Thermophysical investigations of exfoliated graphite nanoplatelets and active carbon in binary aqueous environments at different temperatures

2014 ◽  
Vol 50 (2) ◽  
pp. 587-598 ◽  
Author(s):  
Ion Ion ◽  
Florinela Sirbu ◽  
Alina Catrinel Ion
Keyword(s):  
Active Carbon ◽  
Exfoliated Graphite ◽  
Graphite Nanoplatelets ◽  
Aqueous Environments ◽  
Different Temperatures ◽  
Exfoliated Graphite Nanoplatelets

scholarly journals A Thermodynamics Study on the Tetrahydrofuran Effect in Exfoliated Graphite Nanoplatelets and Activated Carbon Mixtures at Temperatures between 293.15 and 308.15 K

2018 ◽  
Vol 2018 ◽  
pp. 1-13 ◽  
Author(s):  
Florinela Sirbu ◽  
Alina Catrinel Ion ◽  
Luiza Capra ◽  
Ion Ion
Keyword(s):  
Activated Carbon ◽  
Normal Pressure ◽  
Isentropic Compressibility ◽  
Solute Concentration ◽  
Exfoliated Graphite ◽  
Graphite Nanoplatelets ◽  
Relaxation Strength ◽  
Different Temperatures ◽  
Exfoliated Graphite Nanoplatelets ◽  
Experimental Values

A thermodynamics study on exfoliated graphite nanoplatelets dispersed in tetrahydrofuran in comparison with activated carbon dispersed in same solvent was realised. The refractive index, speed of sound, and density of diluted mixed binary solutions of exfoliated graphite nanoplatelets and activated carbon in tetrahydrofuran were measured between 0 and 100 kg·m−3with composition step of 20 kg·m−3and at temperatures from 293.15 to 308.15 K and at normal pressure. The isentropic compressibility, acoustic impedance, specific refraction, relaxation strength, and space-filling factor have been evaluated for six concentrations, at four different temperatures for each system. The identified possible molecular interactions between the edges and the surface of exfoliated graphite nanoplatelets and tetrahydrofuran molecules, which include modifications in the structure of exfoliated nanostructured materials in tetrahydrofuran solvent and the influence of the temperature, and of the solute concentration have been calculated based on the obtained experimental values.

Kinetic Adsorption of Humic Acids Mixture Obtained from Microalgae on Exfoliated Graphite Nanoplatelets

2018 ◽  
Vol 69 (1) ◽  
pp. 191-195
Author(s):  
Elena Radu ◽  
Elena Emilia Oprescu ◽  
Cristina Emanuela Enascuta ◽  
Catalina Calin ◽  
Rusandica Stoica ◽  
...  
Keyword(s):  
Humic Acid ◽  
Humic Acids ◽  
Alkali Treatment ◽  
Exfoliated Graphite ◽  
Acid Mixture ◽  
Acidic Ph ◽  
Graphite Nanoplatelets ◽  
Mixture Concentration ◽  
Ft Ir ◽  
Exfoliated Graphite Nanoplatelets

The dehydration of polysaccharides fraction in the presence of acid catalysts, is a chemical process in which results as secondary product humic matter. In our work, the humic acid mixture was for the first time based on our knowledge extracted from defatted microalgae biomass rich in polysaccharides by standard alkali treatment, followed by precipitation at acidic pH. The dried humic acid mixture has been characterized using infrared spectroscopic measurements (FT-IR). Exfoliated graphite nanoplatelets (xGnP) were used as new adsorbents for this type of humic acids mixture, their adsorption being investigated. The effect of several parameters such as: contact time, concentration of humic acid mixture, concentration of xGnP, temperature and pH of the solutions were studied. The process of adsorption took place with good results, in the following conditions: at a concentration of humic acid mixture of 18.6 mg L-1, an xGnP amount of 0.01 mg in 25 mL of solution, at a temperature of 25 �� and at acidic pH values, in aqueous solution.

Co-milling-assisted exfoliated graphite nanoplatelets filler introduction in polyethylene and alumina composites

2018 ◽  
Vol 53 (13) ◽  
pp. 1815-1826
Author(s):  
Sheng Cai Tan ◽  
Jimmy KW Chan ◽  
Kian Ping Loh
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Composite Materials ◽  
Exfoliated Graphite ◽  
Flexural Properties ◽  
Graphite Nanoplatelets ◽  
Alumina Composites ◽  
Exfoliated Graphite Nanoplatelets ◽  
Polyethylene Composites

This paper aims to investigate the effect of co-milling-assisted exfoliation of graphite into polyethylene and alumina matrices on the mechanical properties of the composites. Tensile mechanical properties of composite materials based on polyethylene reinforced with graphite and graphite-derived fillers at 0–0.75 wt% loading were investigated, while hardness and flexural properties of alumina composites with 0.25 wt% loading of the same additives were assessed. Exfoliated graphite, applied at 0.25–0.75 wt% in pre-exfoliated form or in a co-milling-assisted fashion, has been demonstrated to be effective in enhancing the tensile strength of polyethylene composites. Similar enhancement in hardness and flexural properties was observed in alumina composites with 0.25 wt% loading of the exfoliated graphite. Co-milling-assisted exfoliated graphite nanoplatelets additive introduction has been found to effect a more desirable mechanical properties enhancement in the composites investigated in this study.

Performance Evaluation of Minimum Quantity Lubrication With Exfoliated Graphite Nanoplatelets in Turning Titanium Alloy

2018 ◽  
Author(s):  
Dinh Nguyen ◽  
Pil-Ho Lee ◽  
Yang Guo ◽  
Patrick Kwon ◽  
Kyung-Hee Park
Keyword(s):  
Minimum Quantity Lubrication ◽  
Exfoliated Graphite ◽  
Experimental Result ◽  
Graphite Nanoplatelets ◽  
Crater Wear ◽  
Minimum Quantity ◽  
Preliminary Experimental Result ◽  
Tribological Surfaces ◽  
Exfoliated Graphite Nanoplatelets ◽  
Carbide Inserts

This paper evaluates the performances of dry, minimum quantity lubrication (MQL) and MQL with nanofluid in turning the most common titanium (Ti) alloy, Ti-6Al-4V, in a solution treated and aged (STA) microstructure. In particular, the nanofluid evaluated here is vegetable oil (rapeseed) mixed with small concentrations of exfoliated graphite nanoplatelets (xGnP). The focus of this paper is on turning process because it poses a challenging condition to apply oil droplets directly onto the tribological surfaces of a cutting tool due to the continuous engagement of tool and work material. A series of turning experiments was conducted with uncoated carbide inserts while measuring the cutting forces with the dynamometer under various conditions to determine its effectiveness and optimal MQL condition in turning. The worn inserts are retrieved to measure flank and crater wear using confocal microscopy. This preliminary experimental result shows that the use of MQL and nanofluid is effective in improving the machinability of Ti alloys in turning processes.

scholarly journals Mechanical properties and microstructural investigation of polypropylene/exfoliated graphite nanoplatelets/ nano-magnesium oxide composites

2018 ◽  
Vol 7 (2) ◽  
pp. 897
Author(s):  
A I. Alateyah ◽  
F H. Latief
Keyword(s):  
Mechanical Properties ◽  
Flexural Modulus ◽  
Exfoliated Graphite ◽  
Graphite Nanoplatelets ◽  
Microstructural Investigation ◽  
The Matrix ◽  
Exfoliated Graphite Nanoplatelets ◽  
Polypropylene Matrix ◽  
Xrd Patterns ◽  
Oxide Composites

Polypropylene/exfoliated graphite nanoplatelets composites reinforced with a low concentration of nano-magnesia have been successfully fabricated, using injection molding machine. The mechanical properties and microstructure of the composites were investigated, in the present study. The XRD patterns of the composites showed the peaks of xGnP and n-MgO, where the intensity of the xGnP peaks became stronger with increasing the concentration of xGnP added into polypropylene matrix. In addition, the SEM micrographs revealed a good dispersion of fillers within the matrix. The results showed that increasing the amount of exfoliated graphite nanoplatelets up to 10 wt. % resulted in increasing the composite flexural strength, flexural modulus, and hardness up to 35% and 91%, 6.7%, respectively, compared to the monolithic polypropylene.  

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