Study on Direct Writing of Gallium Metal for the Flexible Sensor

There is an urgent need for a simple and effective method to manufacture flexible sensors composed of liquid metal. Gallium (Ga) metal has become an ideal flexible conductive material due to its high conductivity, low melting point, and high flow characteristics. In this paper, liquid Ga metal is directly written on the polyvinyl alcohol (PVA) film through the driving mode of piston extrusion; then, the Ga metal wire is transferred and sealed with silica gel. The advantages of piston mode are studied, and the direct writing parameters of the liquid Ga metal, including extrusion speed, nozzle height, printing speed, and nozzle inner diameter, are systematically optimized. The flexible sensor based on the sealed liquid Ga metal has good resilience under the external load. This work provides a specific reference for direct writing of liquid Ga metal and its sealing technology for the flexible sensor.

Growth of Ga2O3 Nanowires by a Vapor Transport Method and their Optical Transmittance Spectra

Gallium oxide (Ga2O3) nanowires were grown on fused quartz and Si substrates by a vapor transport method of heating gallium metal at 750−1100 °C in a tube of the horizontal furnace. The obtained white colored product has shown to be the Ga2O3 nanowires with average diameters ranging from 30 to 80 nm. The optical transmittance spectra indicated that the bandgap energy of Ga2O3 nanowire increases as the diameter of nanowire decreases.

Synthesis of Water-Soluble Copolymers of N-vinylpyrrolidone with N-vinyldithiocarbamate as Multidentate Polymeric Chelation Systems and Their Complexes with Indium and Gallium

Dithiocarbamate (DTC) derivatives of N-vinylpyrrolidone-N-vinylamine (VP–VA) copolymers were synthesized via reaction between the copolymers and carbon disulfide in alkaline medium; molecular masses of the products were 12 and 29 kDa; the VP:VDTC ratios were 94:6 and 83:17 mol.%. Complexation between the obtained DTC derivatives and metal ions (indium and gallium) was investigated. It was demonstrated that metal–DTC ligand complexes with 1:3 ratio between components were formed. Gallium metal–polymer complexes (MPC) were unstable in solution. Individual indium MPC were isolated and characterized by spectral and chromatographic methods. Unlike similar gallium MPC, they appeared to be stable in histidine challenge reaction.