Quantum Gravity Theory Founded on Device That Generates Energy from Relative Acceleration Amongst Charged Particles Electrostatically Interacting Under Curvature Deviation

This is an introduction to a new concept of quantum gravity that seamlessly merges General Relativity to the Standard Model. Based upon a novel patent-pending magnetic confinement method that was designed to emulate how our sun confines and rotates charged particles about a singularity; this confinement method uses a collective of off-centered confinement coils that are directed to curve rotating charged particles about a singularity in a way that allows charged particles to relatively accelerate from geodesic deviation. With this confinement method, the subtle Relative Accelerated Energy (RAE) from deviating charged particles has the capability to be focused and exponentially increased relative to the mass-energy of a closed system; which allows for a simple pathway to understand how black holes operate at their singularities. While in the pursuit of proving that this novel method of confinement mimics how our sun operates; I was also able to develop a logical explanation of how our sun reverses its magnetic poles and cycles using the core principles of Michael Faraday. If this concept of quantum gravity is correct, there is a simple explanation for the additional observed gravitational force about the galaxies that are said to obtain dark matter. In short, this theory of quantum gravity has the potential to fully discredit the existence of theorized dark matter with a simple experiment.

Quantum Gravity Theory Founded on Device That Generates Energy from Relative Acceleration Amongst Charged Particles Electrostatically Interacting Under Curvature Deviation

This is an introduction to a new concept of quantum gravity that seamlessly merges General Relativity to the Standard Model. Based upon a novel patent-pending magnetic confinement method that was designed to emulate how our sun confines and rotates charged particles about a singularity; this confinement method uses a collective of off-centered confinement coils that are directed to curve rotating charged particles about a singularity in a way that allows charged particles to relatively accelerate from geodesic deviation. With this confinement method, the subtle Relative Accelerated Energy (RAE) from deviating charged particles has the capability to be focused and exponentially increased relative to the mass-energy of a closed system; which allows for a simple pathway to understand how black holes operate at their singularities. While in the pursuit of proving that this novel method of confinement mimics how our sun operates; I was also able to develop a logical explanation of how our sun reverses its magnetic poles and cycles using the core principles of Michael Faraday. If this concept of quantum gravity is correct, there is a simple explanation for the additional observed gravitational force about the galaxies that are said to obtain dark matter. In short, this theory of quantum gravity has the potential to fully discredit the existence of theorized dark matter with a simple experiment.

Synthesis and antibacterial activity of new chalcones bearing an imidazo[1,2-a]pyridine moiety

Aim and Objective: Herein, A series of new imidazo[1,2-a]pyridine-chalcone derivatives 3a-m were designed and synthesized to find new class of antibacterial agents. These compounds were prepared by the aldol condensation of 2-phenylimidazo[1,2-a]pyridine-3-carbaldehyde 2a-b with acetophenone derivatives and other aromatic acetyls. High reaction yields have been obtained in a short reaction time, through applying this multi-step pathway. Materials and Methods: In vitro antibacterial activities of the synthesized imidazo[1,2-a]pyridine-chalcones were measured against S. aureus, B. subtilis and E. coli with MIC values of 32 -128 μg/mL. Finally, essential structural analyses such as CHN and NMR spectroscopies were used to identify the synthesized chalcones based on imidazo[1,2-a]pyridine derivatives. Results: The results showed that most of the products presented moderate to good antibacterial activities. Compounds 3b, 3d, 3g, 3l and 3m revealed obvious potency against S. aureus, B. subtilis and E. coli with MIC values of 32 μg/mL and 64 μg/mL, which were better when compared with other chalcones. Conclusion: The synthesized antibacterial compounds were obtained with appealing advantages such as high purity, simple pathway, good to excellent yields, inexpensive and easy availability of materials as well as good activities against bacteria. So in this work, new class of antibacterial chalcones based on imidazo[1,2-a]pyridine have been reported.

Ni-Co single atomic anchored conjugated microporous polymer for high-performance photocatalytic hydrogen evolution

The fabrication of single atomic photocatalysts via a simple pathway is a crucial challenge to enable efficient production of hydrogen. Herein, we demonstrate a gaseous diffusion strategy to construct single...

A Nonconjugated Radical Polymer with Stable Red Luminescence in Solid State

<p><b>Luminescent organic radicals have attracted much attention due to its distinctive open-shell structure and all-in-one properties on optoelectronics</b><b>, electronics</b><b>, and magnetics</b><b>. However, organic radicals are usually instable</b><b> and only very limited stable structures with π-radicals can </b><b>exhibit luminescent property</b><b> in the isolated state, most of which originate from the family of triphenylmethyl derivatives</b><b>. Here, we report an unusual radical luminescence phenomenon that nonconjugated radical polymer can readily emits red luminescence at ~635 nm in the solid state. A traditional luminescence quencher, 2,2,6,6-tetramethylpiperidine 1-oxyl (TEMPO)</b><b>, was turned into a red chromophore when grafted onto a polymer backbone. Experimental data confirms the emission is associated with the nitroxide radicals and is also affected by the packing of polymer. As a proof of concept, a biomedical application in intracellular ascorbic acid visualization is demonstrated. This work discloses a novel class of luminescent radicals and provides a distinctive and simple pathway for stable radical luminescence. </b></p>

A Nonconjugated Radical Polymer with Stable Red Luminescence in Solid State

<p><b>Luminescent organic radicals have attracted much attention due to its distinctive open-shell structure and all-in-one properties on optoelectronics</b><b>, electronics</b><b>, and magnetics</b><b>. However, organic radicals are usually instable</b><b> and only very limited stable structures with π-radicals can </b><b>exhibit luminescent property</b><b> in the isolated state, most of which originate from the family of triphenylmethyl derivatives</b><b>. Here, we report an unusual radical luminescence phenomenon that nonconjugated radical polymer can readily emits red luminescence at ~635 nm in the solid state. A traditional luminescence quencher, 2,2,6,6-tetramethylpiperidine 1-oxyl (TEMPO)</b><b>, was turned into a red chromophore when grafted onto a polymer backbone. Experimental data confirms the emission is associated with the nitroxide radicals and is also affected by the packing of polymer. As a proof of concept, a biomedical application in intracellular ascorbic acid visualization is demonstrated. This work discloses a novel class of luminescent radicals and provides a distinctive and simple pathway for stable radical luminescence. </b></p>

Electrochemically Driven Desaturation of Carbonyl Compounds

<p> Electrochemical techniques have long been heralded for their innate sustainability as efficient methods for achieving redox reactions. Carbonyl desaturation, as a fundamental organic oxidation, is an oft-employed transformation to unlock adjacent reactivity. To date, the most reliable methods for achieving it have relied on transition metals (Pd/Cu) or stoichiometric reagents based on I, Br, Se, or S. Herein we report an operationally simple pathway to such structures from enol silanes and phosphates using electrons as the primary reagent. This electrochemically driven desaturation exhibits a broad scope across an array of carbonyl derivatives, is easily scalable (1-100g), and can be predictably implemented into synthetic pathways using experimentally or computationally derived NMR shifts. Mechanistic interrogation suggests a radical-based reaction pathway. <br></p>

Electrochemically Driven Desaturation of Carbonyl Compounds

<p> Electrochemical techniques have long been heralded for their innate sustainability as efficient methods for achieving redox reactions. Carbonyl desaturation, as a fundamental organic oxidation, is an oft-employed transformation to unlock adjacent reactivity. To date, the most reliable methods for achieving it have relied on transition metals (Pd/Cu) or stoichiometric reagents based on I, Br, Se, or S. Herein we report an operationally simple pathway to such structures from enol silanes and phosphates using electrons as the primary reagent. This electrochemically driven desaturation exhibits a broad scope across an array of carbonyl derivatives, is easily scalable (1-100g), and can be predictably implemented into synthetic pathways using experimentally or computationally derived NMR shifts. Mechanistic interrogation suggests a radical-based reaction pathway. <br></p>