Sedimentary Provenance Changes Constrain the Eocene Initial Uplift of the Central Pamir, NW Tibetan Plateau

The Pamir Plateau region of the Northwestern Tibetan Plateau forms a prominent tectonic salient, separating the Tajik and Tarim basins. However, the topographic evolution of the Pamir Plateau remains elusive, despite the key role of this region played in the retreat of the Paratethys Ocean and in aridification across Central Asia. Therefore, the SW Tarim and Tajik basins are prime locations to decipher the geological history of the Pamir Plateau. Here, we present detrital zircon U/Pb and apatite fission-track (DAFT) ages from the Keliyang section of the SW Tarim Basin. DAFT ages show that sediments had three components during the Late Cretaceous and two components since the Oligocene. Detrital zircon U/Pb ages mainly cluster between 400 and 500 Ma during the Late Cretaceous, and coincide with ages of the Songpan-Ganzi and the West Kunlun Mountains. In contrast, detrital zircon U/Pb ages in the Eocene sediments are centered at around 200–300 Ma and 40–70 Ma, with a peak at ∼45 Ma, consistent with data from the Central Pamir and the West Kunlun Mountains. The ∼45 Ma peak in detrital zircon U/Pb ages since the Eocene indicates a new sedimentary source from the Central Pamir. Non-metric multi-dimensional scaling (MDS) analyses also show that the sedimentary source was closer to the Central Pamir after the Eocene, when compared to the Late Cretaceous. The result shows a clear Eocene provenance change in the Keliyang area. Moreover, this Eocene provenance shift has been detected in previous studies, in both the Tajik and Tarim basins, suggesting that the entire Central Pamir region likely experienced quasi-simultaneous abrupt uplift and paleo-geomorphological changes during the Eocene.

Origin of hydrocarbons in the Bach Ho field (The Vietnamese shelf)

This article presents the results of a geochemical study of oil on the Vietnam shelf (Cuu Long basin), including those in the crystalline basement. The Bach Ho field oils in the basement have a hydrocarbon distribution that is no different than oil of numerous accumulations in Oligocene and Miocene sedimentary sequences. Similar to the organic origin oils of the world, oils from the Bach Ho field lack regular isoprenanes С12 and С17 and cheilanthanes (tri-cyclic terpanes) С22 and С27. A distinctive feature of these oils is a large amount of cheilanthanes С19-С29, and large neo-adiantane to adiantane and hopanes to steranes ratios. All these parameters indicate a large bacterial contribution in the generation of these oils. Studies have shown the similarity between oil biomarker parameters and the organic matter of sedimentary rocks, which supports the organic nature of the oils in the basement fields on the Vietnam shelf. It is shown that the hydrocarbon accumulations in the basement complexes of the Cuu Long basin are in a secondary occurrence, and their origin was the organic matter of the sedimentary source rocks.

Natural and anthropogenic drivers of denudation and sedimentary source-to-sink fluxes in the boreal mountain basin of lake Selbusjøen in central Norway

<p>Denudation, including both chemical and mechanical processes, is of high relevance for landscape development and the transfer of solutes and sediments from headwater systems through main stem of drainage basin systems into sinks like lakes or the sea. Denudation is controlled by a range of environmental drivers and is in most environments and landscapes worldwide significantly affected by anthropogenic activities.</p><p>In the boreal mountain environment of central Norway the regulated lake Selbusjøen, situated at ca. 160 m a.s.l. with an area of 58 km<sup>2</sup> and connecting the upstream main mountain river Nea and the downstream main river Nidelva, forms a significant sink for sediments being transferred from its drainage basin area of in total 2876 km<sup>2</sup>.  The significant sediment trapping efficiency of lake Selbusjøen is causing a sediment deficit and locally increased fluvial erosion and down-cutting in the downstream river Nidelva which drains into the Trondheim fjord.</p><p>This ongoing GFL research on natural and anthropogenic drivers and the spatiotemporal variability of contemporary chemical and mechanical fluvial denudation rates and sedimentary source-to-sink fluxes in the boreal mountain basin of lake Selbusjøen is based on statistical analyses of high-resolution meteorological data, detailed field and remotely sensed mapping, computing of morphometric catchment parameters, and year-round process geomorphological field work. Geomorphological field work includes detailed field observations, repeated photographic documentations of selected stream channel stretches and slope surface areas, and field monitoring and frequent measurements with snow, rain water, stream-water and bedload samplings for the analysis of solute and suspended sediment concentrations and the study of atmospheric solute inputs, and the quantification of fluvial solute and sediment transport. Field work is carried out in 25 defined catchments/drainage areas draining into Selbusjøen. The selected catchment/drainage area systems are all characterized by large surface areas with a nearly closed and continuous vegetation cover mostly composed of boreal forests and bogs, and represent a range of different catchment sizes, catchment morphometries, orientations/aspects, and sediment sources and availabilities. In addition, different types and intensities of anthropogenic impact like, e.g., agriculture, forestry and modifications of natural stream channels (e.g., dams, steps, bank protection) and channel discharge for water power purposes are found in various catchments.</p><p>Runoff is occurring year-round and the natural runoff regime is clearly nival. Most fluvial transport is occurring during peak-runoff events generated by snowmelt, rainfall events or combinations of snowmelt and rainfall.  Altogether, chemical denudation is moderate but dominates clearly over mechanical fluvial denudation. Both chemical and mechanical fluvial denudation show a significant spatial variability which can be related to the varying characteristics of the selected catchment/drainage area systems. Agriculture and forestry are generally increasing mechanical fluvial denudation rates whereas anthropogenic stream channel and channel discharge modifications are leading to reduced fluvial bedload transport rates into lake Selbusjøen. Ongoing and accelerated climate change with the related changes of the current wind, temperature and precipitation regimes are expected to increase both chemical and mechanical fluvial denudation and sediment transport rates into lake Selbusjøen, particularly in the surface areas that have been modified by anthropogenic activities.</p>

Air–sea fluxes of greenhouse gases and oxygen in the northern Benguela Current region during upwelling events

Ground-based atmospheric observations of CO2, δ(O2∕N2), N2O, and CH4 were used to make estimates of the air–sea fluxes of these species from the Lüderitz and Walvis Bay upwelling cells in the northern Benguela region, during upwelling events. Average flux densities (±1σ) were 0.65±0.4 µmol m−2 s−1 for CO2, -5.1±2.5 µmol m−2 s−1 for O2 (as APO), 0.61±0.5 nmol m−2 s−1 for N2O, and 4.8±6.3 nmol m−2 s−1 for CH4. A comparison of our top-down (i.e., inferred from atmospheric anomalies) flux estimates with shipboard-based measurements showed that the two approaches agreed within ±55 % on average, though the degree of agreement varied by species and was best for CO2. Since the top-down method overestimated the flux density relative to the shipboard-based approach for all species, we also present flux density estimates that have been tuned to best match the shipboard fluxes. During the study, upwelling events were sources of CO2, N2O, and CH4 to the atmosphere. N2O fluxes were fairly low, in accordance with previous work suggesting that the evasion of this gas from the Benguela is smaller than for other eastern boundary upwelling systems (EBUS). Conversely, CH4 release was quite high for the marine environment, a result that supports studies that indicated a large sedimentary source of CH4 in the Walvis Bay area. These results demonstrate the suitability of atmospheric time series for characterizing the temporal variability of upwelling events and their influence on the overall marine greenhouse gas (GHG) emissions from the northern Benguela region.

Strongly Peraluminous Granites across the Archean–Proterozoic Transition

Strongly peraluminous granites (SPGs) form through the partial melting of metasedimentary rocks and therefore represent archives of the influence of assimilation of sedimentary rocks on the petrology and chemistry of igneous rocks. With the aim of understanding how variations in sedimentary rock characteristics across the Archean–Proterozoic transition might have influenced the igneous rock record, we compiled and compared whole-rock chemistry, mineral chemistry, and isotope data from Archean and Paleo- to Mesoproterozoic SPGs. This time period was chosen as the Archean–Proterozoic transition broadly coincides with the stabilization of continents, the rise of subaerial weathering, and the Great Oxidation Event (GOE), all of which left an imprint on the sedimentary rock record. Our compilation of SPGs is founded on a detailed literature review of the regional geology, geochronology, and inferred origins of the SPGs, which suggest derivation from metasedimentary source material. Although Archean and Proterozoic SPGs are similar in terms of mineralogy or major-element composition owing to their compositions as near-minimum melts in the peraluminous haplogranite system, we discuss several features of their mineral and whole-rock chemistry. First, we review a previous analysis of Archean and Proterozoic SPGs biotite and whole-rock compositions indicating that Archean SPGs, on average, are more reduced than Proterozoic SPGs. This observation suggests that Proterozoic SPGs were derived from metasedimentary sources that on average had more oxidized bulk redox states relative to their Archean counterparts, which could reflect an increase in atmospheric O2 levels and more oxidized sedimentary source rocks after the GOE. Second, based on an analysis of Al2O3/TiO2 whole-rock ratios and zircon saturation temperatures, we conclude that Archean and Proterozoic SPGs formed through partial melting of metasedimentary rocks over a similar range of melting temperatures, with both ‘high-’ and ‘low-’temperature SPGs being observed across all ages. This observation suggests that the thermo-tectonic processes resulting in the heating and melting of metasedimentary rocks (e.g. crustal thickening or underplating of mafic magmas) occurred during generation of both the Archean and Proterozoic SPGs. Third, bulk-rock CaO/Na2O, Rb/Sr, and Rb/Ba ratios indicate that Archean and Proterozoic SPGs were derived from partial melting of both clay-rich (i.e. pelites) and clay-poor (i.e. greywackes) source regions that are locality specific, but not defined by age. This observation, although based on a relatively limited dataset, indicates that the source regions of Archean and Proterozoic SPGs were similar in terms of sediment maturity (i.e. clay component). Last, existing oxygen isotope data for quartz, zircon, and whole-rocks from Proterozoic SPGs show higher values than those of Archean SPGs, suggesting that bulk sedimentary 18O/16O ratios increased across the Archean–Proterozoic boundary. The existing geochemical datasets for Archean and Proterozoic SPGs, however, are limited in size and further work on these rocks is required. Future work must include detailed field studies, petrology, geochronology, and constraints on sedimentary source ages to fully interpret the chemistry of this uniquely useful suite of granites.

Air–Sea Fluxes of Greenhouse Gases and Oxygen in the Northern Benguela Current Region During Upwelling Events

Ground-based atmospheric observations of CO2, δ(O2/N2), N2O, and CH4 were used to make top-down estimates of the air–sea fluxes of these species from the Lüderitz and Walvis Bay upwelling cells in the northern Benguela region, during upwelling events. Average flux densities (±1σ) were 0.64 ± 0.4 μmol m−2 sec−1 for CO2, −5.1 ± 1.4 μmol m−2 sec−1 for O2 (as APO), 0.57 ± 0.3 nmol m−2 sec−1 for N2O, and 4.3 ± 5.5 nmol m−2 sec−1 for CH4. A comparison of our top-down flux estimates with shipboard-based measurements showed good agreement between both approaches. During the study, upwelling events were sources of CO2, N2O, and CH4 to the atmosphere. N2O fluxes were fairly low, in accordance with previous work suggesting that the evasion of this gas from the Benguela is smaller than for other Eastern Boundary Upwelling Systems (EBUS). Conversely, CH4 release was quite high for the marine environment, a result that supports studies that indicated a large sedimentary source of CH4 in the Walvis Bay area. These results demonstrate the suitability of atmospheric time series for characterizing the temporal variability of upwelling events and their influence on the overall marine GHG emissions from the northern Benguela region.