In‐Depth Analysis of the Internal Energy Conversion of Nuclear Batteries and Radiation Degradation of Key Materials

A polymer electrolyte fuel cell (PEFC) is an electrochemical device that converts chemical energy into electrical energy and heat. The energy conversion is simple; however, the multiphysics phenomena involved in the energy conversion process must be analyzed in detail. The gas diffusion layer (GDL) provides a diffusion media for reactant gases and gives mechanical support to the fuel cell. It is a complex medium whose properties impact the fuel cell’s efficiency. Therefore, an in-depth analysis is required to improve its mechanical and physical properties. In the current study, several transport phenomena through three-dimensional digitally created GDLs have been analyzed. Once the porous microstructure is generated and the transport phenomena are mimicked, transport parameters related to the fluid flow and mass diffusion are computed. The GDLs are approximated to the carbon paper represented as a grouped package of carbon fibers. Several correlations, based on the fiber diameter, to predict their transport properties are proposed. The digitally created GDLs and the transport phenomena have been modeled using the open-source library named Open Pore Network Modeling (OpenPNM). The proposed correlations show a good fit with the obtained data with an R-square of approximately 0.98.

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Long-Term Analysis of Atmospheric Energetics Components over the Mediterranean, Middle East and North Africa

Atmosphere ◽

10.3390/atmos11090976 ◽

2020 ◽

Vol 11 (9) ◽

pp. 976

Author(s):

Silas Michaelides

Keyword(s):

Middle East ◽

Kinetic Energy ◽

Energy Conversion ◽

Internal Energy ◽

North Africa ◽

Climatic Data ◽

Monthly Means ◽

Seasonal Behavior ◽

Long Term Changes

In this research, one aspect of the climate that is not commonly referred to, namely, the long-term changes in the components of the atmospheric energy, is investigated. In this respect, the changes in four energy forms are considered, namely, Kinetic Energy (KE), Thermal Energy (TE), Internal Energy (IE), Potential Energy (PE) and Latent Energy (LE); the Energy Conversion (EC) between Kinetic Energy and Potential plus Internal Energy (PIE) is also considered. The area considered in this long-term energetics analysis covers the entire Mediterranean basin, the Middle East and a large part of North Africa. This broad geographical area has been identified by many researchers as a hot spot of climate change. Analyses of climatic data have indeed shown that this region has been experiencing marked changes regarding several climatic variables. The present energetics analysis makes use of the ERA-Interim database for the period from 1979 to 2018. In this 40-year period, the long-term changes in the above energetics components are studied. The monthly means of daily means for all the above energy forms and Energy Conversion comprise the basis for the present research. The results are presented in the form of monthly means, annual means and spatial distributions of the energetics components. They show the dominant role of the subtropical jet-stream in the KE regime. During the study period, the tendency is for KE to decrease with time, with this decrease found to be more coherent in the last decade. The tendency for TE is to increase with time, with this increase being more pronounced in the most recent years, with the maximum in the annual mean in KE noted in 2015. The sum of Potential and Internal energies (PIE) and the sum of Potential, Internal and Latent energies (PILE) follow closely the patterns established for TE. In particular, the strong seasonal influence on the monthly means is evident with minima of PIE and PILE noted in winters, whereas, maxima are registered during summers. In addition, both PIE and PILE exhibit a tendency to increase with time in the 40-year period, with this increase being more firmly noted in the more recent years. Although local conversion from KE into PIE is notable, the area averaging of EC shows that the overall conversion is in the direction of increasing the PIE content of the area at the expense of the KE content. EC behaves rather erratically during the study period, with values ranging from 0.5 to 3.7 × 102 W m−2. Averaged over the study area, the Energy Conversion term operates in the direction of converting KE into PIE; it also lacks a seasonal behavior.

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Understanding mixing efficiency in the oceans: do the nonlinearities of the equation of state for seawater matter?

Ocean Science ◽

10.5194/os-5-271-2009 ◽

2009 ◽

Vol 5 (3) ◽

pp. 271-283 ◽

Cited By ~ 12

Author(s):

R. Tailleux

Keyword(s):

Equation Of State ◽

Potential Energy ◽

Energy Conversion ◽

Internal Energy ◽

Molecular Diffusion ◽

Rate Of Change ◽

Gravitational Potential Energy ◽

Mixing Efficiency ◽

Buoyancy Frequency ◽

Boussinesq Fluid

Abstract. There exist two central measures of turbulent mixing in turbulent stratified fluids that are both caused by molecular diffusion: 1) the dissipation rate D(APE) of available potential energy APE; 2) the turbulent rate of change Wr, turbulent of background gravitational potential energy GPEr. So far, these two quantities have often been regarded as the same energy conversion, namely the irreversible conversion of APE into GPEr, owing to the well known exact equality D(APE)=Wr, turbulent for a Boussinesq fluid with a linear equation of state. Recently, however, Tailleux (2009) pointed out that the above equality no longer holds for a thermally-stratified compressible, with the ratio ξ=Wr, turbulent/D(APE) being generally lower than unity and sometimes even negative for water or seawater, and argued that D(APE) and Wr, turbulent actually represent two distinct types of energy conversion, respectively the dissipation of APE into one particular subcomponent of internal energy called the "dead" internal energy IE0, and the conversion between GPEr and a different subcomponent of internal energy called "exergy" IEexergy. In this paper, the behaviour of the ratio ξ is examined for different stratifications having all the same buoyancy frequency N vertical profile, but different vertical profiles of the parameter Υ=α P/(ρCp), where α is the thermal expansion coefficient, P the hydrostatic pressure, ρ the density, and Cp the specific heat capacity at constant pressure, the equation of state being that for seawater for different particular constant values of salinity. It is found that ξ and Wr, turbulent depend critically on the sign and magnitude of dΥ/dz, in contrast with D(APE), which appears largely unaffected by the latter. These results have important consequences for how the mixing efficiency should be defined and measured in practice, which are discussed.

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Investigation of the vapor-liquid ejector using eco-friendly working fluid with attentions on pressure lift and internal energy conversion

International Journal of Refrigeration ◽

10.1016/j.ijrefrig.2021.12.023 ◽

2021 ◽

Author(s):

Yisheng Huang ◽

Jianyong Chen ◽

Ying Chen ◽

Xianglong Luo ◽

Yingzong Liang ◽

...

Keyword(s):

Energy Conversion ◽

Internal Energy ◽

Working Fluid ◽

Vapor Liquid

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Laser-generated high entropy metallic glass nanoparticles as bifunctional electrocatalysts

Nano Research ◽

10.1007/s12274-021-3804-2 ◽

2021 ◽

Author(s):

Jacob Johny ◽

Yao Li ◽

Marius Kamp ◽

Oleg Prymak ◽

Shun-Xing Liang ◽

...

Keyword(s):

Metallic Glass ◽

Energy Conversion ◽

Photoelectron Spectroscopy ◽

Surface Segregation ◽

Amorphous Structure ◽

High Entropy Alloy ◽

Elemental Distribution ◽

X Ray ◽

High Entropy ◽

Depth Analysis

AbstractHigh entropy metallic glass nanoparticles (HEMG NPs) are very promising materials for energy conversion due to the wide tuning possibilities of electrochemical potentials offered by their multimetallic character combined with an amorphous structure. Up until now, the generation of these HEMG NPs involved tedious synthesis procedures where the generated particles were only available on highly specialized supports, which limited their widespread use. Hence, more flexible synthetic approaches to obtain colloidal HEMG NPs for applications in energy conversion and storage are highly desirable. We utilized pulsed laser ablation of bulk high entropy alloy targets in acetonitrile to generate colloidal carbon-coated CrCoFeNiMn and CrCoFeNiMnMo HEMG NPs. An in-depth analysis of the structure and elemental distribution of the obtained nanoparticles down to single-particle levels using advanced transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) methods revealed amorphous quinary and senary alloy phases with slight manganese oxide/hydroxide surface segregation, which were stabilized within graphitic shells. Studies on the catalytic activity of the corresponding carbon-HEMG NPs during oxygen evolution and oxygen reduction reactions revealed an elevated activity upon the incorporation of moderate amounts of Mo into the amorphous alloy, probably due to the defect generation by atomic size mismatch. Furthermore, we demonstrate the superiority of these carbon-HEMG NPs over their crystalline analogies and highlight the suitability of these amorphous multi-elemental NPs in electrocatalytic energy conversion.

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