Hydrogen production via water splitting over graphitic carbon nitride (g-C3N4 )-based photocatalysis

Photocatalytic splitting of water into hydrogen and oxygen using semiconductor photocatalysts and light irradiation has been attracted much attention and considered to be an alternative for nonrenewable fossil fuel to solve environmental problems and energy crisis and also an as promising approach to produce clean, renewable hydrogen fuel. Owing to their various advantages such as low cost and environmental friendly, chemical, and thermal stability, appropriate band structure, graphitic carbon nitride (g-C3N4 ) photocatalysts have gained multitudinous attention because of their great potential in solar fuels production and environmental remediation. However, due to its fast charge carrier’s recombination, low surface, and limited absorption of the visible light restrict their activity toward hydrogen evolution and numerous modification techniques were applied to solve these problems such as structural modification, metal/nonmetal doping, and noble metal loading, and coupling semiconductors. In this chapter, we summarize recent progress in the synthesis and characterization of the g-C3N4-based photocatalyst. Several modification methods used to enhance the photocatalytic hydrogen production of g-C3N4-based photocatalyst were also highlighted. This chapter ends with the future research and challenges of hydrogen production over g-C3N4-based photocatalyst.

Boron Doped ZnO Nanostructures for Photo Degradation of Methylene Blue, Methyl Orange and Rhodamine B

The design of sensitive and efficient photo catalyst for the energy and environmental applications with minimum charge recombination rate and excellent photo conversion efficiency is a challenging task. Herein we have developed a nonmetal doping methodology into ZnO crystal using simple solvothermal approach. The boron (B) is induced into ZnO. The doping of B did not make any significant change on the morphology of ZnO nano rods as confirmed by scanning electron microscopy (SEM) without considerable change on periodic arrangement of nanostructures. The existence of B, Zn, and O is shown by energy dispersive spectroscopy (EDS). The X-ray diffraction (XRD) patterns are well matched to the hexagonal phase for both pristine ZnO and B-doped ZnO. The XRD has shown slight dislocation of 2theta degree. The UV-visible spectroscopy was used to measure the optical bandgap and photo catalytic activity for the degradation of organic dyes. The nonmetal doped ZnO has shown potential and outstanding photo catalytic activity for the photo degradation of methylene blue (MB), methyl orange (MO) and rhodamine B in aqueous solution. The photo degradation efficiency of MB, MO and rhodamine B is found to be 96%, 86% and 80% respectively. The enhanced photo catalytic activity of B-doped ZnO is indexed to the inhibited charge recombination rate due to the reduction in the optical bandgap. Based on the obtained results, it can be said that nonmetal doping is excellent provision for the design of active materials for the extended range of applications.

Nonmetal-Doping of Noble Metal-Based Catalysts for Electrocatalysis

In response to the shortage of fossil fuels, efficient electrochemical energy conversion devices are attracting increasing attentions while a daunting challenge regarding the limited electrochemical performance and high cost of...

Modified Nano-TiO2 Based Composites for Environmental Photocatalytic Applications

TiO2 probably plays the most important role in photocatalysis due to its excellent chemical and physical properties. However, the band gap of TiO2 corresponds to the Ultraviolet (UV) region, which is inactive under visible irradiation. At present, TiO2 has become activated in the visible light region by metal and nonmetal doping and the fabrication of composites. Recently, nano-TiO2 has attracted much attention due to its characteristics of larger specific surface area and more exposed surface active sites. nano-TiO2 has been obtained in many morphologies such as ultrathin nanosheets, nanotubes, and hollow nanospheres. This work focuses on the application of nano-TiO2 in efficient environmental photocatalysis such as hydrogen production, dye degradation, CO2 degradation, and nitrogen fixation, and discusses the methods to improve the activity of nano-TiO2 in the future.

First-principles investigation of nonmetal doped single-layer BiOBr as a potential photocatalyst with a low recombination rate

Nonmetal doping is an effective approach to modify the electronic band structure and enhance the photocatalytic performance of bismuth oxyhalides.

One-step preparation of sulfur-doped porous g-C3N4 for enhanced visible light photocatalytic performance

Nonmetal doping is a convenient method to adjust the visible light photocatalytic activity of graphitic carbon nitride (g-C3N4).