Effect of Ultra-Fine Grinding on the Structure of Plant Raw Materials and the Kinetics of Melanin Extraction

Enhancing the extraction rate is one of the key objectives in optimization of extraction of substances from biogenic raw materials. Ultra-fine grinding of plant raw materials (to achieve particle size less than 300 µm) is a very appealing method for increasing the extraction rate using relatively simple equipment. However, this approach often fails to yield the desired result. This study focuses on the kinetics of melanin extraction from two types of raw materials: fungus Ganoderma applanatum and buckwheat husk. Particle size is shown to be just one of the key factors. The degree of order of plant-based feedstock strongly affects the intraparticle diffusion constants and can be a parameter controlling the diffusion rate. It has been shown that there exist optimal degrees of disorder of the crystal structure of plant raw materials, which have a dome-shaped dependence pattern and allow one to increase the diffusion coefficient by several dozen times. The kinetics of melanin extraction was described by some kinetic models that include the first order equation, the Baker and Lonsdale model, the Axelrud equation, and the Ritger–Peppas model.

Research into thickening processes of concentrates of gold-bearing ores

The aim was to improve the thickening of an ultra-fine flotation concentrate by efficient flocculants when processing refractory sulphide gold-bearing ores from South Urals deposits. The chemical ore composition was studied using gravimetric, atomic absorption, chemical, X-ray fluorescent, assay test and electron microprobe analytical methods. Particle size analysis of the ultra-fine flotation concentrate under study was performed using a Malvern Hydro Mastersizer 2000MU analyser (Malvern Panalytical Ltd, UK). In thickening experiments, samples with the same composition after the ultra-fine grinding process were used. The gold content in the ore was determined (22.8 g/t) based on analytical studies on the material composition of samples. At least 92% of the final grain size class is -20 microns. Laboratory tests performed on eight samples containing polyacrylamide-based flocculants revealed an optimal A44 flocculant (produced in China). The flocculant meets the requirements for minimum flow rate, deposition rate and L:S ratio. The specific performance of the JX20 radial thickener (JPMFex Corp. Ltd., China) was calculated. The optimal flocculant flow rate is 200 g/t per 1 t of thickened material, leading to thickening 50 t of pulp per 1 m2 of thickener per day. The A44 flocculant is recommended for pilot testing. Thus, developing, testing and implementing fundamentally new reagents and improving existing technologies of processing gold-containing ores and concentrates are necessary to intensify the ore dewatering processes after ultra-fine grinding.

Challenges Related to the Processing of Fines in the Recovery of Platinum Group Minerals (PGMs)

In order to increase the recovery of PGMs by flotation, it is necessary to optimise the liberation of the key minerals in which the platinum group elements (PGEs) are contained which include sulphides, arsenides, tellurides, and ferroalloys among others, while at the same time ensuring the optimal depression of gangue minerals. In order to achieve this, comminution circuits usually consist of two or three stages of milling, in which the first stage is autogeneous, followed by ball milling. Further liberation is achieved in subsequent stages using ultra-fine grinding. Each comminution stage is followed by flotation in the so-called MF2 or MF3 circuits. While this staged process increases overall recoveries, overgrinding may occur, hence creating problems associated with fine particle flotation. This paper presents an overview of the mineralogy of most of the more significant PGM ores processed in South Africa and the various technologies used in comminution circuits. The paper then summarises the methodology used in flotation circuits to optimise recovery of fine particles in terms of the collectors, depressants, and frothers used. The effect of entrainment, slimes coating, changes in rheology caused by the presence of a significant amount of fines and of chromite recovery is addressed.

Experimental results from face and lateral fine grinding of fused silica and BK7 using metal and resin bonded tools

The experimental setup shall compare face grinding with lateral grinding in a single processing step using fused silica and BK7 as materials. Resin and metal bonded tools are used in face and lateral grinding strategies. The paper presents the results in order to deepen the knowledge about those grinding technologies and to further improve the properties of fabricated components. Furthermore, the results confirm, that ultra-fine grinding is a technology, which can be used to process inorganic non-metallic materials with high quality surfaces with a low roughness and high flatness in a low processing time.

Ultra-fine grinding of inorganic non-metallic materials using various types of bonds and processing strategies

Ultra-fine grinding is a technology, which can be used to process inorganic non-metallic materials. High quality surfaces with a low roughness, and high flatness are achievable in a low processing time. The experimental setup which is described shall compare face grinding with lateral grinding in a single processing step using various materials, bonds and processing parameters. The results are supposed to deepen the knowledge about this grinding technology to further improve the properties of fabricated components.

Surface Organic Modification of CaCO3-TiO2 Composite Pigment

To improve the properties and dispersibility of CaCO3-TiO2 composite pigments (CaCO3-TiO2) in organic matrices, the surface modification of CaCO3-TiO2 was performed with sodium stearate (SS) as an organic modifier by wet ultra-fine grinding in a stirred mill. The pigment properties of modified CaCO3-TiO2 and its dispersibility in organic media were tested and characterized. The binding mechanism between CaCO3-TiO2 and SS was explored by infrared spectrometry (IR) and X-ray photoelectron energy spectroscopy (XPS). The results showed that the mechanical grinding strength and SS dosage had a significant effect on the activation index and sedimentation rate of CaCO3-TiO2. After surface modification, the surface of CaCO3-TiO2 turned from a hydrophilic surface to a hydrophobic surface and the surface free energy was reduced. In addition, the hiding property and dispersibility of CaCO3-TiO2 in the organic medium were significantly improved. IR and XPS results indicated that the modifier SS was adsorbed on the surface of CaCO3-TiO2 by chemical combination.