Controlled preparation and properties of acrylic acid epoxy‐acrylate composite emulsion for self‐crosslinking coatings

After the 4-bromo-3,5-difluorophenyl acrylamide (BDPA) and acrylic acid were introduced into the epoxy acrylate (EA), the photosensitive epoxy acrylate (EFBDPA) with good performance was prepared through chemical graft modification. The structure of EFBDPA was confirmed by FTIR and1H-NMR. When the content of BDPA in EFBDPA was 20%, the cured coating of EFBDPA had better performance than the unmodified EA cured coating, its tensile strength, 80 % decomposition temperatures and the residual carbon ratio were improved 86%, 5.7 °C and 4.2 %, respectively.

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Physico-chemical characterisation of epoxy acrylate resin from jatropha seed oil

Pigment & Resin Technology ◽

10.1108/prt-11-2016-0116 ◽

2017 ◽

Vol 46 (6) ◽

pp. 485-495 ◽

Cited By ~ 5

Author(s):

Emiliana Rose Jusoh Taib ◽

Luqman Chuah Abdullah ◽

Min Min Aung ◽

Mahiran Basri ◽

Mek Zah Salleh ◽

...

Keyword(s):

Acrylic Acid ◽

Seed Oil ◽

Acid Value ◽

Chemical Characteristics ◽

Nuclear Magnetic Resonance Analysis ◽

Epoxy Acrylate ◽

Uv Curable ◽

Content Type ◽

Physico Chemical ◽

Jatropha Seed

Purpose This paper aims to demonstrate the synthesis of polyesterification reaction of non-edible jatropha seed oil (JO) and acrylic acid, which leads to the production of acrylated epoxidised-based resin. To understand the physico-chemical characteristics when synthesis the JO-based epoxy acrylate, the effect of temperature on the reaction, concentration of acrylic acid and role of catalyst on reaction time and acid value were studied. Design/methodology/approach First, the double bond in JO was functionalised by epoxidation using the solvent-free performic method. The subsequent process was acrylation with acrylic acid using the base catalyst triethylamine and 4-methoxyphenol as an inhibitor respectively. The physico-chemical characteristics during the synthesis of the epoxy acrylate such as acid value was monitored and analysed. The formation of the epoxy and acrylate group was confirmed by a Fourier transform infrared spectroscopy spectra analysis and nuclear magnetic resonance analysis. Findings The optimum reaction condition was achieved at a ratio of epoxidised JO to acrylic acid of 1:1.5 and the reaction temperature of 110°C. This was indicated by the acid value reduction from 86 to 15 mg KOH/g sample at 6 hours. Practical implications The JO-based epoxy acrylate synthesised has a potential to be used in formulations the prepolymer resin for UV curable coating applications. The JO which is from natural resources and is sustainable raw materials that possible reduce the dependency on petroleum-based coating. Originality/value The epoxidised jatropha seed oil epoxy acrylate was synthesised, as a new type of oligomer resin that contains a reactive acrylate group, which can be alternative to petroleum-based coating and can used further in the formulation of the radiation curable coating.

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Synthesis of Mo/V mixed oxide catalysts via crystallisation and spray drying?a novel approach for controlled preparation of acrolein to acrylic acid catalysts

Applied Catalysis A General ◽

10.1016/s0926-860x(04)00263-7 ◽

2004 ◽

Author(s):

J KUNERT

Keyword(s):

Acrylic Acid ◽

Spray Drying ◽

Mixed Oxide ◽

Oxide Catalysts ◽

Acid Catalysts ◽

Mixed Oxide Catalysts ◽

Novel Approach ◽

Controlled Preparation

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Soft ionic liquid based resistive memory characteristics in a two terminal discrete polydimethylsiloxane cylindrical microchannel

Journal of Materials Chemistry C ◽

10.1039/d0tc03334k ◽

2020 ◽

Vol 8 (38) ◽

pp. 13368-13374

Author(s):

Muhammad Umair Khan ◽

Gul Hassan ◽

Jinho Bae

Keyword(s):

Ionic Liquid ◽

Acrylic Acid ◽

Sodium Hydroxide ◽

Sodium Salt ◽

Resistive Memory ◽

Cylindrical Microchannel ◽

Memory Characteristics ◽

Poly Acrylic Acid

This paper proposes a novel soft ionic liquid (IL) electrically functional device that displays resistive memory characteristics using poly(acrylic acid) partial sodium salt (PAA-Na+:H2O) solution gel and sodium hydroxide (NaOH) in a thin polydimethylsiloxane (PDMS) cylindrical microchannel.

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The Role of the Initiator System in the Synthesis of Acidic Multifunctional Nanoparticles Designed for Molecular Imprinting of Proteins

Periodica Polytechnica Chemical Engineering ◽

10.3311/ppch.15414 ◽

2020 ◽

Vol 65 (1) ◽

pp. 28-41

Author(s):

Marwa Aly Ahmed ◽

Júlia Erdőssy ◽

Viola Horváth

Keyword(s):

Acrylic Acid ◽

Binding Affinity ◽

Molecular Imprinting ◽

Low Temperatures ◽

Ammonium Persulfate ◽

Sodium Bisulfite ◽

Multifunctional Nanoparticles ◽

High Affinity ◽

Initiator System

Multifunctional nanoparticles have been shown earlier to bind certain proteins with high affinity and the binding affinity could be enhanced by molecular imprinting of the target protein. In this work different initiator systems were used and compared during the synthesis of poly (N-isopropylacrylamide-co-acrylic acid-co-N-tert-butylacrylamide) nanoparticles with respect to their future applicability in molecular imprinting of lysozyme. The decomposition of ammonium persulfate initiator was initiated either thermally at 60 °C or by using redox activators, namely tetramethylethylenediamine or sodium bisulfite at low temperatures. Morphology differences in the resulting nanoparticles have been revealed using scanning electron microscopy and dynamic light scattering. During polymerization the conversion of each monomer was followed in time. Striking differences were demonstrated in the incorporation rate of acrylic acid between the tetramethylethylenediamine catalyzed initiation and the other systems. This led to a completely different nanoparticle microstructure the consequence of which was the distinctly lower lysozyme binding affinity. On the contrary, the use of sodium bisulfite activation resulted in similar nanoparticle structural homogeneity and protein binding affinity as the thermal initiation.

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