scholarly journals Effect of graphene nanoplatelets on the mechanical and gas barrier properties of woven carbon fibre/epoxy composites

Author(s):  
Xudan Yao ◽  
Thomas P. Raine ◽  
Mufeng Liu ◽  
Muzdalifah Zakaria ◽  
Ian A. Kinloch ◽  
...  

AbstractCarbon-fibre-reinforced polymer (CFRP) composites are promising materials for non-metallic pipe applications in the oil and gas industry owing to their high corrosion resistance, specific strength and stiffness. However, CFRP has poor gas barrier performance meaning that a liner has to be inserted. Graphene-based nanomaterials have been demonstrated to improve gas barrier properties in thermoplastic polymers, and thus, a CFRP–graphene hybrid composite could provide an alternative to lined pipes. In this work, a method combining spray coating with vacuum-assisted resin infusion was developed to fabricate CFRP hybrid composites with preferred in-plane aligned graphene nanoplatelets. Tensile and flexural properties, as well as CO2 gas permeability, were evaluated. It was illustrated that both tensile and flexural properties performed better under relatively low GNP loadings (< 0.2 vol%), while gas barrier property was significantly improved with the increasing GNP loadings which fits the Nielsen model with an effective GNP aspect ratio of 350. Graphical abstract

RSC Advances ◽  
2016 ◽  
Vol 6 (60) ◽  
pp. 55331-55342 ◽  
Author(s):  
Laura Genovese ◽  
Michelina Soccio ◽  
Matteo Gigli ◽  
Nadia Lotti ◽  
Massimo Gazzano ◽  
...  

Bio-based and compostable poly(ester urethane)s with tailorable mechanical and gas barrier properties designed for packaging purposes.


2019 ◽  
Vol 7 ◽  
pp. 808-815 ◽  
Author(s):  
Mohd Ihsan Che Mohd Noh ◽  
Mohd Ambri Mohamed ◽  
Ahmad Ghadafi Ismail ◽  
Mohd Hanafi Ani ◽  
Burhanuddin Yeop Majlis

Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2097
Author(s):  
Qian Wen ◽  
Ao Tang ◽  
Chengliang Chen ◽  
Yiwu Liu ◽  
Chunguang Xiao ◽  
...  

This study designed and synthesised a meta-amide-substituted dianiline monomer (m-DABA) as a stereoisomer of DABA, a previously investigated para-amide-substituted dianiline monomer. This new monomer was polymerised with pyromellitic dianhydride (PMDA) to prepare a polyimide film (m-DABPI) in a process similar to that employed in a previous study. The relationship between the substitution positions on the monomer and the gas barrier properties of the polyimide film was investigated via molecular simulation, wide-angle X-ray diffraction (WXRD), and positron annihilation lifetime spectroscopy (PALS) to gain deeper insights into the gas barrier mechanism. The results showed that compared with the para-substituted DABPI, the m-DABPI exhibited better gas barrier properties, with a water vapour transmission rate (WVTR) and an oxygen transmission rate (OTR) as low as 2.8 g·m−2·d−1 and 3.3 cm3·m−2·d−1, respectively. This was because the meta-linked polyimide molecular chains were more tightly packed, leading to a smaller free volume and lower molecular chain mobility. These properties are not conducive to the permeation of small molecules into the film; thus, the gas barrier properties were improved. The findings have significant implications for the structural design of high-barrier materials and could promote the development of flexible display technology.


2016 ◽  
Vol 56 (8) ◽  
pp. 922-931 ◽  
Author(s):  
Xiumei Gao ◽  
Dekun Sheng ◽  
Xiangdong Liu ◽  
Tongbing Li ◽  
Fance Ji ◽  
...  

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