Evaluation of porous catalytic membranes operated in pore-flow-through mode for hydrogenation of α-methylstyrene

2010 ◽  
Vol 5 (1) ◽  
pp. 12-25 ◽  
Author(s):  
Daniel Urbanczyk ◽  
Roland Dittmeyer ◽  
Aurel Wolf ◽  
Rafael Warsitz ◽  
Gundula Fischer ◽  
...  
Author(s):  
Richard Holdich ◽  
Serguei Kosvintsev ◽  
Iain Cumming ◽  
Sergey Zhdanov

In filtration, the concept of pore size is not easy to define. In microfiltration, there are numerous advantages in employing a surface filtering membrane, rather than one relying on depth filtration mechanisms from a tortuous pore flow channel. Modern manufacturing techniques provide means to produce surface filtering membranes. For filtration, it is shown that a suitable pore design is an array of long thin slots. An analysis of fluid flow through the slots suggests that a short slot is adequate, but experimental data with suspended material indicates that slot length is important. Using long slots and careful control of the flow through the membrane it is possible to filter deforming particles such as oil drops from water.


Author(s):  
Laura L. Schepp ◽  
Joerg Renner

AbstractWe applied three oscillatory methods, the previously presented axial pore-pressure and pore-flow methods, and the laboratory application of the radial oscillatory pore-flow method, and performed steady-state flow-through experiments (Darcy tests), for comparison, in experiments on samples of Westerly granite and Wilkeson sandstone. The granite and the sandstone exhibit pore spaces dominated by micro-fractures and by the granular-medium character with a connected porosity of about 1 and 10 %, respectively. Permeability determined by the axial pore-pressure method shows the closest agreement with the results of the Darcy tests. Apparent porosity and drained modulus derived from specific storage capacity deviate from measured connected porosity and reference values, respectively. The observed deviations of the hydraulic properties between methods suggest that they bear information about the structure of the pore space. Only for the sandstone, anisotropy in hydraulic properties appears to contribute to differences between the results of the various methods. We argue that oscillatory testing provides three indicators for heterogeneity, period dependence, the relation between apparent and connected porosity, and the relation between amplitude ratio and apparent penetration depth, calculated from the simple scaling law for homogeneous materials. These indicators consistently classify the samples of Wilkeson sandstone as hydraulically homogeneous and those of Westerly granite as heterogeneous.


2021 ◽  
Vol 639 ◽  
pp. 119782
Author(s):  
Na Lu ◽  
Haibo Lin ◽  
Guiliang Li ◽  
Jianqiang Wang ◽  
Qiu Han ◽  
...  

2013 ◽  
Vol 104 ◽  
pp. 1090-1106 ◽  
Author(s):  
J.P. Lopes ◽  
M.A. Alves ◽  
M.S.N. Oliveira ◽  
S.S.S. Cardoso ◽  
A.E. Rodrigues

2013 ◽  
Vol 42 (5) ◽  
pp. 1378-1384 ◽  
Author(s):  
Alexander Sachse ◽  
Noemi Linares ◽  
Pierluigi Barbaro ◽  
François Fajula ◽  
Anne Galarneau

AIChE Journal ◽  
2007 ◽  
Vol 54 (1) ◽  
pp. 258-268 ◽  
Author(s):  
A. Schmidt ◽  
A. Wolf ◽  
R. Warsitz ◽  
R. Dittmeyer ◽  
D. Urbanczyk ◽  
...  

Author(s):  
Richard L. Leino ◽  
Jon G. Anderson ◽  
J. Howard McCormick

Groups of 12 fathead minnows were exposed for 129 days to Lake Superior water acidified (pH 5.0, 5.5, 6.0 or 6.5) with reagent grade H2SO4 by means of a multichannel toxicant system for flow-through bioassays. Untreated water (pH 7.5) had the following properties: hardness 45.3 ± 0.3 (95% confidence interval) mg/1 as CaCO3; alkalinity 42.6 ± 0.2 mg/1; Cl- 0.03 meq/1; Na+ 0.05 meq/1; K+ 0.01 meq/1; Ca2+ 0.68 meq/1; Mg2+ 0.26 meq/1; dissolved O2 5.8 ± 0.3 mg/1; free CO2 3.2 ± 0.4 mg/1; T= 24.3 ± 0.1°C. The 1st, 2nd and 3rd gills were subsequently processed for LM (methacrylate), TEM and SEM respectively.Three changes involving chloride cells were correlated with increasing acidity: 1) the appearance of apical pits (figs. 2,5 as compared to figs. 1, 3,4) in chloride cells (about 22% of the chloride cells had pits at pH 5.0); 2) increases in their numbers and 3) increases in the % of these cells in the epithelium of the secondary lamellae.


Author(s):  
Tian-Chyi Yeh ◽  
Raziuddin Khaleel ◽  
Kenneth C. Carroll
Keyword(s):  

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