Rotational and nuclear-spin level dependent photodissociation dynamics of H2S

The detailed features of molecular photochemistry are key to understanding chemical processes enabled by non-adiabatic transitions between potential energy surfaces. But even in a small molecule like hydrogen sulphide (H2S), the influence of non-adiabatic transitions is not yet well understood. Here we report high resolution translational spectroscopy measurements of the H and S(1D) photoproducts formed following excitation of H2S to selected quantum levels of a Rydberg state with 1B1 electronic symmetry at wavelengths λ ~ 139.1 nm, revealing rich photofragmentation dynamics. Analysis reveals formation of SH(X), SH(A), S(3P) and H2 co-fragments, and in the diatomic products, inverted internal state population distributions. These nuclear dynamics are rationalised in terms of vibronic and rotational dependent predissociations, with relative probabilities depending on the parent quantum level. The study suggests likely formation routes for the S atoms attributed to solar photolysis of H2S in the coma of comets like C/1995 O1 and C/2014 Q2.

The effect of spin level and ball exit speed on forearm muscle activity in the tennis forehand stroke

Elbow tendinopathy injuries are very common in tennis players. One of the commonly accepted theories describing the development of elbow tendinopathy in tennis is based on stiffness of the forearm skeletal muscle units and their repetitive overuse in the forehand stroke. Our objective was to use a novel microcontroller based wearable device to compare the influence of different forehand spin levels (flat, topspin and lob) and ball exit speed on forearm muscle activity in the potential onset of elbow tendinopathy in experienced adult tennis players. Peak normalised extensor carpi radialis (ECR) and flexor carpi radialis (FCR) muscle activity corresponding to each forehand shot and ball exit speed were determined and analysed. For the ECR shots (flat = 121, topspin = 272 and lob = 273) by 8 players, Kruskal-Wallis test (p < 0.001) and Post-Hoc tests revealed a significant difference between the flat and topspin spin levels (p < 0.01) and flat and lob spin levels (p < 0.001). For the FCR shots (flat = 125, topspin = 301 and lob = 303) by 9 players, Kruskal-Wallis test showed no significant difference between the three spin levels. For the corresponding ball speed, the Kruskal-Wallis (p < 0.001) and subsequent Post-Hoc (p < 0.001) showed that flat hits had the significantly highest ball speed followed by topspin then lob accordingly for both muscles included shots. Our results suggest that coaches could consider recommending players to hit forehands with topspin in order to potentially reduce the risk of developing lateral elbow tendinopathy.

Chemical tuning of spin clock transitions in molecular monomers based on nuclear spin-free Ni(ii)

We have directly monitored spin level anti-crossings, or “clock transitions”, in Ni(ii) molecular monomers and shown that the quantum tunnelling gap admits a chemical tuning.

Studying collective nuclear excitations with fast neutrons: a comparison of 76Ge and 76Se

The low-lying, low-spin level structures of 76Ge and 76Se were studied with the (n,n'γ) reaction. Gamma-ray excitation function and angular distribution measurements were performed, and level spins, level lifetimes, γ-ray intensities, and multipole mixing ratios were determined. Large observed B(E2) values support the identification of low-lying band structures.

Verifying Heisenberg’s error-disturbance relation using a single trapped ion

Heisenberg’s uncertainty relations have played an essential role in quantum physics since its very beginning. The uncertainty relations in the modern quantum formalism have become a fundamental limitation on the joint measurements of general quantum mechanical observables, going much beyond the original discussion of the trade-off between knowing a particle’s position and momentum. Recently, the uncertainty relations have generated a considerable amount of lively debate as a result of the new inequalities proposed as extensions of the original uncertainty relations. We report an experimental test of one of the new Heisenberg’s uncertainty relations using a single 40Ca+ ion trapped in a harmonic potential. By performing unitary operations under carrier transitions, we verify the uncertainty relation proposed by Busch, Lahti, and Werner (BLW) based on a general error–trade-off relation for joint measurements on two compatible observables. The positive operator-valued measure, required by the compatible observables, is constructed by single-qubit operations, and the lower bound of the uncertainty, as observed, is satisfied in a state-independent manner. Our results provide the first evidence confirming the BLW-formulated uncertainty at a single-spin level and will stimulate broad interests in various fields associated with quantum mechanics.