Temperature dependence of the fatigue strength of high-temperature nickel alloys

1976 ◽  
Vol 8 (5) ◽  
pp. 518-523
Author(s):  
B. N. Sinaiskii ◽  
A. D. Pogrebnyak ◽  
I. I. Ishchenko
Author(s):  
M.S. Grewal ◽  
S.A. Sastri ◽  
N.J. Grant

Currently there is a great interest in developing nickel base alloys with fine and uniform dispersion of stable oxide particles, for high temperature applications. It is well known that the high temperature strength and stability of an oxide dispersed alloy can be greatly improved by appropriate thermomechanical processing, but the mechanism of this strengthening effect is not well understood. This investigation was undertaken to study the dislocation substructures formed in beryllia dispersed nickel alloys as a function of cold work both with and without intermediate anneals. Two alloys, one Ni-lv/oBeo and other Ni-4.5Mo-30Co-2v/oBeo were investigated. The influence of the substructures produced by Thermo-Mechanical Processing (TMP) on the high temperature creep properties of these alloys was also evaluated.


Author(s):  
I. Khidirov ◽  
V. V. Getmanskiy ◽  
A. S. Parpiev ◽  
Sh. A. Makhmudov

This work relates to the field of thermophysical parameters of refractory interstitial alloys. The isochoric heat capacity of cubic titanium carbide TiCx has been calculated within the Debye approximation in the carbon concentration  range x = 0.70–0.97 at room temperature (300 K) and at liquid nitrogen temperature (80 K) through the Debye temperature established on the basis of neutron diffraction analysis data. It has been found out that at room temperature with decrease of carbon concentration the heat capacity significantly increases from 29.40 J/mol·K to 34.20 J/mol·K, and at T = 80 K – from 3.08 J/mol·K to 8.20 J/mol·K. The work analyzes the literature data and gives the results of the evaluation of the high-temperature dependence of the heat capacity СV of the cubic titanium carbide TiC0.97 based on the data of neutron structural analysis. It has been proposed to amend in the Neumann–Kopp formula to describe the high-temperature dependence of the titanium carbide heat capacity. After the amendment, the Neumann–Kopp formula describes the results of well-known experiments on the high-temperature dependence of the heat capacity of the titanium carbide TiCx. The proposed formula takes into account the degree of thermal excitation (a quantized number) that increases in steps with increasing temperature.The results allow us to predict the thermodynamic characteristics of titanium carbide in the temperature range of 300–3000 K and can be useful for materials scientists.


2019 ◽  
pp. 43-48
Author(s):  
Ben Nengjun ◽  
Zhou Pengfei ◽  
Oleksandr Labartkava ◽  
Mykhailo Samokhin

This work involves an analysis of high-chromium high-temperature deformable wieldable nickel alloys for use in GTE repair assemblies. It is shown that the alloys EP868 (VZh98) and Haynes 230 can be used in welded assemblies with an operating temperature of 800-1100 °C. The alloys Nimonic 81, Nimonic 91, IN 935, IN 939, and Nicrotan 2100 GT also have a high potential for use in welded assemblies. They are characterized by a combination of good weldability, high-temperature strength, and resistance to scaling. There have been conducted studies on high-temperature salt corrosion of model nickel alloys. They allowed establishing the patterns of the impact of base metal alloying with chromium, aluminum, titanium, cobalt, tungsten, molybdenum, niobium, tantalum and rare earth metals on the critical temperature of the start of salt corrosion Tcor and the alloy mass loss. It has been established that alloys with a moderate concentration (13-16%) of chromium can possess satisfactory hightemperature corrosion resistance (HTC resistance) under the operating conditions of ship GTE. The HTC resistance of CrAl-Ti alloys improves upon reaching the ratio Ti/Al ˃ 1. Meanwhile, the ratio Ti/Al ˂ 1 promotes the formation of corrosion products with low protective properties. The positive effect of tantalum on the HTC resistance of alloys is manifested at higher test temperatures than that of titanium, and the total content of molybdenum and tungsten in alloys is limited by the condition 8Mo2 – 2W2 = 89. The presence of refractory elements stabilizes the strengthening phase and prevents formation of the ɳ-phase. However, their excess promotes formation of the embrittling topologically close packed (TCP) phases and boundary carbides of an unfavorable morphology. Based on the studies of the HTC resistance, there has been identified a class of model high-temperature corrosionresistant nickel alloys with a moderate or high chromium content (30%), Ti/Al ˃ 1, and a balanced content of refractory and rare-earth elements.


1996 ◽  
Vol 442 ◽  
Author(s):  
J.-M. Spaeth ◽  
S. Greulich-Weber ◽  
M. März ◽  
E. N. Kalabukhova ◽  
S. N. Lukin

AbstractThe electronic structure of nitrogen donors in 6H-, 4H- and 3C-SiC is investigated by measuring the nitrogen hyperfine (hf) interactions with electron nuclear double resonance (ENDOR) and the temperature dependence of the hf split electron paramagnetic resonance (EPR) spectra. Superhyperfine (shf) interactions with many shells of 13C and 29Si were measured in 6H-SiC. The hf and shf interactions are discussed in the framework of effective mass theory. The temperature dependence is explained with the thermal occupation of the lowest valley-orbit split A1 and E states. It is proposed that the EPR spectra of P donors observed previously in neutron transmuted 6H-SiC at low temperature (<10K) and high temperature (>60K) are all due to substitutional P donors on the two quasi-cubic and hexagonal Si sites, whereby at low temperature the E state is occupied and at high temperature the A1 state. The low temperature spectra are thus thought not to be due to P-vacancy pair defects as proposed previously.


1992 ◽  
Vol 105-110 ◽  
pp. 477-484 ◽  
Author(s):  
C.S. Sundar ◽  
A. Bharathi ◽  
Yan Ching Jean ◽  
W.Y. Ching ◽  
X. Lu ◽  
...  

1988 ◽  
Vol 21 (4) ◽  
pp. 1174-1176 ◽  
Author(s):  
C. De Rosa ◽  
G. Guerra ◽  
V. Petraccone ◽  
R. Centore ◽  
P. Corradini

1978 ◽  
Vol 32 (5) ◽  
pp. 489-493 ◽  
Author(s):  
D. B. Olson ◽  
W. G. Mallard ◽  
W. C. Gardiner

Absorptivity measurements for the 3.39 µm He-Ne laser line are reported for methane, acetylene, ethylene, ethane, propane, n-butane, and n-pentane over the temperature range 300 < T < 2000°K. Shock-heated mixtures containing formaldehyde and methyl iodide showed no absorption or transient absorption at any temperature that could be attributed to formaldehyde or methyl radicals. The temperature dependence of the absorptivities of the C2 and higher hydrocarbons was much weaker than for methane. Comparison with simple theoretical expectations and broad-band absorptivities showed that the higher hydrocarbon absorptions include quite large numbers of absorbing states.


2005 ◽  
Vol 47 (5-6) ◽  
pp. 239-243
Author(s):  
Yu. A. Puchkov ◽  
V. A. Poklad ◽  
Yu. P. Shkretov

2021 ◽  
Vol 10 (1) ◽  
pp. 586-595
Author(s):  
Ruzhuan Wang ◽  
Dingyu Li ◽  
Weiguo Li

Abstract Hardness is one of the important mechanical properties of high-temperature structural ceramics and their composites. In spite of the extensive use of the materials in high-temperature applications, there are few theoretical models for analyzing their temperature-dependent hardness. To fill this gap in the available literature, this work is focused on developing novel theoretical models for the temperature dependence of the hardness of the ceramics and their composites. The proposed model is just expressed in terms of some basic material parameters including Young’s modulus, melting points, and critical damage size corresponding to plastic deformation, which has no fitting parameters, thereby being simple for materials scientists and engineers to use in the material design. The model predictions for the temperature dependence of hardness of some oxide ceramics, non-oxide ceramics, ceramic–ceramic composites, diamond–ceramic composites, and ceramic-based cermet are presented, and excellent agreements with the experimental measurements are shown. Compared with the experimental measurements, the developed model can effectively save the cost when applied in the material design, which could be used to predict at any targeted temperature. Furthermore, the models could be used to determine the underlying control mechanisms of the temperature dependence of the hardness of the materials.


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