We employ a numerical inverse method of extracting the target-ion overlap, or
normalised Dyson orbital, directly from experimental electron momentum
spectroscopy data by using a quantum- mechanically constrained statistical
fitting procedure. This method is used in conjunction with the previously
verified, for molecular targets, plane wave impulse approximation (PWIA)
reaction model. The present procedure was applied to previously measured
momentum distributions (MDs) for the 2e′ and 1e′ valence orbitals
of cyclopropane, the 7ag orbital of trans 1,3-butadiene,
the 2e orbital of 1,2-propadiene and the 3a′1
orbital of [1.1.1]propellane. We note that this is the first
extensive application of the present method to organic molecular systems. In
each case the derived normalised Dyson orbital provided a superior
representation of the experimental MD than did the corresponding Hartree-Fock
orbital. The ramifications of this result are discussed in the text.