Removing Gas from a Closed-End Small Hole by Irradiating Acoustic Waves with Two Frequencies

Filling microstructures in the air with liquid or removing trapped gases from a surface in a liquid are required in processes such as cleaning, bonding, and painting. However, it is difficult to deform the gas–liquid interface to fill a small hole with liquid when surface tension has closed one end. Therefore, it is necessary to have an efficient method of removing gas from closed-end holes in liquids. Here, we demonstrate the gas-removing method using acoustic waves from small holes. We observed gas column oscillation by changing the hole size, wettability, and liquid surface tension to clarify the mechanism. First, we found that combining two different frequencies enabled complete gas removal in water within 2 s. From high-speed observation, about half of the removal was dominated by droplet or film formation caused by oscillating the gas column. The other half was dominated by approaching and coalescing the divided gas column. We conclude that the natural frequency of both the air column and the bubbles inside the tube are important.

Исследование реакции поверхности жидкости на импульсное воздействие наклонной газовой струи при малых числах Рэйнольдса

A mathematical description of the motion of a cavity on the liquid surface under an oblique action of a gas jet is obtained using the well-known expressions for the movement of a gas bubble in a liquid. The boundary of the viscous drag force domination over the form drag force is determined. The impingement of the gas jet on the liquid surface is considered as a dynamic object of the automatic control theory. It is found that the dynamic properties of the two-phase system "gas jet - liquid" are described by the integrator equations. Using a specially designed setup, the transient response of the "gas jet - liquid" system were experimentally obtained for the aerodynamic action at angles of 20º and 50º to the surfaces of liquids with the viscosities of 0.71 and 26.1 Pa•s (Reynolds number Re < 2). The research results are necessary for the analysis of the non-contact aerodynamic method of liquid viscosity measurements.

Генерация поверхностного потока жидкости в каналах капиллярными колебаниями и волнами

The generation of a directed flow on the water surface in channels with sources and resonators of capillary oscillations is detected and investigated. The surface flow is caused by the movement of the liquid through the gaps between the resonators, as well as between the resonator and the channel walls, under a curved surface that is locally deformed by the sources of capillary vibrations, the transfer of energy of the locally curved surface of the liquid by capillary waves, and the transmission of wave momentum to the particles of the liquid surface in one direction. It is shown that capillary waves together with the energy transfer an excess surface, the flux density of which is equal to the flux of the surface deformation. Moving devices with a capillary-wave accelerator of the surface liquid flow are demonstrated.

Opto-Microfluidic Fabry-Perot Sensor with Extended Air Cavity and Enhanced Pressure Sensitivity

An opto-microfluidic static pressure sensor based on a fiber Fabry-Perot Interferometer (FPI) with extended air cavity for enhancing the measuring sensitivity is proposed. The FPI is constructed in a microfluidic channel by the combination of the fixed fiber-end reflection and floating liquid surface reflection faces. A change of the aquatic pressure will cause a drift of the liquid surface and the pressure can be measured by detecting the shift of the FPI spectrum. Sensitivity of the sensor structure can be enhanced significantly by extending the air region of the FPI. The structure is manufactured by using a common single-mode optical fiber, and a silica capillary with the inner wall coated with a hydrophobic film. A sample with 3500 μm air cavity length has demonstrated the pressure sensitivity of about 32.4 μm/kPa, and the temperature cross-sensitivity of about 0.33 kPa/K.

Liquid Surface-Enhanced Raman Spectroscopy (SERS) Sensor-Based Au-Ag Colloidal Nanoparticles for Easy and Rapid Detection of Deltamethrin Pesticide in Brewed Tea

Deltamethrin pesticides can cause inflammation, nephrotoxicity and hepatotoxicity as well as affect the activity of antioxidant enzymes in tissues. As a result of this concern, there is a rising focus on the development of fast and reliable pesticide residue testing to minimise potential risks to humans. The goal of this study is to use Au-Ag colloid nanoparticles as liquid surface-enhanced Raman spectroscopy (SERS) to improve the Raman signal in the detection of deltamethrin pesticide in a brewed tea. The liquid SERS system is fascinating to study due to its ease of use and its unlikeliness to cause several phenomena, such as photo-bleaching, combustion, sublimation and even photo-catalysis, which can interfere with the Raman signal, as shown in the SERS substrate. Our liquid SERS system is simpler than previous liquid SERS systems that have been reported. We performed the detection of pesticide analyte directly on brewed tea, without diluting it with ethanol or centrifuging it. Femtosecond laser-induced photo-reduction was employed to synthesise the liquid SERS of Au, Au-Ag, and Ag colloidal nanoparticles. The SERS was utilised to detect deltamethrin pesticide in brewed tea. The result showed that liquid SERS-based Ag NPs significantly enhance the Raman signal of pesticides compared with liquid SERS-based Au NPs and Au-Ag Nanoalloys. The maximum residue limits (MRLs) in tea in Indonesia are set at 10 ppm. Therefore, this method was also utilised to detect and improve, to 0.01 ppm, the deltamethrin pesticide Limit of Detection (LOD).

Static and Dynamic Optical Analysis of Micro Wrinkle Formation on a Liquid Surface

A spatially periodic voltage was used to create a dielectrophoresis induced periodic micro wrinkle deformation on the surface of a liquid film. Optical Coherence Tomography provided the equilibrium wrinkle profile at submicron accuracy. The dynamic wrinkle amplitude was derived from optical diffraction analysis during sub-millisecond wrinkle formation and decay, after abruptly increasing or reducing the voltage, respectively. The decay time constant closely followed the film thickness dependence expected for surface tension driven viscous levelling. Modelling of the system using numerical solution of the Stokes flow equations with electrostatic forcing predicted that wrinkle formation was faster than decay, in accord with observations.

High-Energy Ejection of Molecules and Gas-Dust Outbursts in Coal Mines

In the current work, using the framework of the formalism found in the Bogolyubov–Born–Green–Kirkwood–Yvon (BBGKY) equations for the distribution functions of particle groups, the effective single-particle potential near the surface of the liquid was analyzed. The thermodynamic conditions under which a sudden opening of the liquid surface leads to high-energy ejection of atoms and molecules were found. The energies of the emitted particles were observed to be able to significantly exceed their thermal energy. Criteria of the ejection stability of the liquid surface and the self-acceleration of ejection were formulated. The developed theory was used to explain the phenomenon of the self-acceleration of gas-dust outbursts in coal mines during the explosive opening of methane traps. The results also explained the mechanisms of generating significant amounts of methane and the formation of coal nanoparticles in gas-dust outbursts. The developed approach was also used to explain the phenomenon of the self-ignition of hydrogen when it enters the atmosphere.

Theoretical background for simulation of physical processes in the interfacial layer “solid-liquid”

The paper shows a modification of the quasi-thermodynamic approach to simulation of the interfacial layer from conditions of its mechanical equilibrium. The anisotropy of the interfacial stress tensor is represented as the sum of the ball and deviator parts, where the ball part defines the pressure in the medium and the deviator part forms the components responsible for the liquid surface tension. Obtaining a closed system of equilibrium equations was possible taking into account evaporation from free surface of liquid. The result is a simple expression for determining the thickness of the interfacial layer.