Preparation of Composite Banana Peel-TiO2 for Methyl Orange Dyes Removal

Composite banana peel activated carbon-TiO2 has successfully prepared using the sol-gel method. In this research, banana peel was activated using KOH activator. This study aimed to compose biomass wastes (banana peels) with TiO2 catalyst for Methyl Orange (MO) dye removal. The banana peel-activated carbon (BPAC) composition varied from 20, 50 and 70 wt. %. The prepared samples were calcined at 400 °C for 4 h. The structure and properties of the prepared samples were characterized by X-ray Diffraction (XRD), Fourier Transmission Infra-Red (FTIR), Scanning Electron Microscope (SEM) and Ultraviolet-Visible Spectrophotometer (UV-Vis). The results obtained from XRD showed the presence of anatase, rutile and potassium formate. The morphological analysis TiO2 showed agglomeration whereas pores were observed in BPAC. FTIR results indicated a C-O stretching and CH functional group formation through a modification that it does not exhibit in pure TiO2. The sample with 50 wt% BPAC-TiO2 has the highest MO removal (72.5%) within 3 h of irradiation time. From the current finding, banana peel-activated carbon-TiO2 can be commercialized for wastewater remediation especially in treating dye pollution.

Activated carbon and biochar from pineapple waste biomass for the removal of methylene blue

Dye pollution in water system is of concern due to its carcinogenicity and its effect on aesthetic feature. One pollutant of interest is methylene blue (MB), which is a cationic dye widely used in industries. In this study, pyrolysis process was used to convert pineapple waste biomass (PWB) into useful adsorbents such as biochar (BC) and activated carbon (AC) to remove MB in water. BC was produced from pyrolysis of PWB (340 °C, 3 hours) whereas AC was prepared from pyrolysis of PWB (500 °C, 1 hour) impregnated with zinc chloride (ZnCl2). Prior to use, AC-PWB and BC-PWB were characterized for surface area, functional groups and surface morphology. Removal of MB was investigated by varying different parameters i.e. initial MB concentration and contact time, adsorbent dosage and temperature. Results obtained showed that AC-PWB has higher adsorption capacity than BC-PWB. The adsorption capacity and adsorption rate increased with increasing initial concentration of MB, adsorbent dosage and temperature until reached equilibrium condition. As a conclusion, PWB can be used as a useful raw material to produce cheap and environmentally friendly adsorbent to remove dye from solution.

Ionic liquid-assisted electrodeposition synthesis of CuO films

With the global dye pollution situation becoming severe, a highly promising material is needed to purify water to safeguard ecological stability and public health. Studies have shown that semiconductor oxides...

Immobilization as a powerful Bioremediation tool for abatement of dye pollution: A review

Dyes are xenobiotic compounds widely used by textile, leather, paper, printing, food, pharmaceutical, and cosmetic industries. Decolorization and dye degradation in the effluents is a prime hurdle in its treatment, and there is still a shortage of economically attractive and easy-to-operate treatments that can eliminate dye pollution. In recent years, chemical-based treatments are being replaced by greener technologies at the lab and industrial scale to combat dye pollution. It is noteworthy that immobilization is a biotechnological tool that greatly enhances bioremediation's potential. The present review has covered the basic concepts of immobilization, including the different immobilization techniques and the various carriers used for immobilization. The efficient immobilization of a biocatalyst depends on the proper choice of a carrier combined with a suitable immobilization technique. Hence, this review provides a comparative analysis of the different immobilization techniques and carriers used. Further, there is an in-depth discussion on the potential of immobilized enzymes and cells as bioremediation agents for dye degradation. Nearly all the studies indicated that immobilization enhanced the biodecolorization of colored wastewater compared to free systems. Further, the potential of immobilized systems for large scale industrial implementation was also examined. The article ends with a note on the loopholes of research on immobilization and future scopes of this technique.

Assessment of the aerobic glass beads fixed biofilm reactor (GBs-FBR) for the treatment of simulated methylene blue wastewater

The present research is focused on the application of glass beads (GBs) in fixed biofilm reactor (FBR) for the treatment of simulated methylene blue (MB) wastewater for 9 weeks under aerobic conditions. The COD of MB wastewater showed a reduction of 86.48% from 2000 to 270.4 mg/L, and BOD was declined up to 97.7% from 1095.5 to 25.03 mg/L. A drastic increase in the pH was observed until the 3rd week (8.5 to 8.28), and later, marginal changes between 8.30 ± 0.02 were noticed. A dramatic fluctuation was observed in ammonia concentration which increased (74.25 mg/L) up till the 2nd week, and from the 3rd week it started declining. In the 9th week, the ammonia concentration dropped to 16.5 mg/L. The color intensity increased significantly up till the 2nd week (259,237.46 Pt/Co) of the experiment and started decreasing slowly thereafter. The SEM–EDX analysis has shown the maximum quantity of carbon content in the GBs without biofilm, and then in the GB samples of 1st, and 9th-week old aerobic biofilms. Furthermore, Raman spectroscopy results revealed that the 9th-week GBs has a fine and strong MB peak and matched with that of the MB stock solution. Overall, the results have shown that the GBs filter media were suitable for the development of active biofilm communities for the treatment of dye wastewater. Thus, GBs-FBR system can be used for wastewater treatment to solve the current problem of industrial pollution in many countries and to protect the aquatic environment from dye pollution caused by the textile industry.