Chelation-enhanced fluorescence of phosphorus doped carbon nanodots for multi-ion detection

2017 ◽  
Vol 184 (7) ◽  
pp. 2063-2071 ◽  
Author(s):  
Khalid M. Omer ◽  
Aso Q. Hassan
2021 ◽  
Author(s):  
Gyeongjin Kim ◽  
Donghwan Choi ◽  
Cheal Kim

Abstract A new benzothiazole-based chemosensor BTN (1-((Z)-(((E)-3-methylbenzo[d]thiazol-2(3H)-ylidene)hydrazono)methyl)naphthalen-2-ol) was synthesized for the detection of Cu2+. BTN could detect Cu2+ with “off-on” fluorescent response from colorless to yellow irrespective of presence of other cations. Limit of detection for Cu2+ was determined to be 3.3 µM. Binding ratio of BTN and Cu2+ turned out to be a 1:1 with the analysis of Job plot and ESI-MS. Sensing feature of Cu2+ by BTN was explained with theoretical calculations, which might be owing to internal charge transfer and chelation-enhanced fluorescence processes.


2018 ◽  
Vol 72 (11) ◽  
pp. 1645-1652 ◽  
Author(s):  
Kailong Dong ◽  
Jiasheng Zhou ◽  
Taiqun Yang ◽  
Shan Dai ◽  
Hao Tan ◽  
...  

In this study, we report a straightforward strategy for Hg2+ ion detection. Fluorescent Au nanoparticles (NPs) were one-pot synthesized using a polymer (polyvinyl pyrrolidone [PVP]) as both capping and fluorescence agent. The as-synthesized PVP-Au NPs showed a remarkably rapid response selectively for Hg2+ ions compared to 14 other metal ions. The detection limit of Hg2+ was estimated at 100 nM. We discuss the emission and quenching mechanism of the PVP-Au NPs, the former being attributed to metal enhanced fluorescence and the latter being related to static quenching by Hg2+. The fluorescence of PVP-Au NPs offers an efficient and reliable strategy for Hg2+ ions detection. They therefore have a great potential for applications in health and environmental monitoring.


2018 ◽  
Vol 6 (44) ◽  
pp. 12086-12094 ◽  
Author(s):  
Virendra Kumar ◽  
Bahadur Sk ◽  
Subhankar Kundu ◽  
Abhijit Patra

Tailoring the formation of dynamic and static excimers in a C3-symmetric architecture led to efficient generation of white light and sensitive detection of Fe3+ and Al3+ in a single molecular platform.


1989 ◽  
Vol 111 (23) ◽  
pp. 8735-8737 ◽  
Author(s):  
Michael E. Huston ◽  
Engin U. Akkaya ◽  
Anthony W. Czarnik

2015 ◽  
Vol 3 (17) ◽  
pp. 3617-3624 ◽  
Author(s):  
Peng Wang ◽  
Jiang Wu ◽  
Panpan Zhou ◽  
Weisheng Liu ◽  
Yu Tang

A novel peptide-based fluorescent chemosensor containing both tryptophan and a dansyl fluorophore has been designed to detect Zn2+ in 100% aqueous solution and living cells via two pathways including fluorescence resonance energy transfer and chelation enhanced fluorescence.


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