Generalized Kerker effect in PT-symmetric nanoantenna array

All-dielectric nanophotonics is a rapidly developing and practical alternative to plasmonics for nanoscale optics. The electric and magnetic Mie resonances in high-index low-loss dielectric nanoresonators can be engineered to exhibit unique scattering response. Recently, nanophotonic structures satisfying parity-time (PT) symmetry have been shown to exhibit novel scattering responses beyond what can be achieved from the conventional nanoresonators. The complex interference of the magnetic and electric Mie resonances and lattice modes excited in PT-symmetric nanoantenna arrays give rise to a scattering anomaly called lasing spectral singularity (SS), where the scattering coefficients tend to infinity. In our previous work [1], we demonstrated the existence of lasing spectral singularities in vertically stacked 2D GaInP PT-symmetric metasurface. In this paper, we analyze the direction-sensitive scattering response of the PT-symmetric GaInP metasurface by decomposing the total scattered field into the electric and magnetic multipoles. The far-field scattering response at the singularity is highly asymmetric for incidence from either the gain or loss side and can be tuned by changing the geometry. By analyzing the phase of even- and odd-parity higher order multipoles, we explain the observed scattering response over a broad parameter space in terms of generalized Kerker effect. The interference between the direction-dependent excitation of different order multipoles and the overall 2D-lattice resonance opens a route towards designing a special class of tunable sources exhibiting direction-sensitive emission properties.

Striping of orbital-order with charge-disorder in optimally doped manganites

The phase diagrams of LaMnO3 perovskites have been intensely studied due to the colossal magnetoresistance (CMR) exhibited by compositions around the $${\frac{3}{8}}^{th}$$ 3 8 t h doping level. However, phase segregation between ferromagnetic (FM) metallic and antiferromagnetic (AFM) insulating states, which itself is believed to be responsible for the colossal change in resistance under applied magnetic field, has prevented an atomistic-level understanding of the orbital ordered (OO) state at this doping level. Here, through the detailed crystallographic analysis of the phase diagram of a prototype system (AMn$${}_{3}^{A^{\prime} }$$ 3 A ′ Mn$${}_{4}^{B}$$ 4 B O12), we show that the superposition of two distinct lattice modes gives rise to a striping of OO Jahn-Teller active Mn3+ and charge disordered (CD) Mn3.5+ layers in a 1:3 ratio. This superposition only gives a cancellation of the Jahn-Teller-like displacements at the critical doping level. This striping of CD Mn3.5+ with Mn3+ provides a natural mechanism though which long range OO can melt, giving way to a conducting state.

In-Situ X-ray Photoelectron Spectroscopy and Raman Microscopy of Roselite Crystals, Ca2(Co2+,Mg)(AsO4)2 2H2O, from the Aghbar Mine, Morocco

Roselite from the Aghbar Mine, Morocco, [Ca2(Co2+,Mg)(AsO4)2 2H2O], was investigated by X-ray Photoelectron and Raman spectroscopy. X-ray Photoelectron Spectroscopy revealed a cobalt to magnesium ratio of 3:1. Magnesium, cobalt and calcium showed single bands associated with unique crystallographic positions. The oxygen 1s spectrum displayed two bands associated with the arsenate group and crystal water. Arsenic 3d exhibited bands with a ratio close to that of the cobalt to magnesium ratio, indicative of the local arsenic environment being sensitive to the substitution of magnesium for cobalt. The Raman arsenate symmetric and antisymmetric modes were all split with the antisymmetric modes observed around 865 and 818 cm−1, while the symmetric modes were found around 980 and 709 cm−1. An overlapping water-libration mode was observed at 709 cm−1. The region at 400–500 cm−1 showed splitting of the arsenate antisymmetric mode with bands at 499, 475, 450 and 425 cm−1. The 300–400 cm−1 region showed the corresponding symmetric bending modes at 377, 353, 336 and 304 cm−1. The bands below 300 cm−1 were assigned to lattice modes.

Critical charge fluctuations and emergent coherence in a strongly correlated excitonic insulator

Excitonic insulator is a coherent electronic phase that results from the formation of a macroscopic population of bound particle-hole pairs—excitons. With only a few candidate materials known, the collective excitonic behavior is challenging to observe, being obscured by crystalline lattice effects. Here we use polarization-resolved Raman spectroscopy to reveal the quadrupolar excitonic mode in the candidate zero-gap semiconductor Ta2NiSe5 disentangling it from the lattice phonons. The excitonic mode pronouncedly softens close to the phase transition, showing its electronic character, while its coupling to noncritical lattice modes is shown to enhance the transition temperature. On cooling, we observe the gradual emergence of coherent superpositions of band states at the correlated insulator gap edge, with strong departures from mean-field theory predictions. Our results demonstrate the realization of a strongly correlated excitonic state in an equilibrium bulk material.

The low energy phonon modes of the hydrogenated and deuterated π-conjugated system 7,7,8,8-tetracyanoquinodimethane: an inelastic neutron scattering study

TCNQ is a fascinating molecule with potential for optical, electronic and magnetic materials. Our work studies the low energy lattice modes of the parent compound to further understand the vibrational properties including their temperature dependence.

Hybridized surface lattice modes in intercalated 3-disk plasmonic crystals for high figure-of-merit plasmonic sensing

Hybridized surface lattice mode in an intercalated 3-disk plasmonic lattice for overcoming an inherent trade-off in plasmonic sensing.

Pickeringite from the Stone Town Nature Reserve in Ciężkowice (the Outer Carpathians, Poland)

Pickeringite, ideally MgAl2(SO4)4·22H2O, is a member of the halotrichite group minerals XAl2(SO4)4·22H2O that form extensive solid solutions along the joints of the X = Fe-Mg-Mn-Zn. The few comprehensive reports on natural halotrichites indicate their genesis to be mainly the low-pH oxidation of pyrite or other sulfides in the Al-rich environments of weathering rock-forming aluminosilicates. Pickeringite discussed here occurs within the efflorescences on sandstones from the Stone Town Nature Reserve in Ciężkowice (the Polish Outer Carpathians), being most probably the first find on such rocks in Poland. This paper presents mineralogical and geochemical characteristics of the pickeringite (based on SEM-EDS, XRPD, EPMA and RS methods) and suggests its possible origin. It belongs to the pickeringite–apjohnite (Mg-Mn joints) series and has the calculated formula Mg0.75Mn0.21Zn0.02Cu0.01Al2.02(S0.99 to 1.00O4)4·22H2O (based on 16O and 22H2O). The unit cell parameters refined for the monoclinic system space group P21/c are: a = 6.1981(28) Å, b= 24.2963(117) Å, c = 21.2517(184) Å and β = 100.304(65)°. The Raman spectra (SO4) bands are the intensive 994 cm−1 and a low-intensive 975 cm−1 (ν1), low-intensive 1081, 1123 and 1145 cm−1 (ν3), 524, 467 and 425cm−1 (ν2), 615 cm−1 (ν4), while those at 344 and 310 cm−1 are attributed to νg H2O and at 223 cm−1 to the lattice modes. Crystallization of pickeringite within the particular tor resulted from a certain set of conditions: climatic (e.g., season, temperature, humidity), physicochemical (e.g., pH, concentration), mineral (the presence of pyrite), and site-related (location and efflorescence protection). The sulfate ions could have been derived from oxidation of pyrite in the Ciężkowice sandstones and possibly are related to local mineral waters.

Riomarinait z Cínovce - první výskyt velmi vzácného sulfátu bismutu v České republice

A very rare bismuth sulphate, riomarinaite, was found in an old abandoned shaft on a Sn-W deposit Cínovec near Teplice, Northern Bohemia. This is first occurrence of this generally very rare mineral in the Czech Republic. Riomarinaite forms grey and blue acicular and columnar crystals up to 30 μm in size in association with native bismuth and bismuthinite. Riomarinaite is monoclinic, space group P21/n, the unit-cell parameters refined from X-ray powder diffraction data are: a 6.0091(19), b 13.328(5), c 6.483(3) Å, β 112.91(5)˚ and V 478.3(3) Å3. Chemical analyses of riomarinaite correspond to the empirical formula (Bi1.10Ca0.02)Σ1.12[(SO4)0.92(MoO4)0.08]Σ1.00(OH)1.33·H2O on the basis of S + Mo = 1 apfu. Raman bands connected with vibrations of (OH)-, H2O, (SO4)2- groups, Bi-O bonds and lattice modes were observed in the Raman spectrum of riomarinaite.