Optical rotation dispersion of cholesteric-nematic mixture

The dispersion of the specific rotation constant of a cholesteric-nematic mixture of 5CB and Ch17 at a low concentration was studied by optical spectroscopy. The dispersion of the anisotropy of the refractive index as a function of the wavelength is studied, and the helical pitch of the cholesteric-nematic mixture is calculated.

THE RESEARCH OF STABILITY OF STATIONARY ROTATION A ROTOR SYSTEM WITH A LIQUID, THE AXLE OF WHICH IS LOCATED IN ANISOTROPIC FIXINGS

Earlier, one of the authors proposed and developed (together with coworkers) an original method to study the stability of stationary rotation of rotary systems containing a viscous liquid and having a drive that maintains the angular velocity of rotation constant. It was assumed that the rotor has axial symmetry, the anchors of its axis are isotropic. The method is based on two theorems, according to which a change in the degree of instability is associated with the possibility of a perturbed motion of the circular precession type. This motion has a remarkable property: the velocity field and the shape of the liquid surface do not depend on time in a specially selected non-inertial reference frame associated with the line of centers. Finding the conditions for the feasibility of circular precession makes it possible to effectively construct the boundaries of the stability regions of the stationary rotation regime in the space of problem parameters. In addition, the study of the occurrence of circular precession allows us to find the conditions under which a subcritical (supercritical) Andronov-Hopf bifurcation takes place in the rotor system and to identify "dangerous" (“safe”) sections of the boundaries of the stability regions. In this paper, the previously proposed method of stability research applies to systems in which the rotor axis is located in anisotropic Laval type anchors. In the study of rotary systems of this type, it is possible to link the change in the degree of instability with the feasibility of perturbed movements of the elliptical precession type. It can be shown that the imaginary characteristic numbers of the equations in deviations from the stationary rotation mode are possible only in the case when there is a perturbed motion in the form of an elliptical precession. An example of a study of the stability of stationary rotation of a typical rotary system is given. Mechanical effects caused by the fact that gyroscopic stabilization becomes impossible with anisotropic fixing of the rotor axis are noted.

Theoretical analysis of NMR shieldings in XSe and XTe (X = Si, Ge, Sn and Pb): the spin-rotation constant saga

How the electronic contribution to the spin-rotation constant is close to the paramagnetic contribution of the NMR absolute shielding constant?

Rotational Spectra of Phosphorus Monosulfide up to 1 THz

The submillimeter-wave rotational spectrum of the PS radical in the electronic and vibrational ground state (X2 ΠI/2 , X2Π3/2) was recorded with the Cologne terahertz spectrometer in the fre-quency region between 540 GHz and 1.07 THz, covering rotational quantum numbers from J = 30.5 to 60.5. The PS radical has been produced by discharging PSCl3 buffered with Ar. For all transitions the Λ-doubling was resolved for both the 2ΠI/2 and 2Π3/2 states. For some transitions with ΔF = 0 the hyperfine structure (hfs) caused by the P-atom could partially be resolved even for rather high J values. Analysis of the complete rotational data set of PS allows the derivation of a full set of molecular parameters, including the rotational constants B, D, H, the fine-structure constants A,γ , Dγ , the parameters for the Λ-doubling p, Dp , q, and the magnetic hyperfine constants a, b, c, d, CI. All parameters have been determined, whereby a, c, and the nuclear spin rotation-constant CI were obtained for the first time.