The influence of soil texture on the course of volume changes of soil

Volume changes of soil associated with soil moisture changes are caused by the presence of clay minerals from illite and montmorillonite groups. Clay minerals are found in the so-called clay soil component which can be quantified by laboratory analysis of the soil particle-size distribution. Consequently, the potential for volume changes in soil can be assessed from soil texture. In our study, 172 soil samples with different textures were used to measure dependencies between volume changes in soil and changes in soil moisture under laboratory conditions. The samples were collected from 11 sites in the Eastern Slovak Lowland. On the basis of the measurements, 10 mathematical models were created to compute the correlation between volume changes of soil and soil moisture content and texture. The highest accuracy was obtained with the model which assumes the content of particles < 0.002 mm. When comparing the clay particles < 0.001 mm (colloidal clay) with the particles < 0.002 mm (colloidal + physical clay) it was also found that the particles < 0.002 mm have a larger impact on the volume changes of soil than the particles < 0.001. The inclusion of particles > 0.002 mm (silt + sand) into the models resulted in either no or only negligible refinement of the soil volume change calculations.

Relationship between assimilable-nutrient content and physicochemical properties of topsoil

In the years 2008-2011, an environmental study was conducted for Polish soils, focusing on the south-eastern Poland soils, as they exhibit significant acidification. This study aimed at assessing the current pHKCl and the supply of basic macro- (P, K, Mg and S-SO4) and microelements (B, Cu, Fe, Mn and Zn) in the collected soil samples, and also at determining their relationship with the soil agronomic category, humus content and pH class. Soil reaction and humus and macronutrient content were positively correlated with the amount of colloidal clay and particles < 0.02 mm. In the majority of cases, the macro-element content in the soil was positively correlated with soil pH and humus content. As for microelements, a usually significant and positive correlation was found between the soil agronomic category and the content of manganese, iron and zinc, whereas for the content of boron and copper, no such relationship was observed. A significant and positive correlation between soil reaction and the content of manganese, iron and boron was also found. Such correlations were not observed in relation to copper and zinc content. Statistical analysis indicated that the content of boron and manganese depended to the greatest extent on the investigated physicochemical properties.

NON-CRACKING TECHNIQUES FOR GROUTING

Techniques for improving the ground base have been used since ancient times. The need of the geotechnical engineer to use zones with weak (cracked or high porosity) soil poses new, increasingly complicated problems. The solutions must consider requirements for the materials used and restrictions over the invasion. The use of natural (inorganic) materials is an approach resulting from the low speed of the change of the properties. The insignificant effect of the environment on the properties of the materials to be grouted is unquestionable. Here we should consider a number of factors connected with the anthropogenic conditions. An important aspect in the choice of materials is the expected positive changes in the structure and properties of the natural materials-improvement of soil skeleton structure, preservation of the migration of water, filling saturation, decreasing the consolidation deformability and others. The use of techniques for grouting with relatively small influence over the structure and properties of the natural materials requires certain basic mechanical parameters. Here we should pay attention to the scale of the interventions as a whole, the effect of which is considerably smaller than in usual techniques for different deep foundations. Another important aspect of these techniques is the economic effect, which creates conditions for a number of optimizations concerning the use of small-scale resources, by-products (colloidal clay, flay ash, lime, gypsum), small quantities of waste products, short periods for realization and others.

Heteroagglomeration of nanosilver with colloidal SiO2 and clay

Environmental contextThe fate of nanomaterials in the environment is related to their colloidal stability. Although numerous studies have examined their homoagglomeration, their low concentration and the presence of high concentrations of natural particles implies that heteroagglomeration rather than homoagglomeration is likely to occur under natural conditions. In this paper, two state-of-the art analytical techniques were used to identify the conditions under which nanosilver was most likely to form heteroagglomerates in natural waters. AbstractThe environmental risk of nanomaterials will depend on their persistence, mobility, toxicity and bioaccumulation. Each of these parameters is related to their fate (especially dissolution, agglomeration). The goal of this paper was to understand the heteroagglomeration of silver nanoparticles in natural waters. Two small silver nanoparticles (nAg, ~3nm; polyacrylic acid- and citrate-stabilised) were covalently labelled with a fluorescent dye and then mixed with colloidal silicon oxides (SiO2, ~18.5nm) or clays (~550nm SWy-2 montmorillonite). Homo- and heteroagglomeration of the nAg were first studied in controlled synthetic waters that were representative of natural fresh waters (50μg Ag L–1; pH 7.0; ionic strength 10–7 to 10–1 M Ca) by following the sizes of the nAg by fluorescence correlation spectroscopy. The polyacrylic acid-coated nanosilver was extremely stable under all conditions, including in the presence of other colloids and at high ionic strengths. However, the citrate-coated nanosilver formed heteroaggregates in presence of both colloidal SiO2 and clay particles. Nanoparticle surface properties appeared to play a key role in controlling the physicochemical stability of the nAg. For example, the polyacrylic acid stabilized nAg-remained extremely stable in the water column, even under conditions for which surrounding colloidal particles were agglomerating. Finally, enhanced dark-field microscopy was then used to further characterise the heteroagglomeration of a citrate-coated nAg with suspensions of colloidal clay, colloidal SiO2 or natural (river) water.

Effect of electrolytes on the microstructure and yielding of aqueous dispersions of colloidal clay

A combination of rheological, electroacoustics and cryo-SEM measurements is used to understand the link between the microscopic structures of clay mineral gels and their yielding and stability behaviours.