig (690 kPa) internal pressure. • Strain gage measurement made in non-leaking 85% corrosion defects; it should be noted that the remaining “15%” ligament was 0.024 inches (0.6 mm); to the author’s knowledge, no high-pressure testing has ever been conducted on such a thin remaining wall. • Long-term 90-day test that included pressurization with nitrogen gas, followed by relatively aggressive pressure cycling up to 80% SMYS followed by burst testing. This is the first comprehensive study conducted by a major transmission pipeline operator evaluating the performance of competing composite technologies used to reinforce severe corrosion features with thru-wall defects. The reinforcement of leaks has not been accepted by regulatory bodies such as the Canadian Energy Regulator (CER), or the U.S. Pipeline and Hazardous Materials Safety Administration (PHMSA). A goal of the current study is to validate composite repair technologies as a precursor to regulatory approval. The results of this study indicate that viable composite repair technologies exist with capabilities to reinforce leaks in pipelines that experience operating conditions typical for gas transmission systems (i.e., minimal pressure cycling).