An Exogenic Origin for the Volatiles Sampled by the LCROSS Impact

Returning humans to the Moon presents an unprecedented opportunity to determine the origin of volatiles stored in the permanently shaded regions (PSRs), which trace the history of lunar volcanic activity, solar wind surface chemistry, and volatile delivery to the Earth and Moon through impacts of comets, asteroids, and micrometeoroids. So far, the source of the volatiles sampled by the Lunar Crater Observation and Sensing Satellite (LCROSS) plume (1, 2) has remained undetermined. We show here that the source could not be volcanic outgassing and the composition is best explained by cometary impacts. Ruling out a volcanic source means that volatiles in the top 1–3 meters of the Cabeus PSR regolith may be younger than the latest volcanic outgassing event (~ 1 billion years ago; Gya) (3).

How atmospheric escape sculped the evolution of the Martian CO2 atmosphere over time

<p>Mars likely had a denser atmosphere during the Noachian eon about 3.6 to 4.0 billion years ago (Ga). How dense this atmosphere might have been, and which escape mechanisms dominated its loss are yet not entirely clear. However, non-thermal escape processes and potential sequestration into the ground are believed to be the main drivers for atmospheric loss from the present to about 4.1 Ga.</p> <p>To evaluate non-thermal escape over the last ~4.1 billion years, we simulated the ion escape of Mars' CO<sub>2</sub> atmosphere caused by its dissociation products C and O atoms with numerical models of the upper atmosphere and its interaction with the solar wind (see Lichtenegger et al. 2021; https://arxiv.org/abs/2105.09789). We use the planetward-scattered pick-up ions for sputtering estimates of exospheric particles including <sup>36</sup>Ar and <sup>38</sup>Ar isotopes, and compare ion escape, with sputtering and photochemical escape rates. For solar EUV fluxes ≥3 times the present-day Sun (earlier than ~2.6 Ga) ion escape becomes the dominant atmospheric non-thermal loss process until thermal escape takes over during the pre-Noachian eon (earlier than ~4.0 - 4.1 Ga). If we extrapolate the total escape of CO<sub>2</sub>-related dissociation products back in time until ~4.1 Ga, we obtain a theoretical equivalent to CO<sub>2</sub> partial pressure of more than ~3 bar, but this amount did not necessarily have to be present and represents a maximum that could have been lost to space within the last ~4.1 Ga.</p> <p>Argon isotopes can give an additional insight into the evolution of the Martian atmosphere. The fractionation of <sup>36</sup>Ar/<sup>38</sup>Ar isotopes through sputtering and volcanic outgassing from its initial chondritic value of 5.3, as measured in the 4.1 billion years old Mars meteorite ALH 84001, until the present day can be reproduced for assumed CO<sub>2</sub> partial pressures between ~0.2-3.0 bar, depending on the cessation time of the Martian dynamo (assumed between 3.6-4.0 Ga) - if atmospheric sputtering of Ar started afterwards. The later the dynamo ceased away, the lower the pressure could have been to reproduce <sup>36</sup>Ar/<sup>38</sup>Ar.</p> <p>Prior to ~4.1 Ga (i.e., during the pre-Noachian eon), thermal escape should have been the most important driver of atmospheric escape at Mars, and together with non-thermal losses, might have prevented a stable and dense CO<sub>2</sub> atmosphere during the first ~400 million years. Our results indicate that, while Mars could have been warm and wet at least sporadically between ~3.6-4.1 Ga, it likely has been cold and dry during the pre-Noachian eon (see also Scherf and Lammer 2021; https://arxiv.org/abs/2102.05976).</p>

How does volcanic outgassing differ on geological time scales between planets with and without plate tectonics?

<div>One of the main factors to assess the possible habitability of a rocky planet (either in or beyond our solar system) is its capability to maintain an atmosphere that allows for moderate temperatures at the surface and would allow water to occur in a liquid form, and that can help shield surface life from harmful radiation.</div> <div>The existence of an atmosphere depends on several factors - possible accretion from the nebula and catastrophic degassing from the crystallizing magma ocean during planet formation, later delivery of volatiles via comets, sinks of atmosphere gases to the surface or to space, and last, but definitely not least, volcanic release of volatiles from the mantle that where stored in the planet's interior during its formation stage.</div> <div>For planets of masses not too different from Earth, volcanic degassing plays a major role for the question if the planet could have an atmosphere. Lower-mass planets might not be able to keep an atmosphere but loose it entirely to space, and much more massive super-Earth planets will likely keep the primordial, catastrophically outgassed atmosphere during magma ocean crystallization, and may never be habitable at their surface due to a thick atmosphere rather comparable to Venus. The "Goldilocks zone" for potentially habitable rocky planets is therefore limited to a range from above Mars' mass to a few Earth masses. However, planets of a few Earth masses may not be able to efficiently outgas volcanic gases, if they are in a stagnant-lid regime. This may be different, though, for planets experiencing plate tectonics like Earth, where hot, molten material reaches the surface at plate boundaries and may therefore build up or replenish an atmosphere. The work presented here compares the efficiency of interior volatile depletion and degassing to the surface for rocky planets of different size and composition, either in the stagnant-lid or in the plate-tectonics regime.</div>

Global chemical weathering dominated by continental arcs since the mid-Paleozoic

Earth’s plate tectonic activity regulates the carbon cycle, and hence, climate, via volcanic outgassing and silicate-rock weathering1,2,3. Mountain building, arc-continent collisions, and clustering of continents in the tropics have all been invoked as controlling the weathering flux4,5,6, with arcs also acting as a major contributor of carbon dioxide (CO2) to the atmosphere7. However, these processes have largely been considered in isolation when in reality they are all tightly coupled. To properly account for the interactions between these processes, and the inherent multi-million-year time lags at play in the Earth system, we need to characterise their complex interdependencies. Here we analyse these interdependencies over the past 400 million years, using a Bayesian network to identify primary relationships, time lags and drivers of the global chemical weathering signal. We find that the spatial extent of continental volcanic arcs — the fastest-eroding surface features on Earth — exerts the strongest control on global chemical weathering fluxes. We find that the rapid drawdown of CO2 tied to arc weathering stabilises surface temperatures over geological time, contrary to the widely held view that this stability8 is achieved mainly by a delicate balance between weathering of the seafloor and the continental interiors.

Exoplanet secondary atmosphere loss and revival

The next step on the path toward another Earth is to find atmospheres similar to those of Earth and Venus—high–molecular-weight (secondary) atmospheres—on rocky exoplanets. Many rocky exoplanets are born with thick (>10 kbar) H2-dominated atmospheres but subsequently lose their H2; this process has no known Solar System analog. We study the consequences of early loss of a thick H2atmosphere for subsequent occurrence of a high–molecular-weight atmosphere using a simple model of atmosphere evolution (including atmosphere loss to space, magma ocean crystallization, and volcanic outgassing). We also calculate atmosphere survival for rocky worlds that start with no H2. Our results imply that most rocky exoplanets orbiting closer to their star than the habitable zone that were formed with thick H2-dominated atmospheres lack high–molecular-weight atmospheres today. During early magma ocean crystallization, high–molecular-weight species usually do not form long-lived high–molecular-weight atmospheres; instead, they are lost to space alongside H2. This early volatile depletion also makes it more difficult for later volcanic outgassing to revive the atmosphere. However, atmospheres should persist on worlds that start with abundant volatiles (for example, water worlds). Our results imply that in order to find high–molecular-weight atmospheres on warm exoplanets orbiting M-stars, we should target worlds that formed H2-poor, that have anomalously large radii, or that orbit less active stars.

Electromagnetic induction heating as a driver of volcanic activity on massive rocky planets

Aims. We investigate possible driving mechanisms of volcanic activity on rocky super-Earths with masses exceeding 3–4 M⊕. Due to high gravity and pressures in the mantles of these planets, melting in deep mantle layers can be suppressed, even if the energy release due to tidal heating and radioactive decay is substantial. Here we investigate whether a newly identified heating mechanism, namely induction heating by the star’s magnetic field, can drive volcanic activity on these planets due to its unique heating pattern in the very upper part of the mantle. In this region the pressure is not yet high enough to preclude the melt formation. Methods. Using the super-Earth HD 3167b as an example, we calculate induction heating in the planet’s interiors assuming an electrical conductivity profile typical of a hot rocky planet and a moderate stellar magnetic field typical of an old inactive star. Then we use a mantle convection code (CHIC) to simulate the evolution of volcanic outgassing with time. Results. We show that although in most cases volcanic outgassing on HD 3167b is not very significant in the absence of induction heating, including this heating mechanism changes the picture and leads to a substantial increase in the outgassing from the planet’s mantle. This result shows that induction heating combined with a high surface temperature is capable of driving volcanism on massive super-Earths, which has important observational implications.

Lethal Volcanic Gases at an Italian Country Club

High levels of carbon dioxide and hydrogen sulfide emitted by volcanic outgassing caused a deadly accident near Rome, Italy, in 2011, geoscientists have shown.