Modern view on steel desulfurization

Modern technological schemes of steel production do not allow to achieve low (< 0.01 % S) and ultra-low (<0.005 % S) sulfur content on the production of in the metal directly. That is why out-of-furnace steel treatment is often used to remove sulfur. Desulfurization process of steel depends on the chemical composition of the slag, the time of its formation in the ladle, metal oxidation, conditions of mixing of steel in a ladle, additional technological operations and ladle metal processing. Methods are widely used for desulfurization of steel treatment of steel with solid slag-forming mixtures, synthetic slag, lime-aluminous slag, silico-calcium and other powdered materials. Modern approaches to the process of steel desulfurization in conditions steel production are analyzed in the Study. In particular, the Ukrainian (on the example of PJSC ‘Azovstal Iron & Steel Works’ and PJSC ‘Dneprovsky Integrated Iron & Steel Works named after Dzershinsky’) and foreign (on the example of PJSC ‘Severstal’ and PJSC ‘Magnitogorsk Iron & Steel Works’) experience of desulfurization under oxygen converter production. The use of technological complexes ‘Installation of pig iron desulfurization steel making unit’ and ‘Cast iron desulfurization installation steel making unit is ‘oven-bucket’ installation’ provides a deeper desulfurization of steel, the possibility of optimizing the cost of steel production, expands range of scarce products and eliminates a number of restrictive conditions that complicate current production. The analysis of steel C80D desulfurization process is given in the conditions of JSC ‘Moldova Steel Works’, in which partial sulfur removal occurs in an arc steel making furnace, and the ultra-low content is achieved by creating a highly basic refining slag in the process out-of-furnace processing of steel. The study of the kinetics of the desulfurization process of 20GL steel in the conditions of JSC ‘Tashkent Mechanical Plant’ with the use of solid slag-forming mixtures and modification of steel with rare-earth metals is analyzed. The issue of desulfurization of electric steel in the conditions of OJSC ‘Byelorussian Steel Works’ with injection of powdered materials through the installation ‘Velko’ during out-of-furnace processing of steel is considered. Keywords: steel desulfurization, desulfurizer reagent, degree of desulfurization, cast iron desulfurization installation, out-of-furnace processing of steel, ‘‘oven-bucket’’ installation.

Investigation of the direct-flow burners and nozzles arrangement at the direct-flow-vortex coal combustion in a furnace with solid slag removal

The paper presents results of the furnace aerodynamics investigation using direct-flow burners and air nozzles (DFBAN) with solid slag removal (SSR). The studies were performed using the computational fluid dynamics software ANSYS Fluent. The paper includes recommendations for the development of effective solid fuel combustion schemes with DFBAN, methods for researching and optimization of the combustion aerodynamics with the use of DFBAN, optimization criteria, initial data for the study. The scheme for burning Kuznetsk lean coal with the use of DFBAN and SSR was developed. Several series of calculations were performed for the developed scheme. In these calculations, the dependencies of the indicators of efficiency, furnace ecological safety and reliability on the nozzles and burners positions, which are located in the first zone of the scheme, were found. The first stage of the optimization of the developed scheme burning solid fuel with the SSR was made.

Numerical Analysis of An 80,000 Nm3/h Fly Ash Entrained-Flow Gasifier At Various Burner Inclination Angles

The raw syngas effluent from a fluidized bed gasifier typically contains a large amount of fly ash having a high concentration of carbon, which is undesirable. The present work examined the newly developed entrained-flow gasification technology intended to gasify raw syngas. Simulation of gas-solid flow and reaction behavior in an industrial-scale entrained-flow gasifier applying this new technology was first performed to obtain a better understanding of the particle flow and gasification characteristics. In addition, the devolatilization and heterogeneous reactions of fly ash particles were characterized by thermogravimetric analysis and user-defined function. The predictions from the simulation showed good agreement with the results of in situ experimental measurements. The combustion reaction for raw syngas occurred in the burner jet zone. As the hot gaseous products diffused, gasification reactions dominated the other zones. When burner inclination angle was 0°, 8.5°, and 25.5°, the temperature at the bottom outlet of the gasifier was lower than the ash fusion temperature with the value of 1360 °C. Solid slag formed and blocked the outlet. By comparison, this gasifier with the burner inclination angle of 17° could discharge the liquid slag and function as a continuous operation. In this way, the carbon conversion in fly ash reached the maximum value of 89.5%.

Integrated research of slaging intensityof the boilerunit heating surfaceswhen burning non-project fuels

THE PURPOSE. Comprehensive research of the slagging intensity is the heating surfaces of the BKZ-420-140 boiler unit with solid slag removal at the Abakan CHP when burning non-project fuels. The relevance of the work is due to the technical necessity and economic feasibility of conversion boiler units to combustion of non-design coals. METHODS. The problem has been analyzed by methodology for conducting complex tests, measurements and processing of experimental data, as well as the results of experimental and computational studies of a boiler unit when operating on coals of various qualities. RESULTS. Qualitative and quantitative parameters for assessing the properties of off-design coals and their behavior in real operating conditions of radiation, semi-radiation and convective conditions, taking into account their modes and design functions, have been obtained. CONCLUSION: A computational analysis of the operating modes of boiler units when burning non-design fuels showed that a promising technology for involving non-design coals in the fuel and energy balance of a thermal power plant is providing a scientifically based mixture of design and nondesign fuels.Analysis of the slagging and polluting properties of non-design coals makes it possible to predict changes in the characteristics of the thermal efficiency of heating surfaces and to develop many practical recommendations for optimizing the parameters of the cleaning equipment installed on the boiler.Also, mixtures of fuels were determined for which the wall temperatures of the metal of the outlet stack of the superheater increase, which significantly reduces the strength characteristics of the surface.The assessment and prediction of the reliability of the heating surface is carried out by calculating the temperature of the metal wall in the most heat-stressed place.

Technical Solution for the Disposal of Solid Slag from Metallurgical Plants with Production of Abrasive Powders

This article considers a technical solution to the production of abrasive powders according to the standard ISO 11126 from copper slag and nickel slag with the use of air classification. Justification of the selection of air classifier for the process of classification of copper slag is performed. The results of laboratory studies on the effect of the consumption concentration on the quality of the separation of slag particles in apparatus with an inclined louver lattice with reverse air suction are presented. This article then discusses the dependence of the material separation boundary on the air flow rate through the classifier’s louver. Based on the theoretical calculation, an industrial apparatus with a capacity of 50 t/h on initial raw materials was developed, laboratory tests were industrialized, and the results of industrial tests were shown. Industrial testing was carried out and the results of are shown. Keywords: granulated slag, disposal, abrasive powder, granulometric composition, consumption concentration, air classifier, screening

Investigation on the Slag-Steel Reaction of Mold Fluxes Used for Casting Al-TRIP Steel

The reaction between [Al] in molten steel and (SiO2) in the liquid slag layer was one of the restrictive factors in the quality control for high Al-TRIP steel continuous casting. In this work, the composition and property variations of two slags during a slag-steel reaction were analyzed. Accordingly, the crystalline morphologies of slag were discussed and the solid layer lubrication performance was evaluated by Jackson α factors. In addition, a simple kinetics equilibrium model was established to analyze the factors which affected SiO2 consumption. The results reflected that slag-steel reacted rapidly in the first 20 minutes, resulting in the variation of viscosity and the melting temperature of slags. The slag-steel reaction also affected the crystal morphology significantly. Slag was precipitated as crystals with a higher melting temperature, a higher Jackson α factor, and a rougher boundary with the consumption of SiO2 and the generation of Al2O3. In other words, although generated Al2O3 acted as a network modifier to decrease the viscosity of the liquid slag layer adjacent slab shell, the consumption of SiO2 led to the deterioration of the lubrication performance in the solid slag layer adjacent copper, which was detrimental to the quality control for high Al-TRIP steel. Finally, a kinetics equilibrium model indicated that it is possible to reduce a slag-steel reaction by adjusting factors, such as the diffusion coefficient k, cSiO2, ρf and Lf, during the actual continuous casting process.

Quantification of crystalline fraction of solid slag film using X-ray powder diffraction

This paper introduces a new method to determine the crystalline fraction in samples containing amorphous phases from experimental X-ray diffraction data. Computer generated codes, one for each measured data point, are used to interpret the pattern as to where diffraction peaks exist and what is the angular breadth of each peak's intensity above background. Two parameters are defined that are used to identify the position and intensity of the crystalline phase diffraction peaks. For mold fluxes used in continuous casting, the crystalline fraction of solid slag film is a key factor that can affect heat transfer between solidified shell and mold. In this work, a new method was developed to determine the crystallinity of solid slag films. This method does not require structure parameters or other references, and results can be obtained directly by reading a text file with diffraction data. Results indicate that, there is a positive correlation between crystalline fraction and integrated intensities corresponding to crystalline phases. The selection of integration interval does not have much effect on results. To simplify computations, 20–45°2θwas considered as an appropriate interval.