Effect of pH value on the synthesis and characterization of Ba0.5Sr0.5Co0.8Fe0.2O3−δ powders prepared by the citrate–EDTA complexing method

2010 ◽  
Vol 45 (14) ◽  
pp. 3824-3832 ◽  
Author(s):  
I.-Ming Hung ◽  
Chen-Yu Liang ◽  
Chun-Jing Ciou ◽  
Ren-Zheng Song ◽  
Zu-Yu Lai
2012 ◽  
Vol 41 ◽  
pp. 1627-1633 ◽  
Author(s):  
Koay Mei Hyie ◽  
Nor Azrina Resali ◽  
Wan Normimi Roslini Abdullah ◽  
W.T. Chong

2007 ◽  
Vol 280-283 ◽  
pp. 661-664 ◽  
Author(s):  
Jing Tao Ma ◽  
Xu Ping Lin ◽  
Bao Qing Zhang ◽  
Jiu Lin Wang

A sol-gel auto-ignited synthesis, which is a hybrid of sol-gel and auto-ignited techniques, was applied to preparation of homogeneous and stoichiometric BaCe0.8Y0.2O2.9 nanocrystalline ceramic powder as solid electrolyte used in solid oxide fuel cells at 1000°C. Optimal pH value for the mixed citrate-nitrate solutions was determined by calculation. The DTA-TG and XRD were used to investigate the thermal decomposition of the gel precursor. The structure and phase present of the nanocrystalline BaCe0.8Y0.2O2.9 powders were characterized by XRD, BET and SEM techniques.


2015 ◽  
Vol 1096 ◽  
pp. 147-155
Author(s):  
Xin Li ◽  
Mei Xiang Wan ◽  
Cong Ju Li

Poly (o-toluidine) (POT), poly (m-toluidine) (PMT) and poly (p-toluidine) (PPT) were chemically oxidized by ammonium persulfate (APS) as both oxidant and dopant through a very simple self-assembly process. The structure characterizations by elemental analysis, XPS and FTIR demonstrated that APS is served as both oxidant and dopant due to the proton acid produced during polymerization, which is proven by the decreasing pH value of the reaction solution along with the increase of polymerization time. Besides, the influences of the alkyl-substitution position on the molecular structure, polymerization process, morphology and electrical properties are also discussed.


2011 ◽  
Vol 287-290 ◽  
pp. 569-572 ◽  
Author(s):  
Mao Lin Zhang ◽  
Yuan Gao ◽  
Long Feng Li

Ca-Mg-Al hydrotalcite-like compounds (CaMgAl-HTLcs) were synthesized by a hydrothermal method, and characterized by X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and differential thermal analysis (DTA) techniques. The effects of the medium pH value, the molar ratio of the raw materials, the reaction temperature and the reaction time on the structure of CaMgAl-HTLcs were studied. The results showed that increasing treatment temperature and reaction time could improve the crystallinity and monodispersity of hydrotalcite-like compound particles. And well-defined CaMgAl-HTLcs could be prepared at a pH value of 10~11 with n (Mg+Ca): n (Al) = 1~3 and n (Mg): n (Ca) = 1~3.


2012 ◽  
Vol 583 ◽  
pp. 391-394 ◽  
Author(s):  
Qiang Zhang ◽  
Li Qin You ◽  
Chun Shan Zhu

The β-CD/NIPAAm-SA microspheres with temperature and pH sensibility were synthesized with β-cyclodextrin(β-CD), N-isopropylacrylamide(NIPAAm) and succinic anhydride(SA), and their drug-releasing properties were investigated. SEM showed that the β-CD/NIPAAm-SA microspheres had a good sphericity and a grain size of 200-300µm.And the swelling results indicated that the swelling rate was decreased with temperature raising and increased with pH value improving, and the phase transition volume changed suddenly at the temperature of about 27°C and 38°C, and the pH values of about 1.4 and 7.4. It revealed that the β-CD/NIPAAm-SA microspheres had pH and temperature sensibilities.


2020 ◽  
Vol 6 (3) ◽  
pp. 44
Author(s):  
Athanasia K. Tolkou ◽  
Anastasios I. Zouboulis

This study presents for the first time the synthesis and characterization of GO (graphene oxide), PFSiC (polyferric silicate chloride), and hybrid GO-PFSiC derivatives, aiming to enhance synergistically the performance of coagulation, when applied for the treatment of water. The structure and the morphology of composite GO-PFSiC coagulants were studied in detail by the application of FTIR, XRD, and SEM characterization techniques. Furthermore, the proposed coagulants were applied for the treatment of simulated turbid surface water. The effects of the reagent’s dosage, pH value, and experimental/operational conditions on the coagulation efficiency, applied mainly for the removal of turbidity, were examined. The results, obtained from the FTIR and XRD measurements, showed the presence of a bond between the PFSiC and the GO surface, indicating that the PFSiC particles are distributed uniformly on the surface of graphene, which was also confirmed by the SEM images. Especially, the composite compound GO-PFSiC1.5-15-0.5 presents the most uniform distribution of iron on the surface of graphene oxide and exhibits the optimum coagulation efficiency, while it significantly reduces the turbidity for doses above 3–5 mg/L, i.e., achieving the respective legislation limit as proposed by WHO. Specifically, at the alkaline pH values (>7.9), the removal of turbidity reaches 96%. Consequently, the results of this study render these materials as potential coagulant agents for further research and applications, aiming to also achieve the co-removal of other water components.


2021 ◽  
Vol 1039 ◽  
pp. 211-214
Author(s):  
Zaid K. Alkaabi

In this work, zinc oxide were synthesized by biological method using Aloe vera plant and the water solution of zinc . The detail characterization of the nanoparticles was carried out on different PH value . The samples were examined with an X-ray diffraction device and the results were almost identical to the JCPDS standard. It was also observed that the size of the particles was affected by the basic and acidic medium in a large way, as the results obtained from the Transmission Electron Microscopy The particle sizes ranged from 5nm to 100nm depending on the change of the PH value.


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