Research on the Metal Corrosion Process in the Sea Mud/Seawater/Atmosphere Interface Zone

Corrosion in the interface zone is a complicated local corrosion phenomenon. The conventional single-electrode method finds it difficult to obtain the kinetic information of corrosion occurrence and development process. In this paper, metal corrosion was studied by Wire Beam Electrode (WBE) technology on the interfaces of sea mud/seawater and seawater/atmosphere. The study found that the metal corrosion in the interface is a process of coupling a dual corrosion cell into a single corrosion cell. Initially, a corrosion cell is formed with the seawater/atmosphere interface acting as the cathode and the upper part of the metal in the seawater area as the anode. This is due to the oxygen concentration cell caused by the waterline effect. The cathode area is always enriched near the seawater/atmosphere interface. The lower part of the metal in the seawater area and the metal in the sea mud area are the anode and the cathode, respectively, of another corrosion cell. Along with the immersion time, the anodic area of the first corrosion cell gradually extends to the lower part of the metal in the seawater zone and finally the sea mud zone, resulting in the disappearance of the second corrosion cell. In the single corrosion cell stage, the seawater/atmosphere interface is the cathode area; the seawater area and the sea mud area are the anode areas, and the electrode adjacent to the cathode area becomes the anode area with the largest current density. During the whole experiment, the sea mud zone is a process of polarity transition from the cathode zone to the anode zone, and finally forms the anode zone of the whole electrode together with the anode zone in the sea zone.

Weak palaeointensity results over a Pliocene volcanic sequence from Lesser Caucasus (Georgia): transitional record or time averaged field?

SUMMARY A palaeointensity study has been carried out on a Pliocene sequence of 20 consecutive lava flows where previous directional results seem to reflect anomalous behaviour of the Earth's magnetic field (EMF), which can be explained by a polarity transition record or non-averaged palaeosecular variation or both. Here, we perform a total of 55 palaeointensity determinations using the original Thellier–Thellier (TT) method and 100 with the IZZI method. We assess the performance of our selection criteria using a set of strict threshold values applied to a set of test data whose TRMs were acquired in known fields. Absolute palaeointensity determinations that passed our selection criteria were obtained on four specimens with the TT method and on 41 specimens with the IZZI method. Application of reliability criteria at a site level yielded palaeointensity results in 8 of 20 studied lava flows. We obtained median values of VADM between 28.9 and 45.6 ZAm2 for the reverse polarity lower Apnia section, while the normal polarity upper section displayed a single value of 54.6 ZAm2. The low palaeointensity values before a transitional direction lava flow and the higher value after it, suggest the common behaviour at the start of a polarity reversal and the recovery after it. However, an isolated record of a stable EMF, where the intensity is lower than the current for the same location (83.7 ZAm2), cannot be discarded. Consequently, this interpretation would support a weak time-averaged field.

Casein Kinase 1γ Ensures Monopolar Growth Polarity under Incomplete DNA Replication Downstream of Cds1 and Calcineurin in Fission Yeast

Cell polarity is essential for various cellular functions during both proliferative and developmental stages, and it displays dynamic alterations in response to intracellular and extracellular cues. However, the molecular mechanisms underlying spatiotemporal control of polarity transition are poorly understood. Here, we show that fission yeast Cki3 (a casein kinase 1γ homolog) is a critical regulator to ensure persistent monopolar growth during S phase. Unlike the wild type,cki3mutant cells undergo bipolar growth when S phase is blocked, a condition known to delay transition from monopolar to bipolar growth (termed NETO [newendtakeoff]). Consistent with this role, Cki3 kinase activity is substantially increased, and cells lose their viability in the absence of Cki3 upon an S-phase block. Cki3 acts downstream of the checkpoint kinase Cds1/Chk2 and calcineurin, and the latter physically interacts with Cki3. Autophosphorylation in the C terminus is inhibitory toward Cki3 kinase activity, and calcineurin is responsible for its dephosphorylation. Cki3 localizes to the plasma membrane, and this localization requires the palmitoyltransferase complex Erf2-Erf4. Membrane localization is needed not only for proper NETO timing but also for Cki3 kinase activity. We propose that Cki3 acts as a critical inhibitor of cell polarity transition under S-phase arrest.