Effect of microencapsulated curing agents on the curing behavior for diglycidyl ether of bisphenol A epoxy resin systems

2007 ◽  
Vol 107 (3) ◽  
pp. 1661-1669 ◽  
Author(s):  
Hongxia Xu ◽  
Zhengping Fang ◽  
Lifang Tong
Keyword(s):  
Bisphenol A ◽  
Epoxy Resin ◽  
Diglycidyl Ether ◽  
Curing Behavior ◽  
Curing Agents

scholarly journals Synthesis of Bisphenol A Based Phosphazene-Containing Epoxy Resin with Reduced Viscosity

Polymers ◽  
2019 ◽  
Vol 11 (12) ◽  
pp. 1914 ◽  
Author(s):  
Kireev ◽  
Bilichenko ◽  
Borisov ◽  
Mu ◽  
Kuznetsov ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Bisphenol A ◽  
Epoxy Resin ◽  
31P Nmr ◽  
Diglycidyl Ether ◽  
31P Nmr Spectroscopy ◽  
Reduced Viscosity ◽  
Lower Viscosity ◽  
Curing Agents ◽  
Flame Retardant Properties

Phosphazene-containing epoxy oligomers (PEO) were synthesized by the interaction of hexachlorocyclotriphosphazene (HCP), phenol, and bisphenol A in a medium of excess of epichlorohydrin using potassium carbonate and hydroxide as HCl acceptors with the aim of obtaining a product with lower viscosity and higher phosphazene content. PEOs are mixtures of epoxycyclophosphazene (ECP) and a conventional organic epoxy resin based on bisphenol A in an amount controlled by the ratio of the initial mono- and diphenol. According to 31P NMR spectroscopy, pentasubstituted aryloxycyclotrophosphazene compounds predominate in the ECP composition. The relative content in the ECP radicals of mono- and diphenol was determined by the MALDI-TOF mass spectrometry method. The organic epoxy fraction, according to gas chromatograpy-mass spectrometry (GC-MS), contains 50–70 wt % diglycidyl ether of bisphenol A. PEO resins obtained in the present work have reduced viscosity when compared to other known phosphazene-containging epoxy resins while phosphazene content is still about 50 wt %. Resins with an epoxy number within 12–17 wt %, are cured by conventional curing agents to form compositions with flame-retardant properties, while other characteristics of these compositions are at the level of conventional epoxy materials.

Cure kinetics, morphological and dynamic mechanical analysis of diglycidyl ether of bisphenol-A epoxy resin modified with hydroxyl terminated poly(ether ether ketone) containing pendent tertiary butyl groups

Polymer ◽  
2006 ◽  
Vol 47 (15) ◽  
pp. 5411-5419 ◽  
Author(s):  
Bejoy Francis ◽  
V. Lakshmana Rao ◽  
Geert Vanden Poel ◽  
Fabrice Posada ◽  
Gabriel Groeninckx ◽  
...  
Keyword(s):  
Bisphenol A ◽  
Epoxy Resin ◽  
Dynamic Mechanical Analysis ◽  
Cure Kinetics ◽  
Mechanical Analysis ◽  
Diglycidyl Ether ◽  
Tertiary Butyl ◽  
Ether Ether Ketone ◽  
Poly Ether Ether Ketone ◽  
Ether Ketone

Diglycidyl ether of bisphenol-A epoxy resin modified using poly(ether ether ketone) with pendenttert-butyl groups

2007 ◽  
Vol 45 (17) ◽  
pp. 2481-2496 ◽  
Author(s):  
Bejoy Francis ◽  
Sabu Thomas ◽  
R. Sadhana ◽  
Nicole Thuaud ◽  
R. Ramaswamy ◽  
...  
Keyword(s):  
Bisphenol A ◽  
Epoxy Resin ◽  
Diglycidyl Ether ◽  
Ether Ether Ketone ◽  
Poly Ether Ether Ketone ◽  
Ether Ketone

scholarly journals Preparation and Characterization of Green Epoxy Resin Composites and Its Use in Corrosion Resistance

2018 ◽  
Author(s):  
Abbas Hassan Faris
Keyword(s):  
Bisphenol A ◽  
Epoxy Resin ◽  
Electrolyte Solutions ◽  
Kraft Lignin ◽  
Diglycidyl Ether ◽  
Kraft Pulping ◽  
Palm Tree ◽  
Scanning Calorimetry ◽  
Ft Ir ◽  
Nano Titanium Dioxide

In this work, appropriate alternative for diglycidyl ether bisphenol A (DGEBA) was found to avoid the destructive effects of bisphenol A. Lignin, an aromatic compound from palm tree leaves, was used as a renewable material to synthesize a bio-based epoxy resin. Lignin extracted using Kraft pulping process. Kraft Lignin was epoxidized with epichlorohydrin in alkaline medium. Nano-titanium dioxide was used as filler with ratio of 10% to prepare the green epoxy composite. The structure of the Kraft lignin and lignin-based epoxy resin was proven via Infrared spectra (FT-IR) were recorded using solid KBr disk by testing Shimadzu (FT-IR-8300) spectrophotometer. The thermal properties of the curing process of lignin-based epoxy resin and composite were investigate using Differential scanning calorimetry (DSC) analysis. Potentiodynamic measurements data revealed that the anti-corrosion performance of the lignin based epoxy resin. The study demonstrates successful of epoxidation of Kraft lignin. In addition, lignin based eopxy resin showed effective inhibitor for carbon steel in 3.5 wt. % NaCl electrolyte solutions

scholarly journals Sustainable access to fully biobased epoxidized vegetable oil thermoset materials prepared by thermal or UV-cationic processes

RSC Advances ◽  
2020 ◽  
Vol 10 (68) ◽  
pp. 41954-41966 ◽  
Author(s):  
Samuel Malburet ◽  
Chiara Di Mauro ◽  
Camilla Noè ◽  
Alice Mija ◽  
Marco Sangermano ◽  
...  
Keyword(s):  
Bisphenol A ◽  
Epoxy Resin ◽  
Vegetable Oil ◽  
Epoxy Resins ◽  
Diglycidyl Ether

Beyond the need to find a non-toxic alternative to DiGlycidyl Ether of Bisphenol-A (DGEBA), the serious subject of non-epichlorohydrin epoxy resins production remains a crucial challenge that must be solved for the next epoxy resin generations.

Curing Behavior of Epoxy Resin Using Controllable Curing Agents Based on Nickel Complexes

2006 ◽  
Vol 291 (2) ◽  
pp. 181-193 ◽  
Author(s):  
Abdollah Omrani ◽  
Mousa Ghaemy ◽  
Abbas A. Rostami
Keyword(s):  
Epoxy Resin ◽  
Nickel Complexes ◽  
Curing Behavior ◽  
Curing Agents

Poly(diglycidyl ether of Bisphenol A) epoxy resin

2013 ◽  
pp. 827-833
Author(s):  
G. Steiner ◽  
C. Zimmerer
Keyword(s):  
Bisphenol A ◽  
Epoxy Resin ◽  
Diglycidyl Ether

scholarly journals Synthesis and Characterization of Nanostructured Blends of Epoxy Resin and Block Copolymers

2013 ◽  
Vol 13 (1) ◽  
pp. 81-88 ◽  
Author(s):  
Rajesh Pandit ◽  
Albrecht Berkessel ◽  
Ralf Lach ◽  
Wolfgang Grellmann ◽  
Rameshwar Adhikari
Keyword(s):  
Fourier Transform ◽  
Block Copolymer ◽  
Block Copolymers ◽  
Bisphenol A ◽  
Epoxy Resin ◽  
Layered Silicate ◽  
Diglycidyl Ether ◽  
Synthesis And Characterization ◽  
Microindentation Technique

Polystyrene–polybutadiene block copolymers having different molecular architectures were epoxidized by using meta-chloroperoxybenzoic acid (MCPBA). Then, the blends with epoxy resin (diglycidyl ether of bisphenol-A; DGEBA) and their nanocomposites with boehmite and layered silicate nanofiller in presence of methylene dianiline (MDA) as a hardener were prepared. The epoxidized copolymers and the composites were characterized by Fourier transform infrared (FTIR) spectroscopy and microindentation technique. In this way, it was possible to tune the morphology of the nanostructured blends of the epoxy resin using the functionalized block copolymer as the template. The presence of nanostructured morphology was attested by the optical transparency of the blends as well as of the composites with nanofiller. The microhardness properties were improved by the incorporation of the nanoparticles, viz. boehmite and layered silicate. Nepal Journal of Science and Technology Vol. 13, No. 1 (2012) 81-88 DOI: http://dx.doi.org/10.3126/njst.v13i1.7445

Thermal and Dielectric Properties of Inorganic-Organic Nanocomposites Involving Epoxy Resin and Polyhedral Oligomeric Silsesquioxanes

2012 ◽  
Vol 476-478 ◽  
pp. 665-669 ◽  
Author(s):  
Li Yang ◽  
Miao Yin ◽  
Xiu Yun Li ◽  
Han Bing Ma
Keyword(s):  
Thermal Stability ◽  
Dielectric Constant ◽  
Dielectric Properties ◽  
Bisphenol A ◽  
Epoxy Resin ◽  
Functional Groups ◽  
Epoxy Matrix ◽  
Epoxy Resins ◽  
Diglycidyl Ether ◽  
Polyhedral Oligomeric Silsesquioxanes

In this paper, a type of nanoporous polyhedral oligomeric silisesquioxanes (POSS) containing eight functional groups have been synthesized and mixed with diglycidyl ether of bisphenol A (DGEBA) to form epoxy resin networks with nanostructures. The cured octa(aminophenyl) silsesquioxane (1c-POSS) and DGEBA system inherently possesses higher thermal stability and higher char yield than the control epoxy resins. Furthermore, the dielectric constant of the 1c-POSS/DGEBA material (4.36) is substantially lower than that of the neat epoxy resins (4.64) as a consequence the presence of nanoporous POSS cubes in the epoxy matrix.

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