Preparation and Performance of Photosensitive Epoxy Acrylate Modified by N-[(4-Bromo-3,5-Difluoro) Phenyl]acrylamide

2013 ◽  
Vol 357-360 ◽  
pp. 1224-1228
Author(s):  
Xin Ding Yao ◽  
Rui Na Fang ◽  
Hong Jian Pang ◽  
Peng Cui ◽  
Guo Ji Liu
Keyword(s):  
Tensile Strength ◽  
Acrylic Acid ◽  
Residual Carbon ◽  
Epoxy Acrylate ◽  
H Nmr ◽  
Graft Modification ◽  
Cured Coating ◽  
And Performance

After the 4-bromo-3,5-difluorophenyl acrylamide (BDPA) and acrylic acid were introduced into the epoxy acrylate (EA), the photosensitive epoxy acrylate (EFBDPA) with good performance was prepared through chemical graft modification. The structure of EFBDPA was confirmed by FTIR and1H-NMR. When the content of BDPA in EFBDPA was 20%, the cured coating of EFBDPA had better performance than the unmodified EA cured coating, its tensile strength, 80 % decomposition temperatures and the residual carbon ratio were improved 86%, 5.7 °C and 4.2 %, respectively.

Synthesis, Characterization and Performance of Superplasticizer with a Multi-Arm Structure

2015 ◽  
Vol 815 ◽  
pp. 594-600 ◽  
Author(s):  
Xiao Liu ◽  
Zi Ming Wang ◽  
Jie Zhu ◽  
Ming Zhao ◽  
Yun Sheng Zheng
Keyword(s):  
Acrylic Acid ◽  
The Self ◽  
Molar Ratio ◽  
Esterification Reaction ◽  
Reaction Products ◽  
Reaction Conditions ◽  
H Nmr ◽  
Polyhydric Alcohols ◽  
Esterification Rate ◽  
And Performance

A novel superplasticizer with a multi-arm structure, i.e., a “core” connected with multiple copolymer “arms”, was synthesized through two steps including an esterification reaction between polyhydric alcohols and acrylic acid and a copolymerization reaction in an aqueous solution among the esterification product, isobutenyl polyethylene glycol and acrylic acid. The reaction conditions were determined, and the results showed that the esterification rate can reach above 95% with a water-carrying agent of 70g, a catalyst/alcohol molar ratio of 0.07, an inhibitor/monomer molar ratio of 0.03, and a reaction time of 7 hrs. The reaction products were characterized by 1H Nuclear Magnetic Resonance (1H NMR) and Fourier Transform infrared spectroscopy (FTIR). It is confirmed to be the multi-arm structure, and the self-synthesized superplasticizer with a multi-arm structure exhibited higher energy efficiency, which was in accordance with its excellent paste fluidity performances and adsorption behavior in cement paste

scholarly journals The potential use of lightweight cellular concrete in pavement application: a review

2020 ◽  
Vol 13 (6) ◽  
pp. 686-696
Author(s):  
Frank Mi-Way Ni ◽  
Abimbola Grace Oyeyi ◽  
Susan Tighe
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Ease Of Use ◽  
Potential Candidate ◽  
Actual Performance ◽  
Freeze Thaw ◽  
Lower Weight ◽  
And Performance ◽  
Potential Use ◽  
Cellular Concrete

AbstractProtecting the pavement subgrade to increase the service life of road pavements is an aspect currently being explored. Several alternative pavement subbase materials are being considered, including Lightweight Cellular Concrete (LCC). Due to its lower weight, LCC incorporating industrial by-product, making it sustainable, and ease of use amongst other benefits, is seen as a potential candidate. This paper reports reviewing the potential application of LCC within the pavement structure with a specific application as a subbase. It examines the various properties such as modulus of elasticity, compressive and tensile strength, Water absorption, and freeze-thaw resistance necessary for pavement application. It also assesses its use in the field in Canada considering the design methods utilized. Some limitations and gaps for LCC application in pavements are also established and recommendations on how to further its use and performance. This review concludes that LCC possesses potential as a pavement subbase alternative; however, other mechanical properties like LCC’s fatigue life is essential. A comparative field study is also recommended to monitor actual performance and various factors on performance.

scholarly journals Kinetics of radical telomerization of acrylic acid in the presence of 1-octadecanethiol

2018 ◽  
Vol 90 (11) ◽  
pp. 1743-1754 ◽  
Author(s):  
Yaroslav O. Mezhuev ◽  
Oksana Y. Sizova ◽  
Yuri V. Korshak ◽  
Anna L. Luss ◽  
Ivan V. Plyushchii ◽  
...  
Keyword(s):  
Critical Micelle Concentration ◽  
Acrylic Acid ◽  
Monomer Concentration ◽  
Atom Economy ◽  
Exponential Factor ◽  
H Nmr ◽  
Radical Telomerization ◽  
Kinetics Of ◽  
End Group ◽  
C Nmr

AbstractThe oligomer of acrylic acid with a thiooctadecyl end-group was obtained by using octadecyl mercaptan as the chain-transfer agent. The resulting oligomer was characterized by 1H NMR and 13C NMR spectroscopy and critical micelle concentration was determined in aqueous solution. The order with respect to the initiator concentration was 0.5 and 1.6 with respect to the monomer concentration. The abnormal reaction order with respect to the monomer concentration was explained by participation in the chain propagation of unassociated and associated forms of acrylic acid, which were stabilized by formation of hydrogen bonds. The kinetic parameters of telomerization were determined. Telomerization with acrylic acid in the non-associated form had lower activation energy and lower pre-exponential factor than in the case of associated forms. The synthesis of the acrylic acid oligomer with a thiooctadecyl end-group having a low critical micelle concentration in water was carried out in one stage and corresponds to the concept of atom economy.

Toughened Chitosan Composite Nanofiltration Membrane by Introduction of Acrylic Acid

2019 ◽  
Vol 815 ◽  
pp. 139-144
Author(s):  
Tao Mu
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Tensile Strength ◽  
Acrylic Acid ◽  
Nanofiltration Membrane ◽  
Modified Chitosan ◽  
Atomic Force ◽  
Infrared Spectrophotometer ◽  
Chitosan Composite ◽  
Scanning Electron

In this paper, acrylic acid was grafted to chitosan in order to change the structure; polymer was obtained from modified chitosan. A series of novel toughened composite NF memebranes were prepared by over-coating the polysulfone ultrafiltration membrane with the polymer of modified chitosan. The chitosan derivatives and the polymer were characterised by infrared spectrophotometer (IR); the structure of the membrane was characrerised by scanning electron microscopy (SEM) and atomic force microscope (AFM). The composite NF membrane’s performances were strictly related to the structure of polymer. The rejection of the membrane was 96.3% with flux as high as 386.46 L m-2 h-1 with the 1000 mg/L of NaCl. Tensile strength of membrane increased 46%. The HCl (5%) resistance increased from 20.3 to 36.8h. The NaOH (5%) resistance increased from 18.3 to 31.6h. These results indicated the prepared toughened composite NF memebrane was excellent NF membrane, which had a wide application prospect.

URSS/PVA/WP Composite Materials: Preparation and Performance

2014 ◽  
Vol 968 ◽  
pp. 80-83
Author(s):  
Chuan Bao Wu ◽  
Bo Qiao
Keyword(s):  
Tensile Strength ◽  
Composite Materials ◽  
Rice Straw ◽  
Hot Pressing ◽  
Vinyl Alcohol ◽  
Tensile Elongation ◽  
Environmentally Friendly ◽  
Waste Paper ◽  
Poly Vinyl Alcohol ◽  
And Performance

A novel kind of environmentally friendly composite materials containing upper part of rice straw segments (URSS), poly (vinyl alcohol) (PVA) and waste paper (WP) were prepared by hot-pressing at 140°C for 10 min. The tensile strength, tensile elongation and hardness of composites were measured. Results showed that the tensile strength and the strength at tensile break of the composites first increased and then decreased with increasing PVA content. Tensile strength was higher than the strength at tensile break at different PVA contents, indicating that URSS/PVA/WP composite materials had certain toughness. Otherwise, URSS/PVA/WP composite materials had higher tensile strength than URSS/PVA composites. The tensile strengths of them were respectively 9.25 MPa and 3.9 MPa when prepared at PVA content of 40%. The hardness of composites lay between 90 and 96. Negligible difference exists in every composite.

Affection of Manufacture Parameters and Mixture Material on Plastic Alloy Bearings

2012 ◽  
Vol 164 ◽  
pp. 37-41
Author(s):  
Cheng Yun Yang ◽  
Jin Min Peng
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Process Parameters ◽  
Peel Strength ◽  
Manufacture Process ◽  
Orthogonal Experiments ◽  
And Performance ◽  
Orthogonal Tests ◽  
Tearing Strength ◽  
Optimal Formula

Manufacture process parameters will be obtained from experiments in research. Molding technology determines the mechanical properties and performance of the product. The influence of molding temperature and time are significant on the performance of water lubricated bearing, the plastic alloy is based on latex material, synthesized with different fillings, accelerators and other matters, and displays great mechanical and friction properties. The main performance included peel strength, tensile strength and wearing capacity. Optimization of manufacture process parameters and the orthogonal experiments on them were carried out by integrating the results of experiments and finally the optimal manufacture process was achieved. In the experiment, three-leveled orthogonal tests were conducted for the three systems to test the tensile strength, tearing strength, stress at definite elongation, hardness and tensile rate. The impacts of the respective systems were analyzed and the content of each component are determined to get the optimal formula.

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