Authigenic Minerals in Sedimentary Rocks

Author(s):  
G. I. Teodorovich
1962 ◽  
Vol 99 (1) ◽  
pp. 63-68 ◽  
Author(s):  
Philip F. Hutchins

AbstractPostdepositional low-temperature mineralogical changes in Carboniferous sedimentary rocks from Vestspitsbergen are described. These include the crystallization of apatite, quartz, and feldspar, and the replacement of feldspar and quartz by calcite and dolomite. Minerals of the chalcedonite–lutecime–quartzine group also occur.


2021 ◽  
Vol 40 (6) ◽  
pp. 100-110
Author(s):  
A.V. Mozherovsky ◽  

Authigenic minerals in volcanogenic-sedimentary and sedimentary rocks of Southern Primorye from Permian to Miocene time have been studied. Corrensite, rectorite, highly ordered mixed-layer differences of the chlorite-smectite (corrensite-like) and mica-smectite (rectorite-like) types, mica, vermiculite-like differences (?), chlorite, defective chlorite, kaolinite, smectite, calcite, and zeolites were found. Such a set of minerals indicates that the sedimentary layer in the studied sedimentary basins could be three to five kilometer thick, and the temperature of their formation is more than 150°C. The formation of the Lower Cretaceous and Paleocene sedimentary strata has similar features, and probably proceeded first in a shallow sea basin setting of the continental margin (rift stage), sometimes under conditions close to evaporitic (presence of corrensite?), with a frequent change of the facial situation from shallow to deep sedimentation, episodic supplies of volcanic material, and gradual deepening of sedimentation basins. It can be assumed that in Early Cretaceous and Paleogene times, a series of discrete sedimentation basins along the northeastern Asia continental margin developed in a single mineralogical, tectonic, and sedimentological regime of crustal extension: minerals accumulated in the sediments, which in the process of epigenesis transformed in the following directions: a) smectite-rectorite-mica; and b) smectite (palygorskite, sepiolite?) - corrensite-chlorite. In the studied sedimentary complexes three mineralogical «layers» are distinguished: 1) chlorite-mica – mica-chlorite (Permian - Cretaceous); 2) transitional from chlorite and mica to smectite - developed are corrensite, rectorite and highly ordered mixed-layer corrensite-like and rectorite-like minerals (Cretaceous - Paleocene-Eocene), and 3) smectite (from Oligocene to the present).


2016 ◽  
Vol 22 (1-2) ◽  
Author(s):  
Aleš Novotný ◽  
Renata Čopjaková

Titanite is a common accessory mineral of magmatic rocks, low- and medium-grade metamorphic rocks and it occurs as a detrital mineral in clastic sediments. Our paper deals with titanite alterations as a result of interaction of diagenetic fluids with detrital titanite during deep burial of sedimentary rocks of Drahany Upland, Protivanov Formation. Detrital titanites and their alteration products were examined by electron microprobe. Titanite dissolution was observed from the rim and along the cracks, accompanied by the formation of an authigenic calcite, TiO2 phase, synchysite-(Ce), and rarely chlorite. With an increasing degree of alteration, detrital titanite occurs as small irregular relics inside a mixture of authigenic minerals. Based on the composition of authigenic minerals, we can suppose diagenetic fluid rich in CO2, F and Ca responsible for alteration of detrital titanite. The maximum temperatures in this area during deep burial of sedimentary rocks reached 250–300 °C, corresponding to the conditions of very low-grademetamorphism. Contents of REE (0.67–3.55 wt. % REE2O3) in detrital titanite are rather high and vary significantly. Authigenic synchysite-(Ce) compared with detrital titanite strongly prefers LREE over HREE, indicating that LREE released during dissolution of detrital titanite were preferentially incorporated into the structure of synchysite-(Ce), whereas HREE were mobilized and removed away by diagenetic fluids.


2016 ◽  
pp. 19-25 ◽  
Author(s):  
D. A. Novikov

For the first time a detailed analysis of the equilibrium-non-equilibrium state of ground waters of hydrocarbon occurrences in Arctic areas of the West Siberian megabasin based on physico-chemical modeling of equilibria in the «water-rock» revealed hydrogeochemical and thermodynamic conditions for the formation of authigenic minerals. For the first time equilibrated compositions of groundwaters and parameters of geochemical environment were identified, being a prerequisite for the mineral neoformations.


Author(s):  
Thomas R. McKee ◽  
Peter R. Buseck

Sediments commonly contain organic material which appears as refractory carbonaceous material in metamorphosed sedimentary rocks. Grew and others have shown that relative carbon content, crystallite size, X-ray crystallinity and development of well-ordered graphite crystal structure of the carbonaceous material increases with increasing metamorphic grade. The graphitization process is irreversible and appears to be continous from the amorphous to the completely graphitized stage. The most dramatic chemical and crystallographic changes take place within the chlorite metamorphic zone.The detailed X-ray investigation of crystallite size and crystalline ordering is complex and can best be investigated by other means such as high resolution transmission electron microscopy (HRTEM). The natural graphitization series is similar to that for heat-treated commercial carbon blacks, which have been successfully studied by HRTEM (Ban and others).


1989 ◽  
Vol 4 ◽  
pp. 244-248 ◽  
Author(s):  
Donald L. Wolberg

The minerals pyrite and marcasite (broadly termed pyritic minerals) are iron sulfides that are common if not ubiquitous in sedimentary rocks, especially in association with organic materials (Berner, 1970). In most marine sedimentary associations, pyrite and marcasite are associated with organic sediments rich in dissolved sulfate and iron minerals. Because of the rapid consumption of sulfate in freshwater environments, however, pyrite formation is more restricted in nonmarine sediments (Berner, 1983). The origin of the sulfur in nonmarine environments must lie within pre-existing rocks or volcanic detritus; a relatively small, but significant contribution may derive from plant and animal decomposition products.


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