Melt blending of linear low-density polyethylene and polystyrene in a Haake internal mixer. II. Morphology-processing relationships

1995 ◽  
Vol 58 (1) ◽  
pp. 129-141 ◽  
Author(s):  
Li-Ying Yang ◽  
David Bigio ◽  
Theodore G. Smith
2013 ◽  
Vol 795 ◽  
pp. 433-437 ◽  
Author(s):  
S.T. Sam ◽  
N.Z. Noriman ◽  
S. Ragunathan ◽  
O.H. Lin ◽  
H. Ismail

Soya spent powder as an inexpensive and renewable source has been used as a filler for linear-low density polyethylene (LLDPE) in this study. Linear-low density polyethylene (LLDPE)/soya spent powder composites were prepared by using Haake internal mixer. The mixing time was 10 minutes at 150°C with rotor speed 50 rpm. Epoxidised natural rubber (ENR 50) has been used as a compatibilizer in the present study. The thermal properties of the LLDPE/soya spent powder composites with and without ENR were studied with a differential scanning calorimetry (DSC). The crystallinity of the LLDPE/soya spent powder composites decreased with increasing soya spent powder content. However, the addition of ENR 50 as a compatibilizer increased the crystallinity of the LLDPE/soya spent powder composites.


2013 ◽  
Vol 795 ◽  
pp. 429-432
Author(s):  
S.T. Sam ◽  
N.Z. Noriman ◽  
S. Ragunathan ◽  
H. Ismail

Linear low-density polyethylene (LLDPE)/soya spent powder blends with different blends ratio were prepared by using internal mixer. Soya spent powder was varied from 5 to 40 wt. The thermal degradability was assessed by subjecting the dumbbell sample to oven aging. Thermal aging was carried out for 5 weeks. The degradability was measured by the periodic change in tensile properties of the blend samples. The tensile strength and elongation at break of the blends reduced as increasing the aging time. The effect of degradation was obvious in higher soya spent powder blends.


2003 ◽  
Vol 89 (14) ◽  
pp. 3757-3768 ◽  
Author(s):  
Kelly S. Anderson ◽  
Shawn H. Lim ◽  
Marc A. Hillmyer

2016 ◽  
Vol 1133 ◽  
pp. 156-160 ◽  
Author(s):  
Ai Ling Pang ◽  
Hanafi Ismail ◽  
Azhar Abu Bakar

Tensile properties and morphological studies of linear low density polyethylene (LLDPE)/poly (vinyl alcohol) (PVA)/kenaf (KNF) composites were investigated. The composites with different KNF loading (0, 10, 20, 30, 40 phr) were prepared using a Thermo Haake Polydrive internal mixer at 150°C and 50 rpm for 10 min. The results indicated that tensile strength and elongation at break were decreased with increasing KNF loading, whereas tensile modulus showed the opposite trend. Tensile fractured surfaces observed by scanning electron microscopy showed better interfacial adhesion between LLDPE/PVA and KNF at 10 phr KNF loading.


2016 ◽  
Vol 1817 ◽  
Author(s):  
L.Y. Jaramillo ◽  
J.C. Posada-Correa ◽  
E. Pabón-Gelves ◽  
E. Ramos-Ramírez ◽  
N.L. Gutiérrez-Ortega

ABSTRACTIn this work there was studied the effect of nano-Mg/Al hydrotalcite (NHT) as filler on maleic anhydride grafted linear low density polyethylene (LLDPE-g-MA). NHT was synthesized by the coprecipitation method with a ratio of Mg/Al=6 and nanocomposites were prepared using 1, 3 and 5 %wt of filler via melt-blending.Morphological and structural analysis of NHT were performed and for nanocomposites, tensile tests and thermal properties were measured. Results showed that filler was well dispersed in the LLDPE matrix, mechanical properties were enhanced in most of the cases and thermal stability improvements were achieved in the nanocomposites.


2014 ◽  
Vol 803 ◽  
pp. 348-352
Author(s):  
A. Ainatun Nadhirah ◽  
S.T. Sam ◽  
N.Z. Noriman ◽  
C.H. Voon ◽  
S.S. Samera

Polyethylene (PE) has found well-known use as a packaging material. The effect of rambutan peels flour (RPF) content on the tensile properties of linear low density polyethylene filled with rambutan peel flour was studied. RPF was melt blended with linear low–density polyethylene (LLDPE). LLDPE/RPF blends were prepared by using internal mixer (brabender) at 160 °C with the flour content ranged from 0 to 15 wt%. The tensile properties were tested by using a universal testing machine (UTM) according to ASTM D638. The tensile strength of LLDPE/RPF decreased gradually with the addition of rambutan peels flour content from 0% to 15%. The Young’s modulus of LLDPE/RPF increased with increasing the RPF size and content.


e-Polymers ◽  
2003 ◽  
Vol 3 (1) ◽  
Author(s):  
Frédéric Prochazka ◽  
Romulus Dima ◽  
Jean-Charles Majesté ◽  
Christian Carrot

Abstract Blends of polystyrene and high-density or linear low-density polyethylene have been prepared in an internal mixer and studied in a wide range of compositions. Phase inversion compositions have been determined using selective extraction and scanning electron microscopy. It appears that phase inversion can occur in a domain of compositions rather than at a single point. The existing models of phase inversion are not complete enough to explain the entire phenomenon, and percolation of each component may be considered to describe the formation of co-continuity.


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