Al-Si Alloys, Minor, Major, and Impurity Elements

Al-Si Alloys ◽  
2017 ◽  
pp. 1-15
Author(s):  
Francisco C. Robles Hernandez ◽  
Jose Martin Herrera Ramírez ◽  
Robert Mackay
Keyword(s):  
Author(s):  
D. A. Petrochenkov

Fossils of marine reptiles are a new jewelry and ornamental material and collected in the Ulyanovsk region from the Upper Jurassic deposits. They consist of (wt. %): calcite — 52, apatite — 24 and pyrite — 23, and also gypsum presents. The contents of radioactive and carcinogenic elements are close to background. The original bone structure of reptiles is preserved. Apatite replaces the bone tissue of marine reptiles, forming a cellular framework. According to the chemical composition, apatite refers to fluorohydroxyapatite with an increased Sr content. The size of the crystals is finely-dispersed. Calcite and pyrite fill the central parts of the cells. Calcite crystals of isometric and elongated shape, 0,01—0,05 mm in size, form blocks up to 0,3 mm during intergrowth. Calcite fills thin, discontinuous veins along the contour of cells with a width of up to 0,03 mm. In calcite, among the impurity elements, there are (wt. %, on the average): Mg — 0,30, Mn — 0,39 and Fe — 0,96. Pyrite forms a dispersed impregnation in calcite and apatite, content of impurities is, wt. %: Ni — up to 0,96 and Cu — up to 0,24. On technological and decorative characteristics of fossils of sea reptiles of Ulyanovsk region are qualitative jewelry and ornamental materials of biomineral group, allowing to make a wide assortment of jewelry and souvenir products.


2021 ◽  
Vol 127 (8) ◽  
Author(s):  
R. Radhakrishnan Sumathi

AbstractAluminium nitride (AlN) is a futuristic material for efficient next-generation high-power electronic and optoelectronic applications. Sublimation growth of AlN single crystals with hetero-epitaxial approach using silicon carbide substrates is one of the two prominent approaches emerged, since the pioneering crystal growth work from 1970s. Many groups working on this hetero-epitaxial seeding have abandoned AlN growth altogether due to lot of persistently encountered problems. In this article, we focus on most of the common problems encountered in this process such as macro- and micro-hole defects, cracks, 3D-nucleation, high dislocation density, and incorporation of unintentional impurity elements due to chemical decomposition of the substrate at very high temperatures. Possible ways to successfully solve some of these issues have been discussed. Other few remaining challenges, namely low-angle grain boundaries and deep UV optical absorption, are also presented in the later part of this work. Particular attention has been devoted in this work on the coloration of the crystals with respect to chemical composition. Wet chemical etching gives etch pit density (EPD) values in the order of 105 cm-2 for yellow-coloured samples, while greenish coloration deteriorates the structural properties with EPD values of at least one order more.


Author(s):  
Dong Feng ◽  
Zhaobo Qin ◽  
Quanxing Ren ◽  
Shihao Sun ◽  
Qian Xia ◽  
...  

2011 ◽  
Vol 32 (3) ◽  
pp. 150-228 ◽  
Author(s):  
Lifeng Zhang ◽  
Xuewei Lv ◽  
Alex Tryg Torgerson ◽  
Mujun Long

Minerals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 451
Author(s):  
Galina Palyanova ◽  
Valery Murzin ◽  
Andrey Borovikov ◽  
Nikolay Karmanov ◽  
Sergei Kuznetsov

Composition of native gold and minerals in intergrowth with rhyolites of the Chudnoe Au-Pd-REE deposit (Subpolar Urals, Russia) was studied using optical microscopy, scanning electron microscopy, and electron microprobe analysis. Five varieties of native gold have been identified, based on the set of impurity elements and their quantities, and on intergrown minerals. Native gold in rhyolites from the Ludnaya ore zone is homogeneous and contains only Ag (fineness 720‰, type I). It is in intergrowth with fuchsite or allanite and mertieite-II. In rhyolites from the Slavnaya ore zone, native gold is heterogeneous, has a higher fineness, different sets and contents of elements: Ag, Cu, 840–860‰ (type II); Ag, Cu, Pd, 830–890‰ (III); Ag, Pd, Cu, Hg, 840–870‰ (IV). It occurs in intergrowth with fuchsite, albite, and mertieite-II (type II), or albite, quartz, and atheneite (III), or quartz, albite, K-feldspar, and mertieite-II (IV). High fineness gold (930–1000‰, type V) with low contents of Ag, Cu, and Pd or their absence occurs in the form as microveins, fringes and microinclusions in native gold II–IV. Tetra-auricupride (AuCu) is presented as isometric inclusions in gold II and platelets in the decay structures in gold III and IV. The preliminary data of a fluid inclusions study showed that gold mineralization at the Chudnoe deposit could have been formed by chloride fluids of low and medium salinity at temperatures from 105 to 230 °C and pressures from 5 to 115 MPa. The formation of native gold I is probably related to fuchsitization and allanitization of rhyolites. The formation of native gold II-V is also associated with the same processes, but it is more complicated and occurred later with a significant role of Na-, Si-, and K-metasomatism. The presence of Pd and Cu in the ores and Cr in fuchsite indicates the important role of mafic-ultramafic magmatism.


Author(s):  
Vasif Mamad Aga oglu Baba-zadeh ◽  
Narmina Nazim kyzy Ismayilova ◽  
Nazim Ajdar oglu Imamverdiyev ◽  
Shakhla Faig kyzy Abdullaeva

The article discusses the geochemical features of the Tulallar gold field in the Lesser Caucasus. Distributions of gold and accompanying elements (Ag, As, Hg, Bi, Cu, Zn) in metasomatically altered rocks taken from mine workings (ditches, adits, etc.) and wells are considered. The results of analyzes of furrow samples showed that the content of Au ranges from 0.4 ppm to 37.5 ppm, Ag - from 0.5 ppm to 48.4 ppm. In strongly kaolinized, weakly limonitized quartzites, the Au content ranged from 0.4 to 1.2 ppm, Ag - from 4.0 to 8.8 ppm. In the well drilled in the Central Block, closer to the surface, the siliceous breccias contain Au 309-363 ppm, Ag 132-250 ppm, and high As, Bi and Hg contents are also noted. A similar picture is observed in the silicified rocks of the wells of the Western block. Correlations between Au, Ag and other impurity elements were determined using the STAT program. A direct positive correlation has been established between Au and Ag, Au and Bi, Au and Hg. A positive relationship was also found between Ag and Bi, Ag and Hg. Cluster analysis revealed two different mineral associations: 1) native elements and their compounds - minerals and 2) polysulfide. The closest connection is observed between Ag, Hg and Au. Mineralogically, the Ag-Hg-Au-Bi cluster apparently corresponds to an early ore association - electrum, bismuth tellurides, possibly with inclusions of finely dispersed gold. The second, polymetallic cluster is characterized by a weak correlation bond Аs-Сu-Zn, which indicates that polysulfides were deposited later. The largest amount of Au was deposited in the early mineral association.


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