Fast One-Step Synthesis of Anisotropic Silver Nanoparticles

The shape control of metal nanoparticles, along with the size, is critical for most of their applications as they control their optical properties. Anisotropic metal nanoparticles show superior performance in a number of applications compared to spherical ones. Shape control is usually achieved by a two-step process, where the first involves the formation of spherical nanoparticles and the second is about the actual shape transformation. In this paper, we report on a fast and facile synthesis of silver nanoplates in a single step, involving laser ablation of a silver target in a liquid medium while this is exposed to light irradiation and hydrogen peroxide flow. We obtained anisotropic particles with a mixture of shapes, of 70–80 nm in size and 10–20 nm in thickness, which showed a plasmon sensitivity greater than 200 nm/RIU.

Fracture prediction in spin forming of anisotropic metal sheets

Fracture often occurs in the spin forming process of thin-walled metal sheets, due to the limited fracture strain and local large plastic deformation of the sheets during the process. However, the accurate fracture prediction is a huge challenge due to the combinations of material anisotropy, complex deformation history and contact boundary conditions in the process. Though there are scattered uncoupled ductile fracture criteria proposed with various deformation mechanisms, reasons for their different fracture prediction abilities remain unclear. Thus in this study, eight popular uncoupled ductile fracture criteria i.e., Freudenthal, C-L, R-T, Brozzo, Oh, Oyane, MMC4 and DF2016, are embedded into an anisotropic constitutive model through VUMAT interface in the ABAQUS simulation software and then realized their fracture prediction in the spin forming process of an anisotropic metal sheet. The results show that the damage accumulation in the spin forming process occurs in a wide range of stress triaxiality, and the most damage accumulation occurs in the stress triaxiality range of 0–1/2. Furthermore, the eight fracture criteria have different prediction abilities in the process and a new deformation history related equivalent fracture strain is proposed to explain these differences. In addition, there exists the abnormal phenomenon that some simple damage models, as Oyane, Oh, etc. provide the more accurate fracture prediction ability than the complex and advanced MMC4 and DF2016 models in the process, and reasons for this phenomenon are explained.

The role of deep eutectic solvents and carrageenan in synthesizing biocompatible anisotropic metal nanoparticles

Plasmonic metal nanoparticles are widely used for many applications due to their unique optical and chemical properties. Over the past decade, anisotropic metal nanoparticles have been explored for imaging, sensing, and diagnostic applications. The variations and flexibility of tuning the size and shape of the metal nanoparticles at the nanoscale made them promising candidates for biomedical applications such as therapeutics, diagnostics, and drug delivery. However, safety and risk assessment of the nanomaterials for clinical purposes are yet to be made owing to their cytotoxicity. The toxicity concern is primarily due to the conventional synthesis route that involves surfactants as a structure-directing agent and as a capping agent for nanoparticles. Wet chemical methods employ toxic auxiliary chemicals. However, the approach yields monodispersed nanoparticles, an essential criterion for their intended application and a limitation of the green synthesis of nanoparticles using plant extracts. Several biocompatible counterparts such as polymers, lipids, and chitosan-based nanoparticles have been successfully used in the synthesis of safe nanomaterials, but there were issues regarding reproducibility and yield. Enzymatic degradation was one of the factors responsible for limiting the efficacy. Hence, it is necessary to develop a safer and nontoxic route towards synthesizing biocompatible nanomaterials while retaining morphology, high yield, and monodispersity. In this regard, deep eutectic solvents (DESs) and carrageenan as capping agent for nanoparticles can ensure the safety. Carrageenan has the potential to act as antibacterial and antiviral agent, and adds enhanced stability to the nanoparticles. This leads to a multidimensional approach for utilizing safe nanomaterials for advanced biomedical and clinical applications.

Efficient overall water splitting in acid with anisotropic metal nanosheets

Water is the only available fossil-free source of hydrogen. Splitting water electrochemically is among the most used techniques, however, it accounts for only 4% of global hydrogen production. One of the reasons is the high cost and low performance of catalysts promoting the oxygen evolution reaction (OER). Here, we report a highly efficient catalyst in acid, that is, solid-solution Ru‒Ir nanosized-coral (RuIr-NC) consisting of 3 nm-thick sheets with only 6 at.% Ir. Among OER catalysts, RuIr-NC shows the highest intrinsic activity and stability. A home-made overall water splitting cell using RuIr-NC as both electrodes can reach 10 mA cm−2geo at 1.485 V for 120 h without noticeable degradation, which outperforms known cells. Operando spectroscopy and atomic-resolution electron microscopy indicate that the high-performance results from the ability of the preferentially exposed {0001} facets to resist the formation of dissolvable metal oxides and to transform ephemeral Ru into a long-lived catalyst.

Laser assisted synthesis of anisotropic metal nanocrystals and strong light-matter coupling in decahedral bimetallic nanocrystals

The advances in colloid chemistry and nanofabrication allowed us to synthesize noble monometallic and bimetallic nanocrystals with tunable optical properties in the visible and near infrared region of the electromagnetic spectrum.