Evaluation of the tribological properties of two PEEKs sliding against Al2O3, WC and DLC coatings under dry friction and water lubrication

The tribology performance of two carbon fibre-reinforced polyether-ether-ketones (450FC30 and WG101) sliding against stainless steel 3Cr13 and 3Cr13 coated with aluminium oxide (Al2O3), tungsten carbide (WC) and diamond-like carbon (DLC) under dry friction and water lubrication were studied to reduce the coefficient of friction and improve the wear resistance of water-lubricated bearings. The friction and wear mechanism of different tribopairs were determined via pin-on-disc sliding tests. Experimental results showed that the WG101/Al2O3 tribopair exhibited excellent wear resistance under dry friction and water lubrication. Carbon fibres were exposed on the friction surface of WG101 when WG101 slid against Al2O3. These carbon fibres bore most of the load to reduce wear. This work provides a practical basis for selecting the optimal tribopair for water-lubricated bearings.

Rapid Synthesis of Asymmetric Methyl-Alkyl Carbonates Catalyzed by α-KMgPO4 in a Sealed-Vessel Reactor Monowave 50

Dimethyl-carbonate (DMC) is a green carboxymethylation agent for synthesis of the versatile long-chain alkyl carbonates through base-catalyzed transesterification with aliphatic alcohols. Herein, we demonstrated the facile preparation of a novel heterogeneous base catalyst α-KMgPO4 using commercially cheap metal salts via hydrothermal-calcination procedure. The combination of temperature programmed desorption (TPD) and FTIR measurements with CO2 pre-adsorbed revealed the presence of weak and medium base sites on α-KMgPO4. Furthermore, α-KMgPO4 catalyzed transesterification of DMC and n-octanol was performed in a sealed-vessel reactor (Monowave 50). The results show that the reaction was completed in only 10 min with the 97.5% conversion of n-octanol and >99% selectivity to asymmetric methyl-octyl carbonate under the optimal conditions. Additionally, the possible catalytic mechanism is proposed. As an extended contribution, the tribology performance of the asymmetric methyl-alkyl carbonates was further evaluated.

Fibers reinforced composite hydrogels with improved lubrication and load-bearing capacity

Hydrogels as one kind of soft materials with a typical three-dimensional (3D) hydrophilic network have been getting great attention in the field of biolubrication. However, traditional hydrogels commonly show poor tribology performance under high-load conditions because of their poor mechanical strength and toughness. Herein, pure chemical-crosslinking hydrogels mixed with different types of the micron-scale fibers can meet the requirements of strength and toughness for biolubrication materials, meanwhile the corresponding tribology performance improves significantly. In a typical case, three kinds of reinforcement matrix including needle-punched fibers, alginate fibers, and cottons are separately combined with Poly(n-vinyl pyrrolidone)-poly(2-hydroxyethyl methacrylate (PVP-PHEMA) hydrogels to prepare fibers reinforced composite hydrogels. The experimental results show that the mechanical properties of fibers reinforced composite hydrogels improve greatly comparable with pure PVP-PHEMA hydrogels. Among three kinds of fibers reinforced composite hydrogel, the as-prepared composite hydrogels reinforced with needle-punched fibers possess the best strength, modulus, and anti-tearing properties. Friction tests indicate that the fibers reinforced composite hydrogels demonstrate stable water-lubrication performance comparable with pure PVP-PHEMA hydrogels. Besides, the hydrogel-spunlace fiber samples show the best load-bearing and anti-wear capacities. The improved tribology performance of the composite hydrogels is highly related to mechanical property and the interaction between the fibers and hydrogel network. Finally, spunlace fibers reinforced hydrogel materials with high load-bearing and low friction properties are expected to be used as novel biomimetic lubrication materials.