Increasing of the steels properties by an ecological method of isothermal and step quenching

The relevance. Improving the mechanical properties of steels makes it possible to increase the service life of machine parts, which is an important task in materials science. One of the promising directions in its solution is to obtain in steel a multiphase structure, one of the main components of which is metastable austenite, which undergoes a dynamic deformation martensitic transformation (DDMT) - self-hardening effect under loading (SHL). Methods providing the required structure are isothermal and step quenching. However, at present, when they are carried out for cooling from the austenitizing temperature and holding at the constant temperature used non-environmentally friendly substances: heated oil, molten salts or alkalis. In this regard the actual problem is the exclusion of them from the technological process. The possibility of solving this problem on several steels has shown. Purpose is to show the possibility of increasing the mechanical properties of the studied steels 30ХГСА, 38ХС, 45Г, 40ХН, 10Г12, 60Х18 by using rational modes of an environmentally friendly method of steels quenching (isothermal - for low-alloyed and step - for high-alloyed) due to obtaining in their structure along with other components of metastable residual austenite and the implementation of the SHL effect. Research methods. Samples of the investigated steels after austenitization (in some cases with holding in IСIT) were cooled in water to the temperature of lower bainite formation (isothermal quenching) or stabilization of supercooled austenite to martensitic transformation upon cooling (step quenching), after which they were kept in a furnace and cooled in air to room temperature. Durometric, metallographic and X-ray research methods were used. The tensile properties and impact strength were determined. These properties were compared with those obtained for the studied steels after a typical heat treatment, including quenching in oil and tempering. Results. It is shown that isothermal and step quenching of the investigated steels without the use of non-environmentally friendly substances, carried out according to rational modes, makes it possible to increase the mechanical properties in comparison with their level after the commonly used quenching in oil (fire hazard, the vapors are cancerogenic) and tempering. This is achieved by obtaining a multiphase structure with metastable austenite. Scientific novelty. It is proposed to obtain a multiphase structure with metastable austenite in them to improve the mechanical properties of the studied steels by conducting isothermal and step quenching in an environmentally friendly way without using heated oil, molten salts or alkalis. Practical value. For the studied steels the modes of isothermal and step quenching are determined in an environmentally friendly way, which make it possible to increase the mechanical properties in comparison with the level achieved by quenching and tempering. Wherein in contrast to a similar typical quenching method are excluded the costs of purchasing salts or alkalis, their disposal and washing of products from them. Compared to quenching and tempering, the new method does not require the use of oil and tempering. The latter improves ecology and reduces energy consumption during heat treatment.

Effect of Martensite Morphologies on Corrosion in 5% H2SO4 Solution of Borided X70 Dual Phase Steel

In the present investigation, some electrochemical properties of dual phase X70 steels with different martensite morphologies which have undergone boriding were studied. To obtain a variety of martensite morphologies, Direct Quenching (DQ), Intermediate Quenching (IQ) and Step Quenching (SQ) heat treatments were applied at an intercritical annealing temperature (IAT) of 760℃. The treatment (DQ) allowed the formation of fine martensite evenly distributed in the ferrite matrix. (IQ) treatment showed the formation of martensite along the ferrite / ferrite grain boundaries. In contrast, treatment (SQ) induced the formation of a banded morphology of martensite and ferrite. The realization of borides on X70 (DP) steel was carried out in a powder mixture containing 5% of B4C as source of boron, 5% of NaBF4 as activator and 90% of SiC as diluent at 950℃ for a period of time from 4 h. The corrosion behavior of X70 (DP) steel has been explored by the Tafel extrapolation method in a 5 wt. % H2SO4 solution. The corrosion resistance of steel which has undergone boriding (BDP) is higher than that of steel which has not undergone it (DP).